光子晶体光纤数值孔径测试的一种新方法

应用光谱仪测量光子晶体光纤(PCF)的数值孔径(NA),不仅克服了传统法只能测量几个固定波长下NA的局限性,还可以对PCF与波长有关的模场面积、截止波长等参数进行研究。实验测量结果与理论计算值进行了比较,取得了满意结果。由测得的NA计算PCF的模场面积,与多极法模拟结果一致性较好。给出了NA与截止波长的关系。     

A rapid-detection method for radioactive cesium in the air

We propose a method of rapidly detecting radioactive cesium floating in the air for the purpose of alerting people active in the ‘difficult-to-return zone’ of Fukushima to changes in airborne radioactivity. With this purpose in mind, we set requirement specifications and created a new system concept. The targeted detection limit was 30 Bq/m³ and the mandatory level of measurement time was 48 min with a target level of 12 min, and these periods are 10 times faster than those of conventional air monitors. The system consists of a conventional gamma-spectrometer with a novel shaped shield. The targeted peak region of the measured energy spectrum is analyzed. After the basic design and confirmation of feasibility, we perform some experiments in the normal environment of Yokohama city and the difficult-to-return zone of Fukushima. Using the results, we conducted the design improvement and performance evaluation. As a result, the system performance is found to satisfy requirements. We thus conclude that this system is a promising candidate for rapid detection of airborne radioactivity in the difficult-to-return zone of Fukushima.     

Aerosol laser time-of-flight mass spectrometer for the on-line measurement of secondary organic aerosol in smog chamber

An aerosol laser time of flight mass spectrometer (ALTOFMS) that can be used for real-time measurement of the size and composition of individual aerosol particles has been designed and utilized to provide on-line measurement of secondary organic aerosol (SOA) particles resulted from Cl-initiated oxidation of toluene in smog chamber. Both the size and chemical compositions of individual aerosol particles were obtained in real-time. According to a large number of single aerosol diameters and mass spectra, the size distribution and chemical composition of aerosol were determined statistically. Experimental results indicate that aerosol particles produced from Cl-initiated oxidation of toluene were predominantly in the form of PM 2.5 particles, and nine positive laser desorption/ionization mass spectra peaks: m/z 18, 29, 30, 44, 46, 52, 65, 77, and 94 may come from the fragment ions of the products of the SOA: aromatic aldehydes, aromatic acids, phenolic compounds, and nitrogenated organic compounds. These results were in good agreement with those ones from previous Cl-initiated oxidation of toluene. These were demonstrated that ALTOFMS is a useful tool to reveal the formation and transformation processes of SOA particles in smog chamber.     

Principle of a two-output-difference interferometer for removing the most important interference distortions

This paper presents a two-output-difference interferometer for removing the most important interference distortions caused by nonlinear detectors. These distortions can be removed not only because the resulting interferogram is composed of the difference between the signals of the two detectors, but also because the modulated signals at each output have the same amplitude and opposite phases. Due to the use of two corner-cube mirrors fixed as a single moving element, the tilt and shearing problem will disappear. The effect of the corner-cube mirror deviation angle and the plane mirror tilt angle are investigated in detail, and the formulas of their tolerance are derived by means of modulation depth and phase error. The advantage of the interferometer enables it to be suitable for Fourier transform spectrometers.     

Design of data feature-driven 1D/2D convolutional neural networks classifier for recycling black plastic wastes through laser spectroscopy

In this study, two types of convolutional neural network (CNN) classifiers are designed to handle the problem of classifying black plastic wastes. In particular, the black plastic wastes have the property of absorbing laser light coming from spectrometer. Therefore, the classification of black plastic wastes remains still a challenging problem compared to classifying other colored plastic wastes using existing spectroscopy (i.e., NIR). When it comes the classification problem of black plastic wastes, effective classification techniques by the laser spectroscopy of Fourier Transform-Infrared Radiation (FT-IR) with Attenuated Total Reflectance (ATR) and Raman to analyze the classification problem of black plastic wastes are introduced. Due to the strong ability of extracting spatial features and remarkable performance in image classification, 1D and 2D CNN through data features are designed as classifiers. The technique of chemical peak points selection is considered to reduce data redundancy. Furthermore, through the selection of data features based on the extracted 1D data with peak points is introduced. Experimental results demonstrate that 2DCNN classifier designed with the help of 2D data feature selection as well as 1DCNN classifier shows the best performance compared with other reported methods for classifying black plastic wastes.     

THE TWO-MESSAGE PROBLEM IN CIPHER TEXT AUTOKEY. PART II

This is Part II of a two-part paper on the problem of the title. In this part the analysis of the two-message problem started in Part I is completed. In addition a brief discussion is given of a computer-assisted solution. A list of twelve two-message problems involving several types of conditions is attached for the benefit of the reader.     

机载摆扫式光谱仪高转速三面摆镜设计与优化

为满足机载摆扫式光谱仪在25Hz扫描频率下工作的要求,设计了具有三面反射镜的摆镜结构。首先,计算镜面反射区域面积与旋转轴偏离量的关系,通过比较摆镜布置不同数目反射镜时的性能,设计了围绕旋转轴布置三面反射镜的摆镜结构形式,通过600r/min的转速即可完成每分钟1 800次的高频摆扫;同时采用匀速摆扫的运动方式,降低了摆镜的控制难度,提高了系统的稳定性。然后,采用拓扑优化、集成优化等方法对摆镜结构进行了优化,摆镜最终质量为5.28kg,轻量化率达到58%。最后,通过有限元仿真计算得到:摆镜在机载平台600r/min转速离心力与1 g重力的作用下,面型精度RMS值优于λ/20,基频达到1 199Hz,具有较高的力学稳定性,满足机载摆扫式光谱仪的高扫描频率要求。     

天宫二号紫外前向光谱仪大气临边高度计算

天宫二号紫外前向光谱仪是一种对全球中层大气进行大气痕量气体垂直分布探测的新型光谱仪,在对大气痕量气体进行反演中,需要高精度地计算观测大气的高度参数等几何位置参数。本文针对该光谱仪的几何成像特点,设计并提出了一种高精度的大气高度的计算方法。首先,计算传感器坐标系下的观测矢量;其次,利用平台的轨道参数、姿态及成像时间等成像几何参数,推导出传感器坐标系到地心固定坐标系的转换矩阵,同时将观测矢量转换到地心固定坐标系下;再次,以标准地球椭球体为基准,建立经过临边切点的虚拟椭球体模型,并计算切点的地理坐标;最后,依据切点坐标推导出切点的临边高度。与理论值对比分析,在相同地球临边高度对应的散射光谱幅亮度分布保持一致,并且与美国OMPS载荷反演的O3结果进行定位误差分析,高度误差小于1pixel,在2km范围内,从而验证了本文所提算法的可行性和正确性。     

甲醇制烯烃催化剂积炭的形成机理

采用二氯甲烷超声波萃取,提取甲醇制烯烃(MTO)待生催化剂和不完全再生催化剂外表面可溶性积炭,采用氢氟酸溶解及碳酸钠溶液中和后再用二氯甲烷超声波萃取,提取待生催化剂和不完全再生催化剂孔道内可溶性积炭,结合气相色谱-质谱(GC-MS)分析了其组成,并对MTO催化剂积炭形成的机理和再生烧炭的机理进行了分析探讨。结果表明:MTO待生催化剂外表面可溶性积炭主要是饱和烃和芳烃,其中饱和烃以C23~C31的正构烷烃为主,芳烃以一环和二环芳烃为主;孔道内可溶性积炭均为芳烃,以三环和四环芳烃为主,从质谱峰强度计算约占总量的80%,菲和芘约占总量的50%。MTO不完全再生催化剂外表面可溶性积炭主要是沸点较高的C23~C31正构烷烃;孔道内可溶性积炭主要是几个高含量组分如芘和菲等的残留。在催化剂外表面的饱和烃可能是由小分子烯烃类化合物经过一系列聚合而成,而催化剂外表面的一环和二环芳烃应该是从分子筛孔道内形成并溢出,在分子筛孔道口吸附。分子筛催化剂孔道内的多环芳烃,是由小分子烃类化合物经过一系列低聚、氢转移、环化和脱氢等反应生成。     

原子荧光仪测试岩石矿物中硒元素试验研究

探讨了原子荧光仪测试岩石矿物中硒元素试验研究。运用原子荧光仪测试岩石矿物中硒元素,结果显示：原子荧光仪测试岩石矿物中方法硒元素的回收率、相对标准偏差、方法检出限分别为98.2%-103.0%、0.95%-5.80%、3.5×10^-11g/m L。原子荧光仪方法测试岩石矿物中硒元素具有较为快捷的速度、较高的灵敏度,且简便易行等,值得推广。