Research on Poly （Styrene-Crylicacid）-Suported Neodymium Complex Catalytic Copolymerization of Styrene and 4-Vinylpyridine

Research on Poly(Styrene-Crylicacid)-Suported Neodymium Complex Catalytic Copolymerization of Styrene and 4-Vinylpyridine     

Analysis of a Gyroscope＇s Rotor Nonlinear Supported Magnetic Field Based on the B-Spline Wavelet-FEM

A supported framework of a gyroscope＇s rotor is designed and the B-Spline wavelet finite element model of nonlinear supported magnetic field is worked out. A new finite element space is studied in which the scaling function of the B-spline wavelet is considered as the shape function of a tetrahedton. The magnetic field is spited by an artificial absorbing body which used the condition of field radiating, so the solution is unique. The resolution is improved via the varying gradient of the B-spline function under the condition of unchanging gridding. So there are some advantages in dealing with the focus flux and a high varying gradient result from a nonlinear magnetic field. The result is more practical. Plots of flux and in the space is studied via simulating the supported system model. The results of the study are useful in the research of the supported magnetic system for the gyroscope rotor.     

丙酸正丁酯绿色合成工艺中固体酸催化剂研制

针对目前酯化工艺过程中存在的环境污染问题,以丙酸正丁酯催化合成为例,对酯化过程清洁生产工艺中固体酸催化剂的制备进行了研究.制备了 SO_4~(2-)/TiO_2固体超强酸催化剂,讨论了各种制备条件对该催化剂的丙酸正丁酯合成催化活性的影响,采用 TG/DTA、FTIR、XRD 等仪器分析手段对催化剂结构进行了表征,实验结果表明,SO_4~(2-)/TiO_2固体超强酸催化剂具有很好的催化活性和选择性,且无腐蚀、反应时间短、后处理简单、重复使用性好.     

周期性脉冲流体对滴流床反应器性能的影响

用铜铬催化剂催化的过氧化氢分解反应作为液体限制反应的例子来研究周期性脉冲流体对滴流床反应器性能的影响.初步研究表明:当催化剂非完全润湿时,周期性脉冲流体能够提高反应器的性能;当催化剂完全润湿时,周期性脉冲流体不能提高反应器的性能,甚至还会产生不利影响.     

高浓度煤粉燃烧时炉内结渣的机理分析

在分析煤粉炉结渣过程及其机理的基础上，对高浓度煤粉燃烧时易导致结渣的主要特性进行了探讨，表明还原性气氛的出现和煤粉浓缩时富铁颗粒的富集有导致和促进结渣的作用；提出了一些防止和减轻结渣的必要措施     

添加催化助燃剂降低烧结焦耗的工业试验

为了降低固体燃料消耗和强化烧结，在考虑烧结用焦粉和烧结工艺特点的基础上，制备出适用于焦粉燃烧的催化助燃剂，并在河西堡铁厂进行了添加助燃剂的工业试验。结果表明，在该厂原料和技术条件下，往焦粉中添加0．137％(按焦粉的质量百分数，下同)左右的催化助燃剂，可节焦8．06％，烧结机利用系数增加3．63％，成品率提高3．44个百分点，烧结矿的质量略有改善。     

Mineralogy of clean coal combustion by-products

Coal combustion technologies are changing in order to burn coal more cleanly. Many “clean combustion“ and postcombustion technologies are developed to remove SO2 and NOx gases, particulate matter during combustion, or from the flue gases leaving the furnace. This paper focuses on three types of fly ash (flue gas desulfurization (FGD) residuals, atmospheric fluidized bed combustion (AFBC) residuals and sorbent duct injection (SDI) residuals) which produced by “the clean combustion“ and postcombustion technologies. The residuals formed by FGD are PCFA (pulverized coal fly ash) grains entrained with reacted and unreacted sorbent and have lower bulk densities than PCFA grains because it contains higher concentrations of calcium and sulfur, and lower concentrations of silicon, aluminum and iron than PCFAs. AFBC residuals consist of spent bed which is a heterogeneous mixture of coarse-grained bed material and irregularly shaped, unfused, spherical PCFAs. The main crystalline phases in AFBC residuals are anhydrite (reacted sorbent), quartz and lime (unreacted sobent), calcite, hematite, periclase, magnetite and feldspars.The residuals produced by SDI contained 65%-70% PCFA with the larger sizes material being irregularly shaped, fused or roughedged. The reaction products of sorbent (portlandite and lime) included calcium sulfate (anhydrite) and calcium sulfate. The chemical properties of these residuals are similar to those of high calcium PCFAs because of the high alkalinity and high pH of these residuals.     

高效空气电极的制备

空气极是整个空气电池中的关键所在，空气极的性能受着防水层的性能、催化层的性能、制备工艺等多种因素的影响．本实验对比了不同含量的聚四氟乙烯、活性碳颗粒等做成的防水层的特性及不同的催化剂(银粉、La-Ca-Co-O等催化剂)做成的催化层的特性．用电化学工作站研究了空气电极的析氧和氧还原特性，认为用碳酸氢铵为造孔剂、用银粉做催化剂的空气电极效果最好．     

铁固体超强酸催化剂的改性及结构特征

用沉淀法在一定条件下制备了由硫酸根促进的以氧化铁为主要活性组分的铁固体超强酸催化剂 ,并选择了氧化镧与氧化锆作为辅助金属氧化物添加剂进行了改性。用红外光谱测定了其分子结构 ,用流动气相色谱法测定了催化剂的比表面积和孔径结构。结果表明 ,铁固体超强酸催化剂的酸强度H0 ≤ - 1 4 5 2 ,比表面积为 1 2 4 8m2 ·g- 1 ,孔径集中在 1 0～ 2 0nm ,分子为桥式双配位结构。经改性后的催化剂用于乙酸丁酯的合成反应 ,有较高的催化活性和使用寿命。     

Attending to the Omissions: A Historical Examination of Evidence-Based Practice Movements.

Evidence-based practice and empirically supported treatment movements are potent forces that affect the practice of psychology today and have the potential to mandate the types of treatments psychologists conduct. The histories of these movements reveal that certain aspects of therapy valued by psychologists have been ignored. It is shown that the evidence-based movements (a) overemphasize treatments and treatment differences and (b) ignore aspects of psychotherapy that have been shown to be related to outcome, such as variation among psychologists, the relationship, and other common factors. It is important that psychologists understand the development of these movements so that they can be critical consumers of research and can effectively influence the future course of events. (PsycINFO Database Record (c) 2010 APA, all rights reserved)