全文获取类型
收费全文 | 14209篇 |
免费 | 1120篇 |
国内免费 | 1284篇 |
专业分类
电工技术 | 1367篇 |
综合类 | 892篇 |
化学工业 | 5489篇 |
金属工艺 | 271篇 |
机械仪表 | 331篇 |
建筑科学 | 1450篇 |
矿业工程 | 107篇 |
能源动力 | 1156篇 |
轻工业 | 284篇 |
水利工程 | 226篇 |
石油天然气 | 991篇 |
武器工业 | 20篇 |
无线电 | 103篇 |
一般工业技术 | 541篇 |
冶金工业 | 202篇 |
原子能技术 | 2866篇 |
自动化技术 | 317篇 |
出版年
2024年 | 17篇 |
2023年 | 120篇 |
2022年 | 259篇 |
2021年 | 367篇 |
2020年 | 414篇 |
2019年 | 388篇 |
2018年 | 364篇 |
2017年 | 458篇 |
2016年 | 511篇 |
2015年 | 440篇 |
2014年 | 817篇 |
2013年 | 1410篇 |
2012年 | 853篇 |
2011年 | 1028篇 |
2010年 | 833篇 |
2009年 | 843篇 |
2008年 | 758篇 |
2007年 | 865篇 |
2006年 | 767篇 |
2005年 | 719篇 |
2004年 | 584篇 |
2003年 | 583篇 |
2002年 | 480篇 |
2001年 | 450篇 |
2000年 | 328篇 |
1999年 | 331篇 |
1998年 | 251篇 |
1997年 | 197篇 |
1996年 | 178篇 |
1995年 | 167篇 |
1994年 | 136篇 |
1993年 | 117篇 |
1992年 | 81篇 |
1991年 | 107篇 |
1990年 | 83篇 |
1989年 | 66篇 |
1988年 | 36篇 |
1987年 | 55篇 |
1986年 | 31篇 |
1985年 | 31篇 |
1984年 | 17篇 |
1983年 | 12篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1979年 | 1篇 |
1975年 | 1篇 |
1959年 | 32篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
21.
光氯化制备对氯三氯甲苯的工艺条件研究 总被引:1,自引:0,他引:1
赵培新 《南京工业职业技术学院学报》2003,3(3):34-37
本研究了在内环流反应器中,以对氯甲苯为原料制备对氯三氯甲苯的新工艺,考察了不同氯气流量、不同氯化温度对对氯甲苯侧链光氯化反应的影响,得出了对氯甲苯的侧链光氯化反应规律。结合正交试验,得出了对氯甲苯侧链光氯化制备对氯三氯甲苯的较优工艺条件。 相似文献
22.
核电材料在模拟反应堆环境中应力腐蚀破裂测试技术与性能评价 总被引:1,自引:0,他引:1
杨武 《理化检验(物理分册)》1996,32(5):7-12
简要介绍了采用慢应变速率试验,U型弯曲和C形环试验等技术,分别对800合金,304和316及316Ti不锈钢A533B压力容器用多在模拟核反应堆环境中的应力腐蚀破裂敏感性性进行的试验研究的一些主要结果;并结合电化学测试和表面膜俄歇电子能谱分析结果进行了讨论。 相似文献
23.
In order to enhance product yields in selective oxidation reactions, numerous reaction engineering concepts are being studied worldwide. Periodic operation has been investigated for decades, yet its application is limited to a few examples, such as the butane oxidation after DuPont or reverse-flow reactors for VOC removal. The use of microchannel reactors is a younger field, but it has already yielded promising results for process optimization. Catalytic wall reactors have proved to be a helpful tool for kinetic studies. On the laboratory scale, membrane reactors have displayed favorable behavior in selective oxidation. The Na vapor-catalyzed dehydrogenation of methanol to formaldehyde is a final example of an unusual new concept for selective oxidation. 相似文献
25.
Two different Ti/Pt–Ir materials (commercial and home made) and Ti/PdO + Co3O4 were investigated for their electrocatalytic properties versus Cl2 evolution reaction. The materials were used in a batch electrochemical reactor to treat biologically recalcitrant di-azo compound. An electrochemically driven oxidation, mediated by a Cl2/Cl− couple, proved efficient for destruction of this complex organic molecule, causing cleavage of the conjugated double bonds and destruction of unsatured bonds. Both Ti/Pt–Ir materials performed well; lower kinetics obtained with the Ti/PdO + Co3O4 anode was caused by adsorption of the model compound, evidenced in preliminary voltammetric measurements. The dye oxidation reaction followed the second order kinetics with partial orders in the model compound and (time varying) chlorine concentrations equal to one. Specific energy consumption of 3.12 kWh m−3 proved the process more economic than the homogeneous phase oxidation. 相似文献
26.
针对壁体材料多样、结构复杂的高耸建筑物的爆破拆除,通过实验研究确定了爆破切口形式,运用力学理论推导了余留支撑体所对应的圆心角和爆破切口高度计算公式,并在工程实践中得到验证.对爆破拆除类似建筑物具有较大的实用价值. 相似文献
27.
Ana MRB Xavier Ana Paula M Tavares Margarida SM Agapito Dmitry V Evtuguin 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(12):1602-1608
BACKGROUND: A sequential batch reactor (SBR) was used for eucalypt kraft pulp effluent treatment with Trametes versicolor. A 23 full factorial design and response surface methodology were applied to optimise the batch fermentation conditions. Effluent concentration, culture medium and inoculum age were the factors selected for this study in order to optimise the reduction of chemical oxygen demand (COD). RESULTS: The presence of Trametes Defined Medium (TDM) in the fermentation was required to obtain a significant COD reduction. Experiments in the batch reactor confirmed, in general, the predicted results of optimisation developed from Erlenmeyer batch assays. The T. versicolor culture remained active during 42 days of study in the SBR, providing approximately 80% of COD reduction. CONCLUSION: Trametes versicolor may be considered as very promising for the biological treatment of effluents from kraft pulp mills in an SBR system instead of the activated sludge mixed cultures traditionally used. Copyright © 2008 Society of Chemical Industry 相似文献
28.
29.
Ricardo Beristain‐Cardoso Anne‐Claire Texier Reyes Sierra‐Álvarez Jim A Field Elías Razo‐Flores Jorge Gómez 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(9):1197-1203
BACKGROUND: Simultaneous removal of sulfur, nitrogen and carbon compounds from wastewaters is a commercially important biological process. The objective was to evaluate the influence of the CH3COO?/NO3? molar ratio on the sulfide oxidation process using an inverse fluidized bed reactor (IFBR). RESULTS: Three molar ratios of CH3COO?/NO3? (0.85, 0.72 and 0.62) with a constant S2?/NO3? molar ratio of 0.13 were evaluated. At a CH3COO?/NO3? molar ratio of 0.85, the nitrate, acetate and sulfide removal efficiencies were approximately 100%. The N2 yield (g N2 g?1 NO3?‐N consumed) was 0.81. Acetate was mineralized, resulting in a yield of 0.65 g inorganic‐C g?1 CH3COO?‐C consumed. Sulfide was partially oxidized to S0, and 71% of the S2? consumed was recovered as elemental sulfur by a settler installed in the IFBR. At a CH3COO?/NO3? molar ratio of 0.72, the efficiencies of nitrate, acetate and sulfide consumption were of 100%, with N2 and inorganic‐C yields of 0.84 and 0.69, respectively. The sulfide was recovered as sulfate instead of S0, with a yield of 0.92 g SO42?‐S g?1 S2? consumed. CONCLUSIONS: The CH3COO?/NO3? molar ratio was shown to be an important parameter that can be used to control the fate of sulfide oxidation to either S0 or sulfate. In this study, the potential of denitrification for the simultaneous removal of organic matter, sulfide and nitrate from wastewaters was demonstrated, obtaining CO2, S0 and N2 as the major end products. Copyright © 2008 Society of Chemical Industry 相似文献
30.
反应器和钢烟囱整体吊装的难点和对策 总被引:1,自引:0,他引:1
介绍了在金陵石化炼油厂200万t/a柴油加氢装置建设中,将质量为237t的反应器和高60m的钢烟囱成功进行整体吊装过程中的关键技术.通过此项工程实践得出以下结论象钢烟囱这样细长重物的整体吊装,由两台吊车抬立起后,再由主吊车独立吊装就位的施工方法简单易行,安全可靠,应用范围广;结构复杂细长杆的吊装强度和挠度计算比较复杂,在计算过程中可以忽略部分次要件的质量,分别以两吊点为支点计算上下吊点所受的力,然后再按比例放余量,使两吊点受力之和等于细长杆的重力,计算挠度时,可以适当地把问题夸大化,从而建立近似的力学模型;高压厚壁重型容器的吊装,宜直接设置专门吊盖与大法兰用螺栓把紧起吊;施工现场地基坚实是保证吊车站位和吊装施工的前提条件. 相似文献