Induction plasma spheroidization of tungsten and molybdenum powders

The melting, evaporation and oxidation behaviors as well as the solidification phenomena of tungsten and molybdenum in induction plasma were studied. Scanning electron microscopy was used to examine the morphology and the cross section of plasma-processed powders. X-ray diffraction was used to analyze the oxides formed on the particle surface of these two metals. The influence of spray chamber pressure on the spheroidization and oxidation phenomena was discussed. The results show that fewer Mo particles than W particles are spheroidized at the same powder feed rate under the same plasma spray condition although molybdenum has a lower melting point. A small fraction of tungsten is evaporized and condensed either on the surface of tungsten particles nearby or on the wall of spray chamber. Tungsten oxides were found in tungsten powder processed under soft vacuum condition. Extremely large grains form inside some spheroidized particles of tungsten powder.     

A novel binder and binder extraction method for powder injection molding of tungsten cemented carbide

1　INTRODUCTIONPowderinjectionmolding (PIM ) ,whichisde rivedfromplasticinjectionmolding ,isakindofnet shapepowdermetallurgyformingprocess[13] .Com bininghigh partcomplexitywithhigh productionquantities ,itsupplementstheestablishedprocesseslikediecompaction ,machiningandinvestmentcasting[4 6 ] .Comparingtoconventionalpressing/sinteringprocess,thePIMhasgreattechniqueandcostadvantagesforthepro ductionofcementedcarbidecomponentswithcomplexshapes[7,8] .Sincehydraulicpressureisappliedduringi…     

含碳球团—铁浴熔融还原法关键技术的应用基础研究

系统研究了以非焦煤粉和铁精矿粉为基础的含碳球团－铁浴熔融还原新流程的关键技术。解决了冷固结含碳球团高温强度问题，提出了含碳球团自还原动力学模型，再氧化机理和提高球团预还原速度，抗氧公有力的技术措施和参数，研制出了具有高配碳量，高强度，高自还原速度，高预还原速度，高抗氧化能力的新型含碳球团。同时，研究了含碳球团在铁浴中熔化还原动力学参数，优化得到了控制还原速度，终还原率，熔渣中最低ＦｅＯ含量，泡沫渣     

钨板轧制的轧制力模型研究

为了使钨板轧制过程中的各项轧制参数得到有效控制，对钨板轧制数学模型进行了研究。首先在Gleeble热模拟机上进行热压缩试验，研究了变形抗力与各种变形条件的关系，确定了变形抗力模型：通过550mm轧机轧制钨板时采集到的有关数据，建立了应力状态影响系数数学模型、变形区长度等模型：最终建立了550mm钨板轧机轧制力模型。利用模型计算值与实际测量参数进行了对比，结果比较满意。     

AZ31镁合金钨极交流氩弧焊焊缝气孔的研究

采用金相显微镜和扫描电镜对AZ31镁合金薄板在钨极交流氩弧焊时产生的气孔进行了研究,分析了气孔的形成原因,并提出了焊缝气孔的防止措施.试验结果表明:焊前彻底清除母材坡口、表面和焊丝表面的油污及氧化膜,采用较大的焊接电流和较高的焊接速度,选用合适的氩气流量,焊前预热等措施都能有效地防止焊缝中气孔的产生.     

钨合金的磨削加工去除机理

目的 解决钨合金磨削加工去除机理不明晰的问题。方法 基于单磨粒刻划有限元仿真、单磨粒刻划和磨削加工实验，探究钨合金的磨削加工去除机理。结果 在刻划过程中，划痕的不同位置材料的去除特性存在显著差异。在单颗粒刻划切入端，材料依次发生了塑性变形、隆起、微裂纹，再到钨相与黏结相的混杂交融。在划痕中段以材料去除为主，出现了材料微卷起和材料卷起现象，沿着刻划方向卷起现象越来越严重。在划痕切出端，划痕边缘和尾部均出现了“飞边”现象，且相较于切入端，切出端的形貌较差，实验与仿真吻合。此外，在不同相位处，材料的去除特性也存在一定不同。在钨相区域，同时存在脆性特征和塑性特征。在黏结相区域，刻划深度较浅时主要呈现塑性变形、塑性流动等特征，刻划中端深度较大时主要呈现与钨相的混杂和交融。在钨相与黏结相的相界处，相邻钨颗粒呈现不同的损伤或去除特征，且相界会阻断特征形貌的传递。最后，磨削后的钨合金表面存在单颗粒刻划痕上出现的所有去除特征，与单颗粒划痕的去除特征吻合。不同的是，磨削后划痕底部出现了区域性和放射状的裂纹。结论 钨合金的两相特性使得磨削表面的去除特征较复杂，存在塑性变形、微裂纹、微卷起、卷起、裂纹和两相交...     

Effects of distance between arc and heat sink on stress and distortion in DC-LSND welding technology

The characteristics of temperatures, stresses and strains fields have been studied numerically for a titanium alloy sheet welded with an improved gas tungsten arc welding method, in which a trailing spot heat sink is introduced to control the welding stress and distortion. The impinging jet model is employed to describe the internee heat transfer between the cooling media and the top suufuce of the workpiece. The influcnee of the distance between arc and heat sink is investigated. Results show that there is an ideal range of distance. Using the ideal distance, a low stress and no distortion welding structure can be derived.     

THERMODYNAMIC AND STRUCTURAL CHEMISTRY DISCUSSIONS FOR OXIDATIVE LEACHING OF Cu－Ni SULPHIDE ORE UNDER ATMOSPHERIC PRESSURE

ＴＨＥＲＭＯＤＹＮＡＭＩＣＡＮＤＳＴＲＵＣＴＵＲＡＬＣＨＥＭＩＳＴＲＹＤＩＳＣＵＳＳＩＯＮＳＦＯＲＯＸＩＤＡＴＩＶＥＬＥＡＣＨＩＮＧＯＦＣｕ－ＮｉＳＵＬＰＨＩＤＥＯＲＥＵＮＤＥＲＡＴＭＯＳＰＨＥＲＩＣＰＲＥＳＳＵＲＥ￥Ｗｕ，Ｗｅｎｊｉａｎ（Ｄｅｐａｒ...     

Molybdenum and tungsten coatings for x- ray targets obtained through the low-pressure plasma spraying process

Low-pressure plasma spraying under an argon atmosphere was employed to deposit molybdenum and tungsten coatings on different metallic, ceramic, and composite substrates. Molybdenum coatings ob-tained through this technique presented a homogeneous structure with an average porosity of about 17 %. These coatings exhibited adhesion greater than 40 MPa on molybdenum and grey cast iron (FT25) substrates. No adhesion was observed on an A1N surface regardless of the preheating temperature and/or surface preparation. Adhesion on AIN-Mo (AM25) composite substrate, containing 25 % dispersed metal-lic phase by volume, showed intermediate results. Tungsten coatings exhibited porosity between 10 to 12% and a typical lamellar structure. The adhesion of tungsten coatings on molybdenum and FT25 sub-strates was around 40 MPa.     

微/纳米氧化钨晶须的制备工艺及原理

采用溶胶-水热反应法，通过添加适量的硫化钠结晶体诱导制备了微／纳米氧化钨晶须。利用扫描电镜观察氧化钨样品的形貌特征，并对氧化钨晶须进行能谱测试，用X射线衍射仪对氧化钨样品进行物相分析和晶面测定，用透射电镜观察微／纳米氧化钨晶须／线的生长特征。结果表明：未添加硫酸钠时，在180℃水热反应12～36h只能得到氧化钨颗粒粉末，而添加适量硫化钠后，可制备出直径为0．2～0．3μm、长径比为5～50的氧化钨晶须和直径为10～30nm、长径比为50～200的氧化钨纳米线；氧化钨纳米线晶体结构良好，物相为六方晶系WO3；微／纳米氧化钨晶须／线主要沿〈200〉，〈002〉，〈202〉和〈100〉方向定向生长。