全文获取类型
收费全文 | 149篇 |
免费 | 33篇 |
国内免费 | 2篇 |
专业分类
综合类 | 9篇 |
化学工业 | 58篇 |
金属工艺 | 15篇 |
机械仪表 | 1篇 |
建筑科学 | 1篇 |
矿业工程 | 28篇 |
轻工业 | 6篇 |
无线电 | 3篇 |
一般工业技术 | 4篇 |
冶金工业 | 55篇 |
自动化技术 | 4篇 |
出版年
2024年 | 2篇 |
2023年 | 6篇 |
2022年 | 4篇 |
2021年 | 8篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 11篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 5篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 3篇 |
2011年 | 11篇 |
2010年 | 2篇 |
2009年 | 9篇 |
2008年 | 4篇 |
2007年 | 5篇 |
2006年 | 5篇 |
2005年 | 12篇 |
2004年 | 7篇 |
2003年 | 6篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 7篇 |
1999年 | 7篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1982年 | 1篇 |
排序方式: 共有184条查询结果,搜索用时 296 毫秒
1.
2.
Max Y. Zhang George J. Dugbartey Smriti Juriasingani Alp Sener 《International journal of molecular sciences》2021,22(12)
Thiosulfate in the form of sodium thiosulfate (STS) is a major oxidation product of hydrogen sulfide (H2S), an endogenous signaling molecule and the third member of the gasotransmitter family. STS is currently used in the clinical treatment of acute cyanide poisoning, cisplatin toxicities in cancer therapy, and calciphylaxis in dialysis patients. Burgeoning evidence show that STS has antioxidant and anti-inflammatory properties, making it a potential therapeutic candidate molecule that can target multiple molecular pathways in various diseases and drug-induced toxicities. This review discusses the biochemical and molecular pathways in the generation of STS from H2S, its clinical usefulness, and potential clinical applications, as well as the molecular mechanisms underlying these clinical applications and a future perspective in kidney transplantation. 相似文献
3.
The pitting behaviour of type 321 stainless steel in sulfide-containing chloride aqueous environments was studied using cyclic potentiodynamic polarization. A well-established correlation between H2S and Na2S2O3 in the study of corrosion was applied, that is, H2S was simulated by Na2S2O3. The major factors affecting the pitting corrosion of type 321 stainless steel are the Cl- concentration, solution pH and temperature. The results clearly indicate that both Epit and E
pp decrease with increasing Cl- concentration and temperature, while I
pass is more sensitive to temperature variation. E
pit decreased with decreasing pH in the range 2 < pH < 7.5. The surface morphology and chemistry of the corroded type 321 stainless steel resulting from anodic polarization in 0.01 M S2O
3
2-
-containing Cl- solution were analysed by XRD, SEM and EPMA. A higher concentration of sulfur was found in the pits, and the dark surface film was mainly composed of FeS and -Fe2O3. The results describe the pitting behaviour of type 321 stainless steel in sulfide-containing Cl- aqueous environments. 相似文献
4.
滴定分析法测定铜的改进 总被引:1,自引:0,他引:1
提出在NH4HF2介质中,有SCNˉ存在下,以Iˉ3—淀粉为指示剂,硫代硫酸钠滴定铜的分析方法 相似文献
5.
硫代硫酸钠合成条件的优化 总被引:6,自引:0,他引:6
优化了亚硫酸钠与硫磺反应制备硫代硫酸钠的合成条件,最佳反应条件为:亚硫酸钠与硫磺质量比为7:2,亚硫酸钠与水质量比为1:1,溶液pH=10,反应时间30min,此时亚硫酸钠转化率为95.9%,产品纯度98.9%,收率94.5%。 相似文献
6.
Thiosulfate has been considered as one of the most promising of the non-toxic alternatives to cyanide for the leaching of gold and much work has been carried out with the aim of understanding and improving the ammoniacal thiosulfate leaching process. In particular the behaviour of gold in thiosulfate solutions containing copper in the absence of ammonia has received little attention. It has been shown in this study involving electrochemical and leaching tests that copper ions catalyze not only the oxidation of thiosulfate but also the dissolution of gold in alkaline thiosulfate solutions. Electrochemical studies have shown that copper has a positive effect on the anodic dissolution of gold with increasing concentrations of copper resulting in higher dissolution rates of gold at a potential of 0.3V. Studies on the dissolution of gold powder in alkaline oxygenated thiosulfate solutions containing low concentrations of copper have shown that the role of copper in enhancing the dissolution rate of gold is possibly associated with the formation of a copper–thiosulfate–oxygen intermediate which is more reactive in terms of cathodic reduction than dissolved oxygen. The electrochemical experiments have been complemented by a leaching study which has shown that milling of gold powder in the presence of copper (added as ions, metal, or oxide) assists with the dissolution of gold in thiosulfate solutions. 相似文献
7.
1 INTRODUCTIONCyanidationprocess ,characterizedbyeffectivenessandlowoperatingcost,asaconventionaltechnologyforgoldextractionfromores ,hasbeenusedinindustryforover 10 0years .Howeverthecyanideisahighlytoxicchemical,andcommercialcyanidationprocessislimitedint… 相似文献
8.
采用密度泛函理论B3LYP法及自恰等密度PCM模型,在6-311G(d)基组条件中研究环氧乙烷在保险粉生产中参加的主要反应,系统论证环氧乙烷的去向.本文首先分析环氧乙烷于控制硫代硫酸钠含量的热力学、动力学基础及体系中各亲核试剂的反应活性,然后分析环氧乙烷各主要反应的比例关系.理论计算结果与实验结论一致,即硫代硫酸钠消耗的环氧乙烷最多(71.5%),其次是水(17.5%),甲醇(5.0%),亚硫酸氢钠(1.3%). 相似文献
9.
硫代硫酸盐在提金领域的应用进展 总被引:4,自引:0,他引:4
从硫代硫酸盐提金法的研究历史、浸金的基本原理和从溶液中回收金的方法及存在的问题等方面综述了硫代硫酸盐在提金领域的应用进展。 相似文献
10.