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91.
92.
K. N. Mehrotra M. Chauhan R. K. Shukla 《Journal of the American Oil Chemists' Society》1996,73(7):897-902
The ultrasonic velocity and density measurements of europium soaps in a mixture of benzene and methanol (3:2, vol/vol) were
used to evaluate various acoustic parameters and molar volume and to determine the critical micelle concentration. The results
showed that the ultrasonic velocity, specific acoustic impedance, molar sound velocity, and molar compressibility increase,
and intermolecular free length, adiabatic Compressibility, and relative association decrease with increasing concentration
and chainlength of the soap. The results were interpreted in terms of soap-solvent interaction. 相似文献
93.
山洪临界雨量是山洪灾害预报预警的重要基础,受降雨、土壤含水量以及下垫面的影响,其中降雨量空间分布是重要的影响因素之一。以湖北省崇阳县高堤河流域为例,采用HEC-HMS分布式水文模型计算设计洪水,试算法计算临界雨量,提出了降雨量空间分布系数,分析了降雨量空间分布系数与临界雨量的关系,探讨了降雨空间分布对临界雨量的影响。结果表明:当降雨从上游到下游逐渐减少时,达到相同成灾流量对应的临界雨量最大,暴雨中心在下游时临界雨量最小,说明降雨量空间分布对临界雨量影响显著。由分析可知,在山洪灾害预警实践中应根据实际的降雨空间分布对预警指标适当修正,对山洪进行动态雨量预警。 相似文献
94.
95.
The preparation of dibasic acid-containing soy phospholipid was made by transesterification reaction with alkyl ester of diabasic acid with both lipase and alkoxide as a catalyst. The extent of incorporation of a dibasic acid varied with the molecular size of the dibasic acid. The extent of incorporation in soy phospholipids was 4–13% in the case of adipic acid and 9–20% in the case of sebacic acid. The surface-active properties of these modified soy phospholipids were examined and were found to be different from those of the original (unmodified) soy phospholipid. The interfacial properties such as critical micelle concentration (CMC), γCMC, surface excess concentration Γmax, and minimum area per molecule (Å), and thermodynamic parameters such as standard free energy of micellization, were found to depend on the hydrophobic part of the dibasic acids. 相似文献
96.
97.
Man-Hee HanJung-Whan Kim Jinwon KimJung Yoon Ko Jules J. MagdaIn Suk Han 《Polymer》2003,44(16):4541-4546
The acrylic comonomers hydroxypropyl methacrylate (HPMA) and N,N-dimethylaminoethyl methacrylate (DMA) have been used in several earlier studies to produce pH-responsive hydrogels. However, these same monomers can also be used to prepare hydrogels that are highly responsive to temperature. One manifestation of this temperature sensitivity is a sharp decrease in hydrogel optical transparency that occurs when the temperature exceeds a critical transition value. For example, a hydrogel that exhibits a swelling transition at the physiological pH value of 7.4 has a transition temperature of about 45 °C when the environmental salt concentration is 0.15 M. The value of the transparency transition temperature is shown to depend on hydrogel synthesis parameters such as comonomer mole ratio, crosslinker mole ratio, and even initiator concentration. By reducing the mole ratio of the crosslinker tetraethylene glycol dimethacrylate (TEGDMA), the transition temperature can be lowered by as much as 15 °C. Environmental salt concentration and solvent polarity are also shown to influence the transition temperature. 相似文献
98.
Nabel?A.?NegmEmail author Salwa?M.?I.?Morsy 《Journal of surfactants and detergents》2005,8(3):283-287
A weight loss technique was used to determine the corrosion inhibition efficiency of synthesized alkyl mono-and dibenzoate
triethanolammonium bromide derivatives (TEAMB, TEADB) in an acidic medium (2 N HCl) at different doses (50, 100, and 200 ppm).
The results showed that monoderivatives had a higher corrosion inhibition efficiency than diderivatives. The results were
correlated with several factors, including the alkyl chain length of the hydrophobic chains, interfacial tension (IT), critical
micelle concentration (CMC), and adsorption free energy of these inhibitors. Increasing the geometric length of the alkyl
chains in the synthesized inhibitors had an increasing effect on their corrosion inhibition efficiency, whereas decreasing
the CMC and IT had an increasing effect on their tendency toward corrosion inhibition. The number of hydrophobic chains attached
to the inhibitor molecules had a vital influence on their efficiency as corrosion inhibitors. 相似文献
99.
The effects of loading rate, fiber sizing, test temperature and global strain level on the adhesion strength between carbon fibers and a thermosetting epoxy (Epon 815) are studied using the single fiber fragmentation test procedure. Analytical methodology describing the viscoelastic behavior observed is also presented. The possibility of rate-temperature-interphase thickness superposition for the interfacial strength function is illustrated based on the analytical models discussed. Experimental data are discussed using Weibull statistics and also presented in the form of percent relative frequency histograms for the fiber fragments in a collective fashion. The use of histograms allows for interpretation of the skewness in the data population. 相似文献
100.
A. G. Anshits N. N. Anshits A. A. Deribas S. M. Karakhanov N. S. Kasatkina A. V. Plastinin A. Yu. Reshetnyak V. V. Sil'vestrov 《Combustion, Explosion, and Shock Waves》2005,41(5):591-598
The detonation velocity of an emulsion explosive containing hollow alumosilicate microspheres (cenospheres) as the sensitizer
is measured. The size of the microspheres is 50–250 μm. The relations between the detonation velocity and the charge density
and diameter are compared for emulsion explosives containing cenospheres or glass microballoons as the sensitizer. It is shown
that for a 55 mm diameter charge, the maximum detonation velocity of the composition with cenospheres of size 70–100 μm is
5.5–5.6 km/sec, as well as for 3M glass microballoons. The critical diameter for the emulsion explosive with cenosphere is
1.5–2 times larger than that for the emulsion explosive with glass microballoons and is 35–40 mm.
__________
Translated from Fizika Goreniya i Vzryva, Vol. 41, No. 5, pp. 119–127, September–October, 2005. 相似文献