具有边梁的悬臂矩形板的弯曲问题

本文建议一个求解具有边梁悬臂矩形板弯曲问题的解析解法。该法将有边梁和无边梁悬臂矩形板弯曲问题的解融为一体,在有边梁悬臂矩形板的解中令边梁弯曲刚度为零即得到无边梁悬臂矩形板的解。     

Effect of doping cobalt on the micro-morphology and electrochemical properties of birnessite MnO2

Birnessite-type MnO₂ nanoparticles are synthesized by mixing KMnO₄ solution directly with ethylene glycol under ambient conditions. When cobalt exists in the solution, the micro-morphology of the products transforms from conglomeration to dispersive state. The result of transmission electron microscopy (TEM) and field emission scanning electron microscopy (FE-SEM) shows that the product is constructed with nanosphere in sizes of ca. 40 nm. These nanospheres are twisted by nanorods clusters. X-ray diffraction (XRD) pattern shows that the products are birnessite-type. The electrochemical properties of the prepared materials are studied using cyclic voltammetry (CV) and galvanostatic charge–discharge test in aqueous electrolyte. The product shows a very high specific capacity of 326.4 F g⁻¹. These results indicate that cobalt has great effects on the micro-morphology and electrochemical properties of manganese dioxide.     

SURFACE ROUGHNESS OF SPUTTERED SILICON. II. MODEL VERIFICATION

Experimental verification of the mathematical surface roughness model for sputtered silicon was performed. The beam shape and its significant level of intensity were determined first by measuring the topography of craters sputtered by focused ion beam (FIB). Then the beam function was generated for various combinations of beam parameters. The material function was developed both by theoretical and experimental analysis. These two functions were then used in the model to calculate the theoretical surface roughness. Microsurface analysis was formed by FIB sputtering of a (100) silicon wafer. The surface roughness at the bottom of the sputtered features was then measured using an atomic force microscope. The theoretical surface roughness was found to be within ±1 and ±5 nm of the measured surface roughness with the measurement uncertainty (standard deviation) of about ±0.36 and ±0.85 nm for R_a and R_t, respectively.     

Low-energy electron interaction with nitrobenzene: C6H5NO2

Low-energy electron attachment to C₆H₅NO₂ (nitrobenzene) in the gas phase is reported in the electron energy range from about 0 up to 10 eV with an energy resolution of 120 meV. Dissociative and nondissociative electron attachment to nitrobenzene were observed. From the numerous ions observed, the two most abundant were NO₂⁻ and C₆H₅NO₂⁻. Based on comparison of the abundance of studied ions with Cl⁻ in the dissociative electron attachment to CCl₄ at 0.8 eV, estimates of cross sections for the all observed ions were obtained for the first time (e.g. σ(NO₂⁻)=4.6×10⁻²⁰ m² and σ(C₆H₅NO₂⁻)=3.8×10⁻²¹ m²).     

30.4 nm Si/C多层膜反射镜的制备与测量

采用离子束溅射镀膜装置制备了一种新的材料组合Si/C多层膜 ,用于 30 4nm波段的正入射多层膜反射镜。并用软X射线反射率计测得其反射比最大值为 0 14。有效地抑制了 15 0nm处的二级衍射峰。     

Effect of V doping concentration on the electronic structure,optical and photocatalytic properties of nano-sized V-doped anatase TiO2

V-doped TiO₂ with V/Ti ratio of 1–5% has been synthesized by hydrothermal method and then characterized by XRD, TEM, BET specific surface area, XPS and UV–vis. absorption spectra. The photocatalytic activity of the as-synthesized samples was investigated by the degradation of methylene blue in aqueous solution under visible light irradiation. Density functional theory (DFT) based calculations were performed to investigate the mechanism of band gap narrowing, the shift of light absorption edge, the location of V in the TiO₂ lattice and the variation in electronic and optical properties of TiO₂ with the increase of V doping concentration. Irrespective of the V doping concentration, TEM images indicate that all the doped samples were composed of equiaxed spherical anatase TiO₂ particles with good crystallinity and uniform particle size distribution. Both the experimental results from XPS survey and the theoretical calculation argue that the doped V replaces the lattice Ti and form substitutional impurity. The visible light absorption can be optimized by adjusting the V doping concentration. Among the doped samples with different V doping concentrations, the sample with V/Ti ratio of 2% depicts better visible light photocatalytic activity due to the enhanced visible light absorption and improved separation of electron–hole pairs.     

Coriander leaf mediated biosynthesis of gold nanoparticles

Extracellular biological synthesis of gold nanoparticles was achieved by a simple biological procedure using coriander extract as the reducing agent. The aqueous gold ions when exposed to coriander leaf extract are reduced and resulted in the biosynthesis of gold nanoparticles in the size range from 6.75-57.91 nm. The gold nanoparticles were characterized by UV-Vis spectroscopy, X-ray diffraction (XRD), energy dispersive X-ray analysis (EDAX), fourier transform infra-red spectroscopy (FT-IR) and transmission electron microscopy (TEM). This eco-friendly approach for the synthesis of nanoparticles is simple, amenable for large scale commercial production and technical applications.     

Microwave radiation as heating method in the synthesis of titanium dioxide nanoparticles from hexafluorotitanate-organic salts

Nanocrystalline anatase was obtained from ionic liquid-like precursors containing hexafluorotitanate-organic salts and less than 25 wt.% of water, and using boric acid as fluoride scavenger. Two alternative heating methods were explored using either a conventional oven or a domestic microwave apparatus. A significant reduction in the reaction time from 24 h to only few minutes was obtained using the microwave route. The as-prepared materials were characterized by X-ray diffraction, transmission electron microscopy, nitrogen sorption analysis, and attenuated total reflectance Fourier transformed infrared, X-ray photoelectronic and Raman spectroscopes. The convenience of using the microwave heating option was a function of the organic cation present in the precursor. Thus, organic ammonium cations containing only hydrocarbon substituents, such as diethylammonium, phenylammonium and benzyltrimethylammonium led to the precipitation of nanocrystalline anatase powder with high specific surface area (up to 120 m² g⁻¹) in a short processing time (1-3 min). Otherwise, alcohol and carboxylate functionalized cations decomposed under microwave treatment. Moreover, the choice of the organic cation allowed tuning several properties of the end material, such as particle size and pore morphology.     

镀厚膜工艺技术研究

通过分析现有镀膜工艺设备的电子束加热原理、结构和热量损耗,并针对实际应用过程中镀膜存在的问题,提出了对现有设备的改进措施,开发出一种新的镀厚膜工艺,较好解决了芯片镀厚膜的工艺技术难题和存在的镀厚膜工艺质量问题,大大提高了镀厚膜工艺的工作效率,极大地改善了特高压超大功率电力电子器件的电性能参数,收到了良好的效果.