The study on the conductivity of styrene-maleic anhydride copolymer electrolytes based on poly(ethylene glycol)400 and LiClO4

Polyelectrolytes, in this study were synthesized from styrene-maleic anhydride (SMA) copolymer, poly(ethylene glycol)400 (PEG400), and lithium perchlorate (LiClO₄). Fourier transform infrared spectroscopy (FTIR), and magic angle spinning (MAS) solid-state NMR were used to monitor the interaction between Li⁺ ions and polymer. The results of FTIR and MAS solid-state NMR indicate the Li⁺ ions are preferentially coordinated to the ether oxygen of PEG. The T_g of the PEG segments in polyelectrolyte increases with LiClO₄ concentration, as determined by differential scanning calorimetry (DSC), indicating that solubility of the Li⁺ ions in the host polymer increases with the PEG content. Impedance spectroscopy (IS) shows that the bulk conductivity of polyelectrolytes and the conductivity behavior obeys the Vogel-Tamman-Fulcher (VTF) equation.     

The onset of Taylor-Görtler vortices in impulsively decelerating swirl flow

The onset of hydrodynamical instability induced by impulsive spin-down to rest in a cylinder containing a Newtonian fluid is analyzed by using propagation theory. It is well-known that the primary transient swirl flow is laminar, but with initial high velocities secondary motion sets in at a certain time. The dimensionless critical time Τ_c to mark the onset of instability is presented here as a function of the Reynolds number Re. Available experimental data indicate that for large Re deviation of the velocity profiles from their momentum diffusion occurs starting from a certain time Τ≈4Τ_c. This means that secondary motion is detected at this characteristic time. It seems evident that during Τ_c⪯Τ⪯4Τ_c, secondary motion is relatively very weak and the primary diffusive momentum transfer is dominant.     

Effect of calcination temperature on the characteristics of SO<Emphasis Type="Italic">sk</Emphasis>4/2-/TiO<Subscript>2</Subscript> catalysts for the reduction of NO by NH<Subscript>3</Subscript>

The catalytic activity of sulfated titania (ST) calcined at a variety of temperatures has been investigated for selective catalytic reduction (SCR) of NO by NH₃. The NO removal activity of ST catalyst mainly depends on its sulfur content, indicating critical role of sulfur species on the surface of TiO₂. The role of sulfur is mainly the formation of acid sites on the catalyst surface. The presence of both BrØnsted and Lewis acid sites on the surface of sulfated titania has been identified by IR study with the adsorption of NH₃ and pyridine on ST. The reduction of the intensity of IR bands representing BrØsted acid sites is more pronounced than that revealing Lewis acid sites as the calcination temperature increases. It has been further clarified by IR study of ST500 catalyst evacuated at a variety of temperatures. The NO removal activity also decreases with the increase of the catalyst calcination temperature. It simply reveals that BrØnsted acid sites induced by sulfate on the catalyst surface are primarily responsible for the enhancement of catalytic activity of ST catalyst containing sulfur for NO reduction by NH₃.     

Assessment of a redox alkaline/iron-chelate absorption process for the removal of dilute hydrogen sulfide in air emissions

The oxidative absorption of hydrogen sulfide (H₂S) into a solution of ferric chelate of trans-1,2- diaminocyclohexanetetraacetate (CDTA) was studied in a counter-current laboratory column randomly packed with 15 mm plastic Ralu rings. The present investigation takes concern about the Kraft pulping situation where dilute H₂S concentrations are omnipresent in large-volume gas effluents. A fractional two-level factorial approach was instigated to determine the significance of six operating variables, namely the solution's alkalinity (pH; 8.5-10.5), the liquid mass flow rate (L;1.73-), the solution's ionic strength (I_C;0.01-), the gas mass flow rate (G;0.19-), the inlet H₂S concentration (C_H2S,0;70-430 ppm) and the initial ferric CDTA concentration (C_Fe,0;100 -). Initially, a Plackett-Burman design matrix of seven duplicated experiments revealed that pH is the leading factor controlling the H₂S conversion rate while the ionic strength and ferric CDTA concentration effects remained negligible within the factorial domain. Surface response analysis based on 11 duplicated factorial experiments plus 10 central composite trials revealed that the H₂S conversion significantly increases with liquid flow rate but decreases with growing H₂S load up. Further examination about the influence of ferric CDTA on H₂S absorption rate was set up over a broader concentration range (C_Fe,0;0- at pH of 9.5 and 10.5. It showed good potential at as H₂S conversion increased by a significant 25% for both pH values in comparison to pure alkaline solutions containing no ferric CDTA.     

Energy spectrum of an electron confined in the hexagon-shaped quantum well

Considering the hexagonal-shaped quantum-scale formations on the surface of thin semiconductor films, a methodology was developed to obtain the analytical solution of the Schrdinger equation when impenetrable walls of a quantum well are treated as mirrors. The results obtained allowed the calculation of the space probability distributions and the energy spectrum of the particle confined in a hex-agonal-shaped well.     

Chlorophyll adsorption on acid-activated clay

An acid-activated clay (Çanakkale montmorillonite from Turkey) was used to adsorb chlorophyll from hexane solutions. The phenomenon seems to be mainly driven by the interaction of chlorophyll with acid sites. The adsorption of chlorophyll on Brönsted acid sites was indicated by a characteristic infrared band for the -OH group at 3671 cm^?1. The variations in the structure of clay mineral and chlorophyll during adsorption have been examined by differential thermal analysis, thermogravimetry and infrared spectroscopy of the activated clay before and after adsorption of chlorophyll. Oxidation of adsorbed chlorophyll was completed at quite a high temperature.     

电子信息科技英语的教学实践

为培养复合型人才,科技英语教学的重要性日益显现。分析了目前电子信息类专业中科技英语教学存在的问题,并围绕教学内容改革、教学过程管理等介绍了该课程的教学实践。同时,本文还指出未来科技英语教学的发展趋势。     

基于IMU与激光雷达紧耦合的混合匹配算法

针对线、面特征匹配的激光雷达测距与地图构建算法(Lightweight and Ground-Optimized Lidar Odometry And Mapping,LeGO-LOAM)在自动导引运输车(Automated Guided Vehicle,AGV)室内室外实时建图与定位时,易出现激光里程计累积误差大和旋转估计不准确等问题,本工作采用惯性测量单元(Inertial Measurement Unit,IMU)与激光雷达紧耦合的LeGO-LOAM算法,通过IMU为激光雷达提供的初始位姿信息,构建IMU与激光雷达联合误差函数,实现位姿共同迭代优化.其中,对于室外结构化信息较少时,在点对点的迭代最近点算法(Iterative Closest Point,ICP)较高定位精度的基础上,结合LeGO-LOAM算法和ICP算法互补性,进一步提出基于IMU与激光雷达紧耦合的混合匹配算法:当环境中结构信息较多时,激光里程计采用LeGO-LOAM算法,而当环境中结构化信息较少时采用ICP算法.实验结果表明,基于IMU与激光雷达紧耦合的混合匹配算法可有效降低激光里程计相对位姿误差和累积误差,提高AGV小车定位精度以消除部分地图重影.     

基于ViLBERT与BiLSTM的图像描述算法

传统图像描述算法存在提取图像特征利用不足、缺少上下文信息学习和训练参数过多的问题,提出基于ViLBERT和双层长短期记忆网络(BiLSTM)结合的图像描述算法.使用ViLBERT作为编码器,ViLBERT模型能将图片特征和描述文本信息通过联合注意力的方式进行结合,输出图像和文本的联合特征向量.解码器使用结合注意力机制的BiLSTM来生成图像描述.该算法在MSCOCO2014数据集进行训练和测试,实验评价标准BLEU-4和BLEU得分分别达到36.9和125.2,优于基于传统图像特征提取结合注意力机制图像描述算法.通过生成文本描述对比可看出,该算法生成的图像描述能够更细致地表述图片信息.     

面向综合效益的城市充电网点规划研究

随着国家大力发展新能源汽车的政策,电动汽车和充电基础设施规模不断扩大,如何科学地规划充电网点成为亟待解决的问题。本文根据分期规划的原则,采用基于注意力机制的长短期记忆网络进行充电需求预测,使用量子粒子群优化算法进行近期充电网点选址定容,然后根据Voronoi图来划分远期充电站服务区域,从而建立了充电网点精准规划模型。通过对杭州市钱江世纪城区域进行验证,表明本文模型在科学规划充电网点的同时,能够实现电网、企业、用户的多方共赢。