制冷剂比定压热容的推算理论研究

为了探索比定压热容具有良好精度的统一的理论预测模型,把比定压热容看成导出热力性质,采用余函数法,分别基于通用性好、精确度高的Peng-Robinson状态方程(P-R)和改进型的M-H方程(M-H81)推导了比定压热容的计算公式并编写了程序。对于M-H81方程,比定压热容数值的获得需基于最佳化的方程常数,在广泛的温度范围内算得了10种制冷剂的M-H81方程各常数。针对具体的制冷剂研究对象,利用该比定压热容的推算理论就可以进行推算和进一步的验证了。     

城市空间扩张及结构演化的制度因素分析

改革开放以来,中国城市的发展环境发生了巨大的变迁,制度力成为深刻影响城市空间扩张与结构演变的关键因素。在转型期,中国只有加快推进地方政府企业化治理体系,土地制度、土地规制等相应的制度性变革,才是实现城市空间的集约增长、理性增长和结构优化的根本之策。     

晶闸管弧焊逆变器半桥变换电路的工作状态分析及设计

在新建立的电流、电压均为非零初始条件的ＲＬＣＵ型电容放电理论基础上，分析了各种典型运行状态及相应的激磁范围，确定了合理的设计依据状态。通过设计状态下的Ｔ形等效电路，解相应的电路方程，得到了有关电磁量的变化规律，提供了进行精确、合理的工程设计的基本公式，为晶闸管弧焊逆变器的发展和提高创造了有利条件。     

相干态光场的位相涨落

根据Pegg-Barnett位相理论,推导出相干态光场的位相概率分布函数,计算出位相涨落,并利用MATHEMATICA对相干态光场的位相函数和位相涨落进行了数值模拟,画出了示意图.结果表明位相函数同时受e指数函数和幂指数函数的制约,从均匀分布到泊松分布到均匀分布,直至呈现零分布;在位相变化的一个周期内,相干态位相分布曲线出现涨落,涨落同时受参考位相和相干系数的影响,随着n值的增加,曲线趋向于高斯分布.     

Transport properties of 1,1,1,2-tetrafluoroethane (R134a)

New equations for the thermal conductivity and the viscosity of R134a that are valid in a wide range of pressures and temperatures are presented. They were obtained through a theoretically based, critical evaluation of the available experimental data, which showed considerable inconsistencies between data sets, in particular in the vapor phase. In the critical region the observed enhancement in the thermal conductivity is well represented by a crossover model for the transport properties of fluids. Since thermodynamic properties enter into the calculation of the critical enhancement of the transport properties, a new fundamental equation for the critical region was developed also.Paper dedicated to Professor Joseph Kestin.     

Mixture equations of state: Composition dependence

This paper discusses theoretical models for the composition dependence of equations of state and compares the quality of predictions against experimental thermodynamic property data. The mean density approximation (MDA) and the van der Waals one-fluid (VDW1) model are compared with hybrid mixing rules (HMR), in which rigorous composition dependence is used for the second and third virial coefficients and the conformai solution model is used for equation-of-state density terms beyond the third virial term. It is found that when values of unity are used for all binary and three-body unlike interaction parameters, calculated densities for methane-normal heptane mixtures have average absolute deviations of 3.54% for MDA, 4.04% for VDW1, and 2.59% for HMR. When vapor-liquid equilibrium calculations were performed for the methane-normal heptane system, average absolute deviations of calculatedK values from experimental values were 16.7% for methane and 36.4% for normal heptane using HMR, whereas when conformal solution model (CSM) mixing rules were used, the results were 34.8% for methane and 66.7% for normal heptane. When the binary interaction parameter for the characterization of interaction energies is determined, it is found to be less sensitive to state conditions in the case of HMR than either MDA or VDW1. These preliminary results suggest the potential of mixture equation-of-state methods which utilize rigorous composition dependence for the lower-order virial coefficients.Paper presented at the Second U.S.-Japan Joint Seminar on Thermophysical Properties, June 23, 1988, Gaithersburg, Maryland, U.S.A.     

New Group-Contribution Method for Predicting Temperature-Dependent Properties of Pure Organic Compounds

A new method for predicting temperature-dependent properties of organic compounds is presented. It is a combination of a group-contribution method with the novel non-random hydrogen-bonding (NRHB) equation-of-state theory. First-order and second-order groups are used to predict the three characteristic scaling constants of the NRHB model. With these scaling constants, one is able to estimate/predict temperature-dependent properties of pure organic compounds such as vapor pressure, liquid density, heat of vaporization and more, in a wide range of temperatures. The influence parameter, κ, which is needed for the estimation of surface tension at any given temperature, is also predicted by the same group-contribution method     

非间断软件回归测试模型研究

软件测试是开发过程的重要环节。回归错误在开发过程中严重影响着开发的效率,其隐匿特性也使得测试比较困难。因此,本文提出一种非间断测试的模型,用于加强对回归错误的管理,节约不必要的无谓工作时间,提高软件开发的效率。这种模型对用户开发行为进行模拟和推测,在经过大量的数据训练后,寻找测试行为、错误发生等开发动作的捕获点,从而找到最佳的测试策略。在不影响开发人员工作的前提下,可对当前最新的代码进行测试,最大程度上避免回归错误长期隐藏在前期代码中,保持整个开发过程的稳步前进。     

Study of Electronic Structure and Magnetic, Properties of NdFe 10 M 2 Compounds by LMTO Method

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