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991.
992.
以TiCl4为原料,分别以Cr(NO3)3、Fe(NO3)3和Al(NO3)3为掺杂剂,采用共沉淀制备了含不同掺杂剂和掺杂量的纳米二氧化钛凝胶,利用综合热分析仪(热重分析一差示扫描量热联用仪,简称DSC-TG)研究了纳米二氧化钛凝胶从30-1100℃热稳定性以及组分和物相的变化,XRD测定了二氧化钛凝胶在煅烧过程中晶型转变。结果表明:含不同掺杂剂和不同掺杂量凝胶的DSC-TG曲线有很大的差别;Cr3+和Fe3+掺杂能促进金红石相的形成,Al3+掺杂有利于锐钛矿相的稳定。 相似文献
993.
It is well known that the electrode structure of a PEMFC has a huge influence on the water management and thereby on the cell performance. In this work, two MEAs – one prepared by an airbrushing technique and the other by a novel fast spray coating technique (multilayered MEA) – were analysed with respect to porosity, pore size distribution, tortuosity and their electrochemical performance. FIB nanotomography with following 3D reconstruction, SEM investigation on ultramicrotomic thin‐sections, and single cell tests were performed on these MEAs. The results show a higher porosity and lower pore size for the multilayered MEA. The multilayered MEA reaches a Pt utilisation of 1,962 mW mg–1 and a peak power density of 210 mW cm–2, whereas the airbrushed MEA only provides a Pt utilisation of 879 mW mg–1 and a peak power density of 218 mW cm–2. The Pt utilisation calculations showed in combination with the structural characterisations that a homogeneous pore structure and Pt distribution provide an advantage with regard to performance and efficiency of the PEMFC. Furthermore, the multilayered MEA may offer an advantage over the airbrushed MEA in its long term stability, which was observed in preliminary tests. 相似文献
994.
The kinetics of zinc and lead ions removal by modified zeolite-clinoptilolite has been investigated. The rate of the ion exchange process for lead ions is faster than for zinc ions, as well as the time needed to reach the equilibrium. The ion exchange capacity of zeolite of lead ions is doubly higher than that of zinc ions. Diffusion models according to the Vermeulen's approximation, the parabolic diffusion model and the homogeneous diffusion model have been tested with the experimental data of ion exchange for zinc and lead. For both systems examined, the best fit of the models proposed with the experimental data was shown by the Vermeulen's approximation and the homogeneous diffusion model with t-->t(infinity). The diffusion coefficients are calculated from kinetic models of lead ions they are of the order of 10(-6)cm(2)/min, constant for all examined initial concentrations and not dependent on time. The diffusion coefficients in the system of zinc ions is of the order of 10(-8)cm(2)/min, also independent of initial concentrations, but decreasing with time from the beginning of ion exchange to the equilibrium. 相似文献
995.
Atia AA 《Journal of hazardous materials》2006,137(2):1049-1055
Glycidyl methacrylate/N,N'-methylene bis-acrylamide (GMA/MBA) was prepared and allowed to react with tetraethylenepentamine (TEP) to give glycidyl methacrylate amine resin (RPA) followed by treatment with glycidyl trimethylammonium chloride (GTA) to give glycidyl methacrylate resin bearing quaternary ammonium chloride moieties (RQA). Zeta potential measurements showed that RQA particles are positively charged over pH 2-10 indicating the strong basic nature of the quaternary amine sites. The effect of pH on the recovery of chromate by RPA and RQA was examined. The results indicated that RQA is an efficient sorbent for chromate from both acidic and basic media. The repeated use of RQA was tested through stripping the adsorbed chromate using a mixture of 0.05 NaOH and 2 M NaCl in the case of the uptake from acidic media and using 2 M NaCl solution in the case of alkaline solutions. 相似文献
996.
Improving purity and size of single-crystal diamond plates produced by high-rate CVD growth and lift-off process using ion implantation 总被引:1,自引:0,他引:1
The lift-off process using ion implantation has recently been applied to produce large and thick single-crystal diamond plates by chemical vapor deposition (CVD). CVD growth conditions for undoped, as opposed to nitrogen-doped, diamond were investigated to improve the purity of plates produced by this technique. This utilized apparatus identical to that for high-rate growth with nitrogen addition under high-density plasma. By lowering the growth temperature to 900 °C, an undoped single-crystal CVD diamond plate with a maximum length of 9 mm and thickness of 0.47 mm was successfully produced without formation of non-epitaxial crystallites. The UV–Vis–NIR transmission spectrum of this plate was identical to high-pressure high-temperature (HPHT) synthetic IIa diamond, suggesting high purity of the plate. To increase the size of single-crystal CVD diamond plates, a process to enlarge the seed crystal by combining the lift-off process and a side-surface growth technique is proposed. By this process, a half-inch single-crystal CVD diamond seed crystal was successfully synthesized and half-inch freestanding single-crystal CVD diamond plates were produced from the seed. 相似文献
997.
A. El HajjB. Lucas M. ChakarounR. Antony B. RatierM. Aldissi 《Thin solid films》2012,520(14):4666-4668
We investigated the electrical and optical properties of ZnO/Ag/ZnO multi-layer electrodes obtained by ion beam sputtering for flexible optoelectronic devices. This multi-layer structure has the advantage of adjusting the layer thickness to favor antireflection and the surface plasmon resonance of the metallic layer. Inserting a thin (Ag) metallic layer between two (ZnO) oxide layers decreases the sheet resistance while widening the optical transmittance window in the visible. We found that the optimal electrode is made up of a 10 nm thin Ag layer between two 35 nm and 20 nm thick ZnO layers, which resulted in a low sheet resistance (Rsq = 6 Ω/square), a high transmittance (T ≥ 80% in the visible) and the highest figure of merit of 1.65 × 10-2 square/Ω. 相似文献
998.
Alternate hard TiAlN/TiB2 multilayers with different modulation periods (Λ) ranging from 0.6 to 27 nm and modulation ratios (tTiAlN:tTiB2) ranging from 8:1 to 25:1 were prepared using an ion beam assisted deposition (IBAD) system. The effect of Λ and tTiAlN:tTiB2 on the hardness, elastic modulus, residual stress, and fracture resistance were investigated using various characterization techniques. All multilayers with clear interfaces displayed higher hardness than individual TiAlN and TiB2 layers. The maximum hardness of 35 GPa and critical load of 84 mN were obtained for the multilayer with a Λ of 2.2-8.8 nm and tTiAlN:tTiB2 of 8:1. Strong TiAlN (111) crystallographic texture as well as multilayer structure is thought to be be responsible for the increasing hardness of the TiAlN/TiB2 multilayers. 相似文献
999.
1000.
M. Buljan U.V. DesnicaI. Bogdanovi?-Radovi? N. Radi?M. Ivanda G. Dra?i?S. Bernstorff V. Holý 《Vacuum》2012,86(6):733-736
We compare structural and optical properties of Ge quantum dot lattices in amorphous silica matrix obtained by two recently published techniques for the preparation of regularly ordered quantum dot lattices in amorphous matrices. The first technique is self-ordering growth of (Ge + SiO2)/SiO2 multilayer at an elevated substrate temperature where diffusion and surface morphology effects drive the self-ordering. The second one is irradiation of (Ge + SiO2)/SiO2 multilayer by oxygen ions. The multilayer used for the irradiation is grown at room temperature in this case, resulting with no Ge clusters after the deposition process. The irradiation causes clustering of Ge and ordering of Ge quantum dots in the irradiation direction. We show that the size of the dots and their arrangement can be easily manipulated by the preparation parameters. The structural properties of the films prepared by these methods affect the quantum confinement of the charge carriers which is visible in the absorption properties of the films. 相似文献