炼钢厂系统的运行原则与调控策略

炼钢厂系统是钢铁制造过程系统的一个重要子系统，其制造过程的复杂性、过程控制的艰巨性是钢铁制造过程多维物质流管制最集中的体现. 炼钢区段的优化与控制是钢铁制造过程系统运行控制的关键. 在总结以往炼钢厂物质流管制研究工作的基础上，从理性角度对炼钢厂系统的运行与控制进行探索，归纳出炼钢厂系统运行优化的逻辑与实现关系，并对转炉炼钢厂系统调控策略进行补充，阐述了炼钢系厂统运行优化的层次与指导策略.     

Molybdenum Oxycarbide and Tungsten Oxycarbide Coatings on Silicon Carbide Fibers

The strength and toughness of fibrous composites depend on the interface properties which control the bonding between the fibers and matrices. One method of controlling the interface involves coating the fiber with an appropriate material. In a previous study, it was found that there is a definite advantage in using low coating temperatures to prevent fibers from degrading. We therefore were interested in a report that Mo₂C could be deposited from Mo(CO)₆ at temperatures as low as 300° to 475°C. Our studies indicated that the material was not Mo₂C, but an oxycarbide, which, with an analogous tungsten oxycarbide coating, was applied to SiC yarns. Both oxycarbides could be converted to the metals by heat-treating in N₂.     

粤北某市"土法炼砷"土壤中化学砷污染的研究

粤北某市“土法炼砷”造成的砷污染,严重破坏了当地生态环境,而且砷还会进入河流或地下水,严重威胁了当地及北江下游的饮用水安全和生态安全。本文对“土法炼砷”遗址现场进行调查取样,并对砷污染的特点进行了分析。     

碳化钨催化剂上烷烃异构化研究进展

综述了用于长链烷烃异构化的碳化钨催化剂的研究进展。介绍了催化剂的制备方法和异构化反应机理。分析了此类催化剂今后的发展趋向和应用前景。     

The role of the WO x ad-component to Pt and PtRu catalysts in the electrochemical CH3OH oxidation reaction

High surface area carbon-supported platinum-based catalysts, Pt/C, PtWO _x /C, PtRu/C and PtRuWO _x /C, were prepared via a chemical reduction route using single metal precursor salts. The catalyst particles were found to be in the nanoscale range, and the addition of Ru clearly decreased the particle size. The Ru was found to be partially incorporated into the face centered cubic lattice of Pt and to form a single Ru catalyst component. X-ray diffraction and X-ray photon spectroscopy did not provide evidence for electronic interactions between WO _x and Pt as well as WO _x and Ru. However, the addition of tungsten to the PtRuWO _x /C catalyst resulted in a high degree of catalyst particle agglomeration. Both Ru containing catalysts showed significantly higher activities for the CH₃OH oxidation reaction in terms of Pt + Ru mass as well as electroactive Pt + Ru surface area than the Pt/C and PtWO _x /C catalysts. The addition of tungsten appeared to mainly result in some ‘physical’ modification of the catalytically active Pt and Ru surface components such as differences in electroactive surface area rather than promotion of the CH₃OH oxidation reaction via a true catalytic mechanism.     

In Situ Synthesis and Microstructures of Tungsten Carbide-Nanoparticle-Reinforced Silicon Nitride-Matrix Composites

A W₂C-nanoparticle-reinforced Si₃N₄-matrix composite was fabricated by sintering porous Si₃N₄ that had been infiltrated with a tungsten solution. During the sintering procedure, nanometer-sized W₂C particles grew in situ from the reaction between the tungsten and carbon sources considered to originate mainly from residual binder. The W₂C particles resided in the grain-boundary junctions of the Si₃N₄, had an average diameter of ∼60 nm, and were polyhedral in shape. Because the residual carbon, which normally would obstruct sintering, reacted with the tungsten to form W₂C particles in the composite, the sinterability of the Si₃N₄ was improved, and a W₂C–Si₃N₄ composite with almost full density was obtained. The flexural strength of the W₂C–Si₃N₄ composite was 1212 MPa, ∼34% higher than that of standard sintered Si₃N₄.     

重防腐涂料在冶金行业的应用

阐述了涂料的防腐蚀机理，并结合冶金企业设备防腐蚀应用实例，介绍了两种新型防腐蚀涂料。     

Pore structure of bulk tungsten carbide powder catalysts

Bulk tungsten carbide catalysts are prepared by direct carburization/reduction of tungsten trioxide in methane-hydrogen mixtures. The catalytic properties of such catalysts have been studied by several authors. The porous structure of these catalysts is studied by adsorption of N₂, Kr, CF₄ and neohexane. Adsorption isotherms and hysteresis loops for the catalysts suggest the presence of a microporous structure made of parallel plates distant approximately by 20 Å. These results are compared to those obtained using such catalysts for hydrogen oxidation and where condensation in the porous structure was observed.     

纯钨MIM黏结剂的优化及其流变性能

为了获得适合纯钨注射成形的黏结剂,通过热力学计算和喂料的流变实验,系统地研究了黏结剂组元的相容性和不同配方的蜡基黏结剂的流变性能,分析了多种因素对喂料黏度的影响,综合评价了不同黏结剂构成的喂料的流变性能,并对喂料进行了SEM观察,结果表明：所选用的黏结剂体系中各组元之间有很好的相容性,当PW与其他组元的质量比大于4时,表现为热力学相容性;由60%PW-10%HDPE-12%PS-13%PP-5%SA组成的黏结剂的流变性能最好,其综合模塑性指数为7.07 m2/N.s.K,SEM结果显示其喂料相当均匀.     

江西浒坑钨矿含矿韧性剪切带及其^40Ar-^39Ar年代学约束

江西省浒坑钨矿是一个大型石英脉黑钨矿矿床,含矿石英脉除了块状石英脉以外,还大量发育条带状石英脉。本文针对条带状石英脉进行了专门研究,认为条带状石英脉实质上是韧性剪切带,以透入性发育的剪切面理和拉伸线理、剪切透镜体、剪切分异条带普遍发育为特色。剪切带岩石以石英质糜棱岩为主,具有丰富的塑性变形显微构造特征。显微剪切指向构造统计表明,东西向和北西向脉组的运动方式均以左旋正滑为主,近水平脉组则以正滑为主。北西向韧性剪切带的新生绢云母^40Ar-^39Ar坪年龄为140．3±1．0Ma,相应的等时线年龄为139．6±2．4Ma;而东西向韧性剪切带绢云母^40Ar-^39Ar坪年龄则比较复杂,高温阶段年龄可能受到成矿期白云母残斑的影响,中温阶段的表观年龄和总气体年龄更接近前一样品的坪年龄。据此认为韧性剪切变形的年龄为140Ma左右,韧性变形发生在成岩和成矿之后。条带状石英脉系块状石英脉韧性剪切改造而成,推测其形成主要与晚期补充岩体的斜向上侵作用有关,但更为合理的模式需要更多资料的进一步证实。