丁苯乳液对钢纤维混凝土韧性和微观结构的影响

本文对比研究了丁苯乳液改性混凝土、钢纤维改性混凝土以及丁苯乳液增强钢纤维混凝土的力学性能和韧性.试验结果表明:丁苯乳液能改善新拌混凝土的工作性能;混凝土的抗压强度随着丁苯乳液掺量的增加而显著降低,但其抗折强度随着丁苯乳液的增加而提高;丁苯乳液与钢纤维复掺,混凝土具有更高的抗折强度、以及弯曲韧性.丁苯乳液在混凝土中交织成膜,提高了界面过渡区的显微硬度;增加了浆体的致密性,增强了钢纤维与混凝土之间的界面粘结强度.     

基于混料试验设计的水泥-钢渣-矿渣三元胶凝体系的配比优化

针对钢铁渣粉用作水泥辅助性胶凝材料时胶凝体系的配比优化,采用混料设计方法并基于抗压强度测试建立了水泥-钢渣-矿渣三元胶凝体系的强度与各组分含量之间的数学拟合模型.模型可准确预测三组分任意配比时不同龄期的抗压强度;利用混料设计中的“响应优化器”工具可获得最大限度利用钢铁渣粉条件下不同目标强度等级水泥的最优配比.基于52.5强度等级水泥,在钢铁渣粉的取代量为50％时制备42.5和42.5R强度等级的复合水泥,水泥、钢渣和矿渣的最优配比分别为0.50∶0.33∶0.17和0.50∶0.15∶0.35.     

钢渣-粉煤灰基地质聚合物的制备及性能研究

本文以钢渣和粉煤灰为原料,通过碱激发方式制备了地质聚合物胶凝材料.测试了钢渣不同含量下,粉煤灰基地质聚合物的1d、3d、7d、28 d抗压强度,并采用XRD、FTIR、SEM对28 d样品进行表征.抗压强度测试中,当钢渣掺量为30％时强度最高,达到40.33 MPa.红外图谱分析表明反应生成了Si-O-T(Si,Al)三维网状结构的地质聚合物.样品晶相分析中发现了C-S-H相,表明在发生地质聚合反应的同时也发生了水化反应.通过SEM微观形貌图可以看到,钢渣掺量为30％的样品结构致密,孔隙率低,但当钢渣掺量过高时,由于钢渣活性较低,钢渣碱激发效果下降,仍有部分未反应的钢渣颗粒出现.     

新显色剂4—（2—苯并噻唑偶氮）邻苯二酚—钼（Ⅵ）—OP体系的分光光度研究

在ｐＨ５．０～５．７范围内，新显色剂４－（２－苯并噻唑偶氮）邻苯二酚（ＢＴＡＰＣ）与钼（Ⅵ）和非离子表面活性剂ＯＰ反应，形成稳定的、带负电荷的、紫红色三元胶束配合物。该配合物中Ｍｏ（Ⅵ）与ＢＴＡＰＣ的组成比为１∶２；其λｍａｘ为５６０ｎｍ，对比度（Δλ）为１２８ｎｍ；在２０℃、ｐＨ５．２和μ０．１时，配合物的表观稳定常数为３．０２×１０１０，表观摩尔吸光系数ε５６０为８．１１×１０４Ｌ·ｍｏｌ－１·ｃｍ－１，真实ε５６０为７．６７×１０４Ｌ·ｍｏｌ－１·ｃｍ－１。钼含量在０～０．７２ｍｇ／Ｌ范围内遵从比耳定律。建议了配合物的结构。本法简便、快速、准确，用于合金钢试样中痕量或小量钼的测定，取得了满意的结果。     

碳钢锻件的超声波检测

对碳钢锻件在不同加工阶段进行超声波检测,做到及早发现缺陷,及时处理缺陷,从而达到减少损失、降低损害、保证锻件质量的目的。     

防腐工艺对钢铁零件耐盐雾性的影响

通过对几种钢铁防腐工艺耐盐雾检测结果的对比研究,分析了不同防腐蚀工艺对钢铁零件防腐性能的影响,说明在实际工作中如何根据产品的使用环境和需要选择不同的防腐蚀工艺。     

超高性能混凝土的制备

采用超低水胶比和高强度水泥常温养护制备超高性能混凝土,以水胶比、钢纤维的体积掺量为变化参数分析了其对超高性能混凝土抗压强度、抗折强度及拉伸性能的影响.研究结果表明:在最大密实度的情况下,混凝土的抗压强度随水胶比的增大而降低.本文钢纤维体积掺量2％,水胶比在0.12～0.22范围内,28d抗压强度随水胶比的增大先升高后降低,水胶比为0.18时,UHPC的抗压强度最大,达152.8 MPa;钢纤维体积掺量在1.7％ ～2.9％时,随掺量的增加,抗压强度、抗折强度均呈增大的趋势,在2.9％ ～3.5％时,抗压强度和抗折强度有下降的趋势,体积掺量为2.9％时,28 d抗压强度和抗折强度达到最大值,分别为153.5 MPa和37.1 MPa.综合经济性、施工性能、力学性能来看,2％为钢纤维最佳体积掺量.在最佳掺量下,拉伸应力达到峰值8.94 MPa时,拉伸应变达0.012％.     

9．00R20全钢载重子午线轮胎胎体骨架材料研究

为适应9.00R20轮胎实际使用的需要,采用3+9+15×0.22+0.15钢丝帘线作为胎体骨架材料,对胎体强度与胎侧曲挠变形以及胶与钢丝帘线的粘合力进行了分析、研究、改进.产品经过实际使用性能考核,达到改进设计目的,克服了胎侧"拉链式"爆破病疵,提高了轮胎使用安全性.     

Corrosion Inhibition of Mild Steel in Acidic Medium using 2-amino Thiophenoland 2-Cyanomethyl Benzothiazole

The corrosion inhibition characteristics of 2-amino thiophenol (ATP) and 2-cyanomethyl benzothiazole (CNMBT) on two types of steel in 1m HCl medium were investigated at different temperatures (25, 30, 35, 40 and 50°C). The pitting corrosion behaviour for the same system was studied using a potentiodynamic technique. The pitting corrosion resistance of steel samples increased with increase in concentration of the ATP and CNMBT. Some samples were examined by scanning electron microscopy. The effects of the inhibitors on the general corrosion of the two samples were investigated by using gravimetric and galvanostatic polarization techniques. The inhibition efficiencies increased with increase their concentration but decreased with increase in temperature. Free energies of activation, enthalpies and entropies for the inhibition processes were determined from rate constant data measured and different temperatures at different concentrations of ATP and CNMBT. Results were compared with fits obtained from the application of the Langmuir isotherm. Results were correlated to the chemical structure of the inhibitors. The inhibition efficiency of CNMBT is higher than that of ATP.     

An investigation of some Schiff bases as corrosion inhibitors for austenitic chromium–nickel steel in H2SO4

The corrosion inhibition of austenitic chromium–nickel steel by two Schiff bases, N-(1-toluidine)salicylaldimine and N-(2-hydroxyphenyl)salicylaldimine, was investigated in sulphuric acid medium. The effect of concentration and temperature on inhibition properties was determined. It was found that when the concentrations of inhibitor were increased the inhibition efficiencies () and surface coverage () increased. Some thermodynamic parameters such as free energy of adsorption, G _ads, and enthalpy, H, were determined for the Schiff bases. Experimental results agree with the Temkin isotherm for N-(1-toluidine)salicylaldimine, but the Langmuir isotherm is more appropriate for N-(2-hydroxyphenyl)salicylaldimine.