Proton conducting acid-base mixed materials under water-free condition

In recent years, a lot of attentions have been paid for a development of water-free polymer electrolyte membranes fuel cells (PEMFC) at intermediate temperatures (above 100 °C) because of many technological advantages of higher temperature operation. However, the proton conductivity of conventional polymer membranes under water-free condition is usually very low and the polymeric membranes are not stable at higher temperatures. So, the development of non-hydrous proton conducting membrane under water-free condition has been a state of the art issue in the advanced PEMFC technology. In this study, non-hydrous protonic conducting material was prepared by the mixing of acidic surfactant of mono-dodecylphosphate (MDP) and organic base of benzimidazole (BnIm). The proton conductivity and thermal stability of MDP-BnIm mixed material increased with the mixing ratio of BnIm. Maximum proton conductivity of MDP-BnIm mixed material (BnIm mixing ratio of 200 wt.%. vs. MDP) was found to be 1×10⁻³ S cm⁻¹ at 150 °C under water-free condition.     

凝结水精处理混床铵化运行条件的分析探讨

从树脂离子交换的角度，通过分析计算，给出了凝结水精处理混床铵化运行的基础数据，进而提出了凝结水精处理铵化运行的条件。     

Synthesis of binary mixed homopolymer brushes by combining atom transfer radical polymerization and nitroxide-mediated radical polymerization

This communication describes a novel strategy to synthesize binary mixed homopolymer brushes from mixed self-assembled monolayers (SAMs) on silica substrates by combining atom transfer radical polymerization (ATRP) and nitroxide-mediated radical polymerization (NMRP). Mixed SAMs terminated by ATRP and NMRP initiators were prepared by coadsorption of two corresponding organotrichlorosilanes from toluene solutions. Mixed poly(methyl methacrylate) (PMMA)/polystyrene (PS) brushes were synthesized by ATRP of MMA at 80 °C followed by NMRP of styrene at 115 °C. Corresponding ‘free’ initiators were added into the solutions to control the polymerizations. We have found that the brush thickness increases with molecular weight in a nearly linear fashion. For a series of binary brushes consisting of PMMA of molecular weight of 26,200 and PS of various molecular weights, we have observed a transition in water contact angles with increasing PS molecular weight after CH₂Cl₂ treatment. Moreover, binary mixed polymer brushes with comparable molecular weights for two grafted polymers undergo reorganization in response to environmental changes, exhibiting different wettabilities.     

Positivity and stability of mixed fractional‐order systems with unbounded delays: Necessary and sufficient conditions

This article provides a comprehensive study on quantitative properties of linear mixed fractional‐order systems with multiple time‐varying delays. The delays can be bounded or unbounded. We first obtain a result on existence and uniqueness of solutions to these systems. Then, we prove a necessary and sufficient condition for their positivity. Finally, we provide a necessary and sufficient criterion to characterize asymptotic stability of positive linear mixed fractional‐order systems with multiple time‐varying delays.     

电大尺寸复杂目标散射问题的并行矩量法分析

目前飞机和导弹等电大尺寸复杂目标的电磁散射特性采用高频分析法精度较低,本文研究在PC集群环境下三维导体散射问题矩量法的并行化,并应用于复杂目标的RCS计算。本文使用混合积分方程,再用RWG基函数进行离散,阻抗矩阵元素按行分解,并行共轭梯度法进行求解,通过MPI通信库实现。最后使用基准目标NASA杏仁核验证了该并行计算的准确性。     

一种提取抖动视频中前景目标的新方法

提取视频中的前景目标信息是视频处理领域非常重要的问题,考虑到现实生活中会出现监控摄像头不可避免地会出现晃动或偏移情况,造成监控视频短暂抖动,此时背景图像灰度和纹理信息都会受到较大的影响,从而给后期进一步分析前景信息带来了巨大的困难。为了兼顾纹理特征提取和噪声抑制两方面的要求,针对抖动视频的前景提取问题,提出了一种有效的融合小波变换和在线混合高斯模型的方案。首先运用仿射变换在线逐帧校准,接着利用小波变换对图像去噪,并建立自适应模型迭代上述过程,最后利用在线混合高斯模型提取前景。实验结果表明,与同类方法相比,该算法无论针对单目标还是多目标视频均可以有效去除抖动,得到较好的前景目标提取效果,具有较高的准确性和鲁棒性。     

基于OBE的工程图学混合式教学新体系

突如其来的疫情下“停课不停学”的线上教学,使得以成果导向教育(OBE)为理念的教学存在 特殊性。以《现代工程图学》课程为载体,提出突发事件下 OBE 在线教学应着眼于培养学生的图学素养,融 入计算机实体造型。教学重点集中在整合和挖掘教学资源、依托网络教学平台和加强工程能力培养,教学过程 强调以学生为中心的教学理念、加大多元化过程考核机制,拓宽制图课教学的知识面和受训面。构建了“课内 与课外相结合、线上和线下相结合、理论与实践相结合”的混合式制图教学新体系。并在机自专业制图课程教 学过程中加以实践,适度解决了远程教学中课堂互动性差、实践和测绘教学难以及上机实战少等问题,确保与 线下课程教学质量实质等效,为工程类基础课程教学提供改革思路。     

混有CACC车辆和ACC车辆的混合交通流驾驶舒适性

为了探索协同自适应巡航控制(cooperative adaptive cruise control,CACC)车辆对交通系统的潜在影响,分析了CACC车辆市场普及过程中存在的CACC车辆、自适应巡航控制(adaptive cruise control,ACC)车辆与人工驾驶车辆混合交通流驾驶舒适性.应用加州伯克利PATH实车验证的ACC模型和CACC模型进行数值仿真实验,采用国际ISO-2631-1标准评价混合交通流舒适性,并对ACC和CACC期望车间时距进行参数敏感性分析.最后,从交通流稳定性的角度,对舒适性仿真结果进行了讨论.结果表明:随着CACC市场率的增加,舒适性呈现先恶化、再逐渐提升的趋势.较大的ACC车间时距有利于抑制舒适性的恶化程度,CACC车辆对舒适性的提升作用不受其车间时距取值的影响.混合交通流稳定性定性地决定了舒适性的变化趋势,人工车辆安装车车通信设备,有助于舒适性的逐渐提升.     

复杂事件处理的自适应制造情景识别方法

制造过程中的任务、自然条件、电力水平等环境因素,制约物体状态及其关系的变化.智能制造单元需要自适应的对不同情境约束下的事件和复杂情形及时理解判断,提出基于复杂事件处理(Complex event processing,CEP)的情境约束情景识别方法,以实时作出合理的优化决策.针对忽视情境约束对事件判别的影响,构建基于情境约束的多层次事件模型,给出同生、情境、协同等事件新算子,提出基于事件聚合的制造情景模型与演算过程.针对情景识别知识库中模式规则生成的不足,通过整合物体数据与环境数据建立映射关联,将感知信息转化为情境事件图谱.通过综合序数、名义变量等距离计算和自适应熵权法,提出改进的混合聚类方法处理事件图谱实例属性的多样性和关联性,构建知识库以为情景实时识别提供服务支持.运用4个真实数据集和1个制造过程仿真数据集进行实验,均验证本文模型和方法的有效性,适用于大规模学习问题,并阐明情境因素能显著提升复杂制造应用中的事件判断、情景识别的准确性.     

对混合属性数据表可行的差分隐私保护方法

为加强隐私保护和提高数据可用性,提出一种可对混合属性数据表执行差分隐私的数据保护方法。该方法首先采用ICMD（insensitive clustering for mixed data）聚类算法对数据集进行聚类匿名,然后在此基础上进行
-差分隐私保护。ICMD聚类算法对数据表中的分类属性和数值属性采用不同方法计算距离和质心,并引入全序函数以满足执行差分隐私的要求。通过聚类,实现了将查询敏感度由单条数据向组数据的分化,降低了信息损失和信息披露的风险。最后实验结果表明了该方法的有效性。