Synthesis and photovoltaic properties of an alternating phenylenevinylene copolymer with substituted-triphenylamine units along the backbone for bulk heterojunction and dye-sensitized solar cells

We have fabricated bulk heterojunction (BHJ) photovoltaic devices based on the as cast and thermally annealed P:[6,6]-phenyl-C-61-butyric acid methyl ester (PCBM) blends and found that these devices gave power conversion efficiency (PCE) of about 1.15 and 1.60% respectively. P is a novel alternating phenylenevinylene copolymer which contains 2-cyano-3-(4-(diphenylamino)phenyl)acrylic acid units along the backbone and was synthesized by Heck coupling. This copolymer was soluble in common organic solvents and showed long-wavelength absorption maximum at 390-420 nm with optical band gap of 1.94 eV. The improvement of PCE after thermal annealing of the device based on the P:PCBM blend was attributed to the increase in hole mobility due to the enhanced crystallinity of P induced by thermal treatment. In addition, we have fabricated BHJ photovoltaic devices based on the as cast and thermally annealed PB:P:PCBM ternary blend. PB is a low band gap alternating phenylenevinylene copolymer with BF₂-azopyrrole complex units, which has been previously synthesized in our laboratory. We found that the device based on this ternary blend exhibited higher PCE (2.56%) as compared to either P:PCBM (1.15%) or PB:PCBM (1.57%) blend. This feature was associated with the well energy level alignment of P, PB and PCBM, the higher donor-acceptor interfaces for the exciton dissociation and the improved light harvesting property of the ternary blend. The further increase in the PCE with thermally annealed ternary blend (3.48%) has been correlated with the increase in the crystallinity of both P and PB. Finally, we used copolymer P as sensitizer for quasi solid state dye-sensitized solar cell and we achieved PCE of approximately 3.78%.     

水性紫外光木器涂料的研制

以水性UV丙烯酸酯树脂、水性UV脂肪族聚氨酯丙烯酸酯树脂为基料制备成水性紫外光木器涂料,经检测,水性UV涂装性能上大大得到改善,气味比普通UV涂料低、硬度比水性木器涂料高、表面效果与施工方法得到有效的改善,解决了水性木器、UV光固化涂料在喷涂技术领域遇到的技术瓶颈。     

基于ANSYS的U71Mn重轨感应加热温度场数值模拟

利用有限元分析软件对U71Mn重轨感应过程中的温度场分布进行了数值模拟,得到了随时间变化的重轨截面温度分布图,并分析了感应加热整个温升过程的特点.结果表明:通过调整重轨移动速度、加热装置的频率、线圈宽度等工艺参数,可以使重轨连续通过感应加热器的情况下保证轨头升温到相变温度,对U71Mn重轨感应加热工艺的运用和改进具有一定的指导意义.     

基于ANSYS的U71Mn重轨轨头淬火组织场的数值模拟

利用有限元分析软件对U71Mn重轨轨头喷水冷却过程进行数值模拟,拟合出轨头各部分温降速度曲线,并根据求得的轨头各部位实际冷却速度与各组织极限冷却速度对比结果,成功预测了轨头在该参数下喷水冷却得到的组织,对重轨轨头淬火时相关参数的选择具有一定的指导意义.     

基于71M6513数字三相多功能表的设计

介绍了TERIDIAN三相多功能电能计量芯片71M6513的基本功能和特点,在此基础上,设计计量精度高、工作稳定、成本相对较低的数字多功能表,实现对电能的计量(三相电流、电压,有功、无功功率)、电能脉冲的输出等功能,用于电力系统、工矿企业、公用设施、智能大厦的电力监控。     

基于SHT71的温湿度无线远程监控系统

针对温室大棚的温湿度采集,提出了一种无线远程系统设计方案,介绍了系统结构和软硬件设计．系统以HT46R24单片机为节点控制核心,采用了数字式微型智能传感器SHT71,通过GSM网络与上位机进行无线数据通信．当温湿度出现异常时,启动语音报警功能,控制通风装置进行环境温湿度调节．上位机软件采用VB6．0编写,实现了与温湿度采集节点的数据通信以及对采集到的数据进行处理、储存、分析等操作．实验表明,系统运行稳定,具有很好的环境适应性．     

新型SHT71温湿度传感器的数据通讯校验

基于温湿度内漏检测系统介绍了使用新型SHT71传感器的生成电路及主要特点;并重点说明了和微控制器之间串行通讯时采用的校验方法一循环冗余校验法(CRC)及其原理、优点;并根据SHT71循环冗余校验的硬件生成电路给出了它的算法及软件实现方法,实践结果表明：用软件实现CRC校验过程既简单实用又成本低廉,十分有效。     

野外快速测定铀废石堆氡析出率

在铀矿山环境综合治理过程中,野外现场测量氡析出率是一项费时、费力的工作.本项目初步研究了用FD-3017 RaA土壤测氡仪野外现场快速测定铀废石堆氡析出率.研究结果表明,该常规土壤氡测量仪器可用于测量铀废古石堆上的氡析出率,即使在氡析出率不超标的地区,该仪器也是可实际应用的.在进行大量氡析出率测定工作而并不需要严格定量时,可考虑应用氡浓度与氡析出率8的相关关系,快速估算该点的氡析出率.     

井间地震资料解释方法初探——以垦71区块井间地震为例

垦71区块井间地震代表胜利油田地震勘探工作进入一个新的时期。通过合成记录的制作以及井间地震反射波成像资料与常规地震资料的对比,对垦71区块井间地震资料的可靠性进行了评价。通过粗化处理和测井约束反演,探讨了井间地震资料的综合解释方法。