新型可控电抗器大幅度限制操作过电压功能的研究

通过数值计算和模拟研究,本文叙述了新型可控电抗器的广泛的无功调节功能,揭示了它所具有的大幅度限压的能力,并在理想数学模型的基础上分析了电抗器的限压机理。     

含腐蚀凹坑尿素合成塔的安全评定与分析

对尿素合成塔上封头腐蚀凹坑采用中国SAPV-95和美国API579规范分别进行安全评定，给出安全裕度，简略分析安全评定的结果。     

广西洛东水电厂增机扩容可行性设计

通过对洛东水电厂的来水量、地质和经济指标等技术资料的分析,认为采用灯泡贯流式机组扩大其装机的容量是可行的。并介绍了洛东水电厂增机扩容的可行性设计情况。     

Reactor modelling for electrochemical processes

This paper presents a relatively straightforward approach to the modelling of electrochemical reactors operated in batch or continuous modes. The models are based on ideal flow assumptions of either well-mixed or plug flow and incorporate reaction rate models based on electrochemical kinetics and mass transport at one electrode. General characteristics of the reactor models are described, particularly with regard to the need for good mass transport in metal recovery applications. An example is given on the use of the model in the recovery of a heavy metal (Cd²⁺) from an acidified solution containing Cd(II) and Fe(III) ions. The reaction rate model is based on experimental data.     

Effect of H2O2 addition mode on enzymatic removal of phenol from wastewater in the presence of polyethylene glycol

The effect of batch and semi-batch additions of the stoichiometric amount of H₂O₂ on enzymatic removal of phenol has been studied over the phenol concentration range of 1-10 mmol/L. It is found that the ratio between the maximum H₂O₂ concentration during the reaction and the initial horseradish peroxidase concentration ((H₂O₂)_max/(HRP)_o) controls the rate of phenol removal by horseradish peroxidase in the presence of the additive, polyethylene glycol. An optimum range of this ratio is determined to be between 10 and 25 μmol/U. Empirical models are proposed to predict the values of (H₂O₂)_max/(HRP)_o required to treat given phenol concentrations under different modes for adding H₂O₂.     

乳液聚合螺旋半园管夹套反应釜

本文将螺旋半园管夹套反应釜与传统的夹套反应釜进行了对比 ,并介绍了螺旋半园管夹套釜在乳液聚合中的应用     

反应器网络综合优化方法的研究进展

反应器网络综合优化方法在选择反应器类型和反应工艺条件时,比传统的方法表现出了很大的优势。综述了各类反应器网络综合优化方法的基本原理和研究进展,并分析了它们的优缺点。这些方法有基于过程特征的方法,包括可得区法和导数分析法;超结构优化法;目标类方法,包括目标法、构造目标法和构造MINLP法;以及经验推断法和分布参数法等。最后分析了这方面研究的发展趋势。     

薄管板换热器的设计及薄管板计算的探讨

结合化肥厂丁辛醇装置薄管板换热器的设计 ,着重分析薄管板的特点 ,应用合理的计算方法对薄管板进行强度校核 ,验证这一新型换热器的安全性和经济实用性     

Modeling the continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor

A model of continuous melt transesterification of bisphenol-A and diphenyl carbonate in a continuous stirred tank reactor is developed using phase equilibria assumption and the method of molecular weight moments. The model equations can be simplified into a polynomial system that has 17 equations and 17 unknowns. Solution of the polynomial system gives out almost every aspects of the continuous transesterification process. Molecular weight and polydispersity index, end group ratio of hydroxyl to phenyl carbonate, contents of molecular species, and lost diphenyl carbonate fractions are studied in different operation parameters.     

Optimization of anodic oxidation and Cu–Cr oxide catalyst preparation on structured aluminum plates processed by electro discharge machining

This paper describes the optimization of three processes applied in fabrication of a microstructured reactor for complete oxidation of volatile organic compounds. The first process involves the optimization of the electro discharge machining (EDM) method to produce a set of microchannels with a high length to diameter ratio of 100, with a standard deviation from the average diameter below 0.2%, and with a surface roughness not higher than 2.0 μm. To satisfy these criteria, fabrication of microchannels must be carried out with two machining passes in the Al51st alloy. Then, the effect of several parameters on the anodization current efficiency with respect to oxide formation was studied. The best process conditions to get a 30 μm porous alumina layer in a 0.4 M oxalic acid electrolyte, were found to be a temperature of 1 °C, an anodic current density of 5 mA/cm², and 23 h oxidation time. At last, the resulting coatings were impregnated with an aqueous solution of copper dichromate followed by drying and calcination at 450 °C to produce active catalysts. The effect of a copper dichromate concentration, number of impregnation cycles (1 or 2), and different after-treatments on catalytic activity and stability in complete oxidation of n-butane were studied. The catalytic activity of the obtained coatings is superior to that of alumina supported pelletized catalysts even at much lower loadings of active metals.