25CrMo车轴钢塑性的协调单元及其优化研究

采用OM、SEM、EBSD及TEM对25CrMo钢的微观组织进行定量表征,分析微观组织对试验钢塑性的控制作用。结果表明：随着晶粒的粗化,低碳板条马氏体钢的塑性逐渐增加,其与传统的理解不同,即具有大角度取向的原奥氏体晶粒(也包括束和块)不再是塑性的协调单元.只有属于小角度取向的马氏体板条对塑性的影响满足细晶增塑的原理,即在低碳板条马氏体钢中板条是塑性的有效控制单元.因此,在板条马氏体钢中,细化马氏体板条或增加小角度界面比例,是提高塑性的重要途径,其弥补了细化晶粒在大型构件中难以实现的不足.此外,也为高强度、高塑性材料的设计和开发提供了新思路.     

Photocatalytic oxidation of CO with various oxidants by Mo oxide species highly dispersed on SiO2 at 293 K

The photocatalytic oxidation of CO into CO₂ with oxidants such as NO, N₂O and O₂ proceeded efficiently on a Mo/SiO₂ with high Mo dispersion under UV light irradiation. It was found that the reaction rate greatly depended on the kind and concentration of the oxidant. Photoluminescence investigations reveal the close relationship between the reaction rate and the relative concentration of the photo-excited Mo⁶⁺-oxide species, i.e. charge transfer–excited–triplet state (Mo⁵⁺–O⁻)^*, under steady-state reaction conditions. Moreover, the photocatalytic oxidation of CO with O₂ in excess H₂ was carried out to test suitability for applications to supplying pure H₂. This reaction was seen to proceed efficiently on Mo/SiO₂ with a high CO conversion of 100% and CO selectivity of 99% after 180 min under UV light irradiation, showing higher photocatalytic performance than TiO₂ (P-25) photocatalyst. UV–vis, XAFS, photoluminescence and FT-IR investigations revealed that the high reactivity of the charge transfer–excited–triplet state (Mo⁵⁺–O⁻)^*, with CO as well as the high reactivity of the photoreduced Mo-oxide species (Mo⁴⁺-species) with O₂ to produce the original Mo-oxide species (Mo⁶⁺O²⁻), played a crucial role in the reactions.     

25Cr2Mo1V钢在高温服役中的组织和性能研究

采用SEM、金相及能谱分析方法,通过力学性能测试,对25Cr2Mo1V钢在高温服役状态下的组织和性能进行了研究．结果表明：25Cr2Mo1V铜在长期高温下服役会形成黑色网状晶界,且晶界粗化及V、S元素在晶界处的偏聚,导致冲击韧性降低,产生脆化现象,造成其服役时间缩短．     

2.25Cr-1Mo不锈复合钢板加氢高压换热器的制造

主要介绍了2.25Cr-1Mo不锈复合钢板加氢高压换热器的制造工艺技术。在分析研究的基础上通过采取合理的焊接及热处理工艺，不但成功地保证了复合钢板基材的力学性能和抗回火脆性性能，而且还有效地保证了复层的耐蚀性能。     

噻虫·咯·霜灵FS拌种对大麦蚜虫防治效果及增产作用研究

考察不同剂量25%噻虫·咯·霜灵FS拌种对大麦蚜虫的防治效果,以及对大麦产量的影响。结果表明,不同剂量的25%噻虫·咯·霜灵FS拌种能有效控制蚜虫对大麦的危害,蚜虫发生初期防效达100%,蚜虫增长期防效为70.9%~96.7%,且持效期长。同时,25%噻虫·咯·霜灵FS拌种能显著提高大麦产量、有效穗、穗实粒数及千粒重,此外对白粉病具有兼治效果。大麦生产中采用60~70 mL25%噻虫·咯·霜灵FS拌10 kg种子,不仅能有效防治蚜虫,还能提高大麦产量和品质。     

基于AT25DF641的弹载数据记录器的设计

文中设计了一种基于新型串行Nand Flash存储器AT25DF641的低成本炮弹弹载数据记录器。采用五片存储器阵列,通过对数据采集和存储过程的优化,写入速度可达980kbitls。采用贴片、小封装元件实现小型化。采用电路板固封、控制引脚单独连接、存储器编程和擦除的保护等抗干扰措施。弹载条件下,实际平均速度800kbitls以上,很好的满足了实际需求。     

Kinetic study of photocatalytic degradation of carbamazepine, clofibric acid, iomeprol and iopromide assisted by different TiO2 materials--determination of intermediates and reaction pathways

The light-induced degradation of clofibric acid, carbamazepine, iomeprol and iopromide under simulated solar irradiation has been investigated in aqueous solutions suspended with different TiO2 materials (P25 and Hombikat UV100). Kinetic studies showed that P25 had a better photocatalytic activity for clofibric acid and carbamazepine than Hombikat UV100. For photocatalytic degradation of iomeprol Hombikat UV100 was more suitable than P25. The results can be explained by the higher adsorption capacity of Hombikat UV100 for iomeprol. The study also focuses on the identification and quantification of possible degradation products. The degradation process was monitored by determination of sum parameters and inorganic ions. In case of clofibric acid various aromatic and aliphatic degradation products have been identified and quantified. A possible multi-step degradation scheme for clofibric acid is proposed. This study proves the high potential of the photocatalytic oxidation process to transform and mineralize environmentally relevant pharmaceuticals and contrast media in water.     

超音速火焰喷涂Cr_3C_2-25%NiCr涂层的滑动摩擦磨损性能研究

采用超音速火焰喷涂工艺制备了Cr_3C_2-25%NiCr陶瓷,对涂层的组织结构、显微硬度及在滑动摩擦条件下的失重进行了分析,得出了涂层摩擦因数与时间的关系,对涂层的滑动摩擦磨损机理进行了分析。结果表明Cr_3C_2-25%NiCr涂层致密,孔隙率为0.96%,涂层截面的显微硬度平均值HV_(0.3)为867。涂层稳定的摩擦因数为0.1。初始阶段涂层的磨损主要是磨屑对涂层的磨粒磨损作用,摩擦稳定后涂层的磨损主要是由于相对运动面的磨削作用。     

JS25Mn钢管内表面起皮缺陷分析与控制

通过对JS25Mn钢管内表面起皮缺陷进行分析,认为造成该缺陷的原因主要为:钢中含有高熔点及含钛化合物非金属夹杂;低熔点非金属夹杂在铸坯疏松缺陷位置发生偏聚。通过真空处理钢液及连铸工艺优化调整后,钢液纯净度得到提高,铸坯内部质量得到优化,有效解决了起皮缺陷问题。用户对产品使用情况给予了认可。