尿素对以硝酸铝和葡萄糖为原料合成氮化铝粉末反应过程中相变及反应速率的影响

以硝酸铝(Al(NO3)3·9H2O)和葡萄糖(C6H12O6·H2O)为原料,利用碳热还原法制备氮化铝粉末,研究了尿素对前驱物的制备及前驱物氮化反应的影响,研究发现添加尿素合成的前驱物和未添加尿素合成的前驱物在氮化反应过程中相变和反应速率存在较大差异。在没有添加尿素合成的前驱物的氮化反应过程中,出现了γ-Al2O3、α-Al2O3、AlON和AIN相,该前驱物的反应速率慢,完全氮化需要在1600℃下才能完成。对于添加尿素合成的前驱物而言,在其氮化反应过程中仅出现了γ-Al2O3和AIN相,没有α-Al2O3和AlON的生成,AIN直接由γ-Al2O3氮化生成,该前驱物的氮化反应速率快,氮化反应温度低,在1400℃下即可实现完全氮化。分析讨论了两种前驱物的氮化反应速率不同的主要原因,并利用XRD、SEM等分析方法对粉末进行了表征。     

吉化化肥厂一硝漂白系统的改进

本文介绍了一硝漂白系统以前存在的问题,并找出了一硝成品含N_2O_4高的原因。通过漂白塔的更新改造和移位,从而改进了生产,取得了显著的经济效益。     

NP装置加负荷试验总结

山西化肥厂 NP 装置用摩洛哥与王集混矿进行的加负荷试验,从产量、质量、消耗、装置运行及工艺指标执行情况等作了全面的总结,对所暴露的问题进行简要的分析。     

270m3铝制卧式浓硝酸储罐失效原因分析及加固措施

分析了290m^3铝制卧式浓硝酸储罐蠕变的原因，经过计算校核，找出导致储罐变形的根源所在，提出了解决办法。     

山西天脊煤化工投资有限公司

山西天脊煤化工投资有限公司前身是山西化肥厂，其硝酸磷肥的生产装置属国家“六五”重点建设项目，是国家投资16亿元，成套引进德国、日本、法国和挪威等8个国家的11项专利技术建设的我国第一套大型复合肥生产装置。目前主要产品的年生产能力为：合成氨75万t，硝酸81万t，硝酸磷肥90万t（或硝酸磷钾100万t），尿素60万t，工业硝铵20万t，苯胺13万t，水泥30万t，塑料编织袋7500万条。     

国产双加压法硝酸生产装置运行情况的分析及建议

介绍了国内外硝酸工业生产情况.分析已投运的国产"四合一"机组在运行中出现的问题,并对国产"四合一"机组和硝酸装置设计提出几点建议.     

Thermokinetics of Liquid-Liquid Reaction of Dy（NO3 ）3 with Histidine

The thermokinetics of liquid-liquid reaction of dysprosium nitrate with histidine were studied using a microcalorimeter. On the basis of experimental and calculated results, threethermodynamic parameters (the activation enthalpy, the activation entropy and the activation free enegy),the rate constant, three kinetic parameters (the activation energy, the pre-exponential constant and the reaction order) wereobtained. On the basis of thermodynamics and kinetics, the for marion reaction of the complex was discussed.     

LASER CLADDED TiCN COATINGS ON THE SURFACE OF TTTANIUM

Laser cladded coatings of TiCN were produced on the surface of titanium. To obtain the optimal techniques, several conditions were tested by varying the laser scanning rate. The choice of shielding gas was also studied. The cladded coatings were then evaluated from the surface mechanics point of view based on their microhardness. The microstructure of some interesting samples was investigated by optical micrographs （OM）. The results showed that under the condition of fixed pulse frequency and pulse width, the laser scanning rate and the shielding gas are the main factors influencing the components of coatings. TiCN coatings were decompounded and oxidized during the cladding process in the condition of no shielding gas of N2. X-ray diffraction results indicated that the composite coatings composed of TiCN, TiC, Ti2N, and TiO2 were produced using appropriate techniques. The results indicated that the best condition in terms of the surface microhardness is obtained when the scanning rate is 1.5mm/s, the pulse frequency is 15Hz, the pulse width is 3.0ms, and N2 is chosen as the shielding gas. The microhardness of the composite coatings is about 1331kg · mm^-2, which is about 4 times that of the substrate. The optical micrographs indicated that the cladding zone is made up of TiCN, TiO2 and some interdendritic Ti, but the diffusion zone mainly consists of the dendrites phase, and the cladded depth is about 80μm, which is more than 2 times that of the laser nitrided sample. There were no microcracks or air bubbles in the cladded sample, which was cladded using the above optimal techniques.