DCPD和PET合成不饱和聚酯的研究

探讨了用双环戊二烯和聚对苯二甲酸乙二醇酯废料合成不饱和聚酯树脂的方法：PET用二元醇醇解后，加入顺入烯二酸酐和DCPD，在80－120℃条件下滴加与DCPD等量的水进行反应，反应大约2.5h，加入其它成分，升温酯化直至反应完全。PET一定时，DCPD的含量影响不饱和聚酯同苯乙烯的互溶性和固化过程，DCPD和PET合成的不饱和聚酯树脂与标准树脂相比较，机械性能好，空干性好，解决了环境污染，具有很好的经济效益。     

聚乙烯醇侧链液晶的结构与液晶性研究

研究了聚乙烯醇侧链液晶主链分子量和液晶基元等结构因素对其液晶性的影响，结果表明随着聚合物的分子量增加，导致复合物清亮点温度下降。但是在液晶主链尚未被液晶基元饱和之前，随着液晶基元相对主链摩尔比的增加，样品形成较为完善的氢键结构。     

聚羧酸类LEX-9高性能减水剂性能分析及应用

介绍了聚羧酸类LEX-9高性能减水剂的性能和在实际应用中的体会。     

Preparation of Laminin-apatite-polymer Composites Using Metastable Calcium Phosphate Solutions

A synthetic polymer with a laminin-apatite composite layer on its surface would be useful as a percutaneous device. The preparation of such a composite was attempted in the present study using poly（ ethylene terephthalate ） （PET） and polyethylene （PE） as the synthetic polymer. PET and PE plates and those pretreated with an oxygen plasma were alternately dipped in calcium and phosphate ion solutions, and then immersed in a metastable calcium phosphate solution supplemented with laminin （ LCP solution ）. The PET and PE plates pretreated with an oxygen plasma formed a uniform and continuous layer of a laminin-apatite composite on their surfaces. In contrast, the PET and PE plates that had not been pretreated with an oxygen plasma did not form a continuous layer of a laminin-apatite composite on their surfaces. The hydrophilic functional groups on the PET and PE surfaces introduced by the plasma treatment were responsible for the successful laminin-apatite coruposite coating.     

Synthesis and Characterization of Poly （L-lactide-co-ε-caprolactone） Copolymers

A series of random and block poly（ L-lactide-co-e-caprolactone ） （ PCLA ） copolymers whh different composition are prepared using stannous octaoate as catalyst.The effects of the amount of initiator on the intrinsic viscosity have been investigated. The structure of the PCLA copolymers is characterized by means of nuclear magnetic resonance（ NMR ）, Fourier transform infrared spectrum （ FTIR ）, differential scanning calorimetry （ DSC ） and X- ray diffraction （ XRD ） methods. It is shown that the synthesis condition and the composition of copolymers obrious influence on the structure of PCLA copolymers. Hydrolytic degradation of the copolymers in a PBS solution of pH 7.4 at 37.0℃ shows that the copolymers of different composhions degrade at different rates.     

孤岛油田中一区Ng5-6注聚前调剖工艺应用

孤岛油田中一区Ng^5-6储层非均质严重，注入动态表明油层中存在高渗透带或大孔道，支PI决策技术，注聚前区块实施整体调剖后，注水井油压、启动压力、压降指数大幅度得到提高，吸水剖面得到改善，表明大孔道高渗透带得到控制，此技术有利于扩大聚合物的波及体积，提高区块的开发效果。     

聚己内酯多元醇的合成和应用

综述了聚己内酯多元醇的的合成方法 ,并介绍了其在合成聚氨酯弹性体、涂料以及胶粘剂中的应用。     

有机羧酸钠盐对PET结晶和熔融行为的影响

采用差示扫描量热仪研究了5种具有不同取代基的苯甲酸钠盐作为结晶成核剂对聚对苯二甲酸乙二醇酯（HET）结晶和熔融行为的影响，并同滑石粉进行了对比。结果表明，成核剂的加入能明显改变PET的结晶和熔融行为。苯甲酸钠、对苯二甲酸甲酯单羧酸钠和对羟基苯甲酸钠提高既汀的熔融结晶温度（Tc）分别达22．93、21．7和19．37℃，但使PET降解严重；对苯酚钠甲酸钠能够提高Tc达17．75℃且对PET相对分子质量影响很小；对苯二甲酸二钠成核作用最差。低于滑石粉。此外，成核剂的成核能力越强，PET双熔融峰中的低温峰顶温度就越高。     

马来西亚聚丙烯公司推出高加工性均聚聚丙烯

马来西亚聚丙烯公司推出用于带材、纺丝、纤维、薄膜以及注塑应用的系列均聚聚丙烯（PP）牌号Propelinas SHAC320。根据加工者的反馈，这种新牌号产品可以使加工能力提高10％～15％，特别是对于带材和纺丝应用。