TiB2和SiCW对Al2O3陶瓷材料高温摩擦磨损特性的影响

研究了Ａｌ２Ｏ３、Ａｌ２ｏ３／ＴｉＢ２和Ａｌ２Ｏ３／ＴｉＢ２／ＳｉＣＷ三处陶瓷材料在不同条件下的擦靡损特性。结果表明：三种陶瓷材料与硬质合金摩擦副的摩擦系数随温度温度的增加有不同的变化规律，摩擦表面的Ｘ射线衍射分析表明，摩擦系数的变化与陶瓷物膜的和结构有关，在高温下Ａｌ２Ｏ３／ＴｉＢ２陶瓷材料摩擦表面形成了具有优良的高温润性的ＴｉＯ２氧化膜，因而ＴｉＢ２的加入明显改善了Ａｌ２Ｏ３陶瓷材料 摩擦磨损     

Knowledge-based diagnosis of drill conditions

One major bottleneck in the automation of the drilling process by robots in the aerospace industry is drill condition monitoring. This paper describes a system approach to solve this problem through the advancement of new machine design, sensor instrumentation, metal-cutting research, and intelligent software development. All drill failures can be detected and distinguished: chisel edge wear, flank wear, crater wear, margin wear, corner wear, breakage, asymmetry, lip height difference, and chipping at lips. However, in the real manufacturing environment, different workpiece materials, drill size, drill geometry, drill material, cutting speed, feed rate, etc. will change the criteria for judging the drill condition. The knowledge base used for diagnosing the drill failures requires a huge data bank and prior exhaustive testing. A self-learning scheme is therefore introduced to the machine in order to acquire the threshold history needed for automatic diagnosis by using the same new tool under the same drilling conditions.     

Photo-reversible Reaction in Polymer Langmuir-Blodgett Films

Preparation of photoreactive Langmuir-Blodgett (LB) films was carried out using polymers/oligomers prepared from long-chain dialkyl esters of di-and tetra-olefins and having cyclobutane rings in the main chain. These polymers/oligomers formed stable monolayers on a water surface when mixed with arachidic acid. These monolayers could be deposited onto a substrate successfully forming Y-type films. The oligomer LB films were polymerized on irradiation. The polymer LB films showed a photo-reversible process between polymers and oligomers, depending on wavelength of the irradiating light. On the basis of spectral data and molecular weight change, this behaviour was found to be caused by cleavage and formation of cyclobutane rings.     

A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

n-Al2O3/Ni复合镀层的组织与滑动磨损性能研究

用电刷镀技术制得了镍基n-Al2O3复合镀层，并对镀层的滑动磨损性能进行了试验研究。纳米复合镀层的表面形貌比较细腻，镀层中纳米粒子分布均匀，与基质金属结合紧密。镀层显微硬度达到HV700，比快速镍镀层提高约40％。滑动磨损试验结果表明，随着纳米粒子含量的增大，镀层的耐磨性提高，摩擦系数也呈增大趋势；但当镀层中n-Al2O3粒子的超过2.56%(质量分数）时，镀层的耐磨性显著下降。纳米复合镀层的磨损机制以疲劳磨损为主，而快速镍底层以粘着磨损为主。     

石灰竖窑工作衬砖蚀损机理的探讨

阐述了石灰竖窑的预热带、煅烧带和冷却带工作衬砖蚀损机理，并讨论了如何根据耐火砖性能和石灰竖窑不同区域的蚀损机理，选择耐火材料。     

Wear resistance of plasma coatings for a constant work of friction

We analyze the wear resistance of plasma coatings for a constant work of friction. The dependences of the wear resistance of the coatings are obtained for a broad range of loading conditions. It is shown that the minimum sensitivity to loading conditions is exhibited by the molybdenum coatings. It is also established that the wear resistance of the coatings decreases as the amplitude of displacements increases and the cyclic frequency of the tests decreases due to the intensification of fatigue processes on the surfaces. The comparative characteristics of coatings are presented. __________ Translated from Problemy Prochnosti, No. 5, pp. 94–100, September–October, 2007.     

Proton and hydrogen formation by cyclohexyl benzene during overcharge of Li-ion batteries

This study provides experimental evidence for proton and hydrogen formation caused by the anodic electropolymerization of cyclohexyl benzene (CHB), which is a popular electrolyte additive for overcharge protection of lithium-ion batteries (LIBs). It is found that considerable H₂ evolution is observed in overcharged LiCoO₂/graphite cells, especially when CHB is included as an electrolyte additive. In order to confirm the proton generation during the CHB oxidation, Pt/Pt-rotating ring disc electrode (RRDE) measurements are performed in 1 M Li(C₂F₅SO₂)₂N ethylene carbonate/ethyl methyl carbonate (1/2, v/v) solutions with and without CHB. The cathodic ring current is intimately correlated to the anodic disc current, and the cathodic reaction at the ring is determined to be the reduction of the proton. The proton generation efficiency during the CHB oxidation is as high as 90%. Proton liberation is also observed during the anodic decomposition of the electrolyte solvents, although it occurs in a much less stoichiometric way compared with that during the CHB oxidation.     

PLC在环锭捻线机上的应用

介绍了如何使用PLC和数字变频调速技术 ,对传统环锭捻线机进行技术改造 ,使锭速、捻度和卷绕成形变换实现数字化柔性控制 ,扩大了工艺参数的变化范围 ,使整个捻线加工车间实现信息化管理成为可能。     

Influence of load and speed on wear characteristics of grey cast iron in dry sliding — selection for minimum wear

The wear of grey cast iron in dry sliding conditions has been studied with the aims of (1) finding the influence of working conditions on the wear rate, and (2) determining the region of speed and load where low wear is accomplished. Grey cast iron with flake and nodular graphite was submitted to investigation using a pin-on-disc machine. The results indicate that the flake graphite cast iron is more suitable for applications at speeds greater than 4 m s⁻¹ and lower loads, while nodular cast iron has greater wear resistance at lower speeds in the range of loads investigated - from 50 N cm⁻² to 200 N cm⁻²