Development of sealing compositions with nanostructure iron-based fillers

The possibility of utilizing nanopowders of iron and Fe-Co-Ni produced bu a thermochemical method in the fabrication of sealing composition materials is investigated. It is established that such hermetic sealing composition materials function reliably under extremal conditions and guarantee elevated strength of adhesion to the surface of the metal and high corrosion and temperature stability. __________ Translated from Poroshkaya Metallurgiya, Nos. 3–4(448), pp. 112–117, March–April, 2006.     

Synthesis and characterisation of a submicrometre silicon carbide powder

A beta-silicon carbide powder with a surface area of 30m²g^?l and a mean particle size of < 1μm was produced from the thermal conversion of silicon resin in an atmosphere of hydrogen. The amount of product increased with increasing iron content (0–2.1 wt%) and firing temperature (1200–1500°C). Chemical analysis, X-ray diffraction and i.r. absorption spectrometry were used to follow the conversion reaction.     

THE STICKY ISSUES OF DRYING

Unconrolled agglomeration of particles and adhesion of the particulate mass to wall surfaces are common severe problems in many drying operations. This paper reviews the mechanisms of interparticle and particle-surface attraction as well as the theory and the existing tests for characterising powders in terms of internal strength, wall friction and adhesion. The usefulness of the information obtained from these tests in dryer design and operation is critically reviewed. The importance of powder stickiness in various types of dryers is discussed and established methods of combating the problem are presented Recommendations an made for further research in the area of powder cohesion and adhesion.     

М.Ю.巴利新的粉末冶金理论

巴利新(原苏联)是世界知名的粉末冶金学家。1938年他提出的压制方程ln p=—AV+B仍为美国1984年出版的《金属手册》第九版第七卷‘粉末冶金’所引用。早在70年代,巴利新就根据他提出的一系列新理论,提出一个新的压制或固结方程式组α=~2z,f=F(,α),p=pαf,但除原苏联外,该方程鲜为人知。鉴于此,本文作者对巴利新60年代以来发表的一系列关于粉末冶金理论的论著进行了整理,现扼要地予以阐述,这对我国粉末冶金理论的研究或许是有益的。     

Dental amalgam – the effect of the technology of alloy powder preparation on the corrosion behaviour and the release of mercury

Dental amalgams are based on a broad spectrum of materials differing in their chemical composition, metallurgical treatment, and in the way the initial alloys powders are prepared. In addition to their chemical composition, amalgams based on various powders differ in both their microstructure and the amount of mercury needed for preparation. All these facts may affect electrochemical processes occurring during their interaction with oral fluids, and also mercury release. While verifying the effect of the technology used for the preparation of the high‐copper ternary alloy powder on the properties of resulting amalgams, this study aimed at the mechanism of their interaction with a model saliva solution as well as mercury release was included. Measurements were done in a model saliva solution using standard electrochemical methods and exposition measurements. The interaction of individual types of amalgams with artificial saliva did not reveal any significant differences. The free corrosion potential of all these amalgams in an aerated solution settled in the range of values in which tin oxidation, resulting in a layer of insoluble corrosion producsts, turned out to be the dominant anodic process. The rate of mercury release was the lowest for amalgams based on a gas‐atomized alloy. The highest rate of mercury release, and also its dependence on time, was exhibited by lathe‐cut powder based amalgam. In addition to different volume fraction of the Ag‐Hg phase and the level of its tin alloying, this different behaviour may be explained by differences in the rate at which a layer of tin corrosion products acting as a barrier to mercury release is formed.     

锰锌铁氧体纳米粉体的液相制备及磁性能

以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点.     

Effect of Hydrogen Heat Treatment on the Chemical Composition of Aluminum Nitride Powder

The effect of hydrogen heat treatment on impurity contents in aluminum nitride powder of different fineness is studied. Thermodynamic calculations are provided pointing to the possibility of forming gaseous hydrogen compounds with impurity elements. It is established that as a result of treatment the contents of impurity elements, i.e. oxygen, carbon, sulfur, are reduced by a factor of 3-13. The optimum hydrogen heat treatment regime is determined: a temperature of 1323 K and an exposure time of 30 min.     

低工作温度的氧化钨气敏材料

本文报道了一种可以在１００℃左右工作的氢化钨气敏材料，它对氢气和一氧化氮有很高的灵敏度和良好的选择性，并可对空气中的一氧化氮进行探测     

50kg／m钢轨轨底缺陷的检验和分析

钢轨轨底缺陷有三种：底伤、结疤和底裂缺陷。取２０根有底缺陷５０ｋｇ／ｍＵ７１Ｍｎ钢轨做试样，通过低倍、断口、金相检验和扫描电能谱分析，详细描述了轨底缺陷的宏观和微观特征，研究出钢轨轨底缺陷出现的规律臁其产生的原因。通过对比试验，发现淄博１号保护渣有利于改善钢锭表面质量，提高钢轨一级品率。     

佛尔哈德法测定氯化除汞上清液中的氯量

控制pH4-6，用锌粉还原氯化除汞上清液中的汞（Ⅱ）离子，取置换后液加入过量的硝酸银标准溶液，以硫酸铁铵溶液作指示剂，用硫氰酸钾标准滴定溶液滴定来测定氯量。该方法的检出限：0．25mg／100mL，回收率：98％-101％。