全文获取类型
收费全文 | 3569篇 |
免费 | 46篇 |
国内免费 | 74篇 |
专业分类
电工技术 | 4篇 |
综合类 | 91篇 |
化学工业 | 1935篇 |
金属工艺 | 159篇 |
机械仪表 | 19篇 |
建筑科学 | 125篇 |
矿业工程 | 54篇 |
能源动力 | 430篇 |
轻工业 | 195篇 |
水利工程 | 8篇 |
石油天然气 | 54篇 |
武器工业 | 3篇 |
无线电 | 16篇 |
一般工业技术 | 328篇 |
冶金工业 | 181篇 |
原子能技术 | 46篇 |
自动化技术 | 41篇 |
出版年
2023年 | 23篇 |
2022年 | 34篇 |
2021年 | 67篇 |
2020年 | 84篇 |
2019年 | 83篇 |
2018年 | 89篇 |
2017年 | 68篇 |
2016年 | 72篇 |
2015年 | 54篇 |
2014年 | 153篇 |
2013年 | 283篇 |
2012年 | 106篇 |
2011年 | 282篇 |
2010年 | 182篇 |
2009年 | 257篇 |
2008年 | 252篇 |
2007年 | 230篇 |
2006年 | 219篇 |
2005年 | 153篇 |
2004年 | 148篇 |
2003年 | 160篇 |
2002年 | 120篇 |
2001年 | 58篇 |
2000年 | 54篇 |
1999年 | 49篇 |
1998年 | 36篇 |
1997年 | 49篇 |
1996年 | 46篇 |
1995年 | 43篇 |
1994年 | 52篇 |
1993年 | 30篇 |
1992年 | 32篇 |
1991年 | 25篇 |
1990年 | 25篇 |
1989年 | 26篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 5篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 4篇 |
排序方式: 共有3689条查询结果,搜索用时 24 毫秒
21.
Duc Nguyen Hong 《Chemical engineering science》2006,61(6):1846-1853
New experimental data coupled with a numerical model and an approximate solution are proposed to predict dissociation time of hydrate plugs in oil sub-sea pipelines. The experimental hydrate plugs are dissociated by the method of symmetric depressurisation, both in a specially designed apparatus and a classical batch reactor. The agreement between the estimation of the model and the experimental data and the simplicity of the approximate equation presents an advantage in estimating the time of hydrate plug dissociation in pipelines. 相似文献
22.
Pierre Darcy Patrick Da Costa Henry Mellotte Jean-Michel Trichard Grald Djga-Mariadassou 《Catalysis Today》2007,119(1-4):252-256
To comply with the new regulations on particulate matter, car manufacturers more and more commonly use diesel particulate filters (DPF). The working of these systems needs to periodically burn soot that has been accumulated during the loading of the DPF. This paper describes the kinetics of the non-catalytic and catalytic oxidation of real diesel soot with oxygen. From these experiments, mechanisms for catalyzed and non-catalyzed soot oxidation have been proposed. 相似文献
23.
Z. Gruba? 《Materials Letters》2007,61(3):794-798
The initial stage of copper electrodeposition on the electrochemically activated assembly of carbon microelectrodes from an acid solution of copper sulfate was investigated using cyclic voltammetry, potentiostatic pulse technique and electrochemical impedance spectroscopy. Analysis of the experimental current transients has been carried out using a non-linear fitting procedure according to the model that takes into account spherical diffusion towards a disc-shaped microelectrode. The higher values of diffusion coefficient in comparison with those observed on planar electrodes were explained with an increased diffusion caused by the electrode geometry. Impedance spectra showed two time constants, the high-frequency related to the charge transfer process and the low-frequency corresponded to the deposit morphology. 相似文献
24.
D. Srinivasa Rao H. Suresh Hebbar M. Komaraiah 《Materials and Manufacturing Processes》2007,22(7):825-829
Burnishing is used increasingly as a finishing operation which gives additional advantages such as increased hardness, fatigue strength, and wear resistance. Experimental work based on 34 factorial design was carried out to establish the effects of ball burnishing parameters on the surface hardness of high-strength low alloy steels (HSLA) dual-phase (DP) steel specimens. Statistical analysis of the results shows that the speed, feed, lubricant and ball diameter have significant effect on surface hardness. 相似文献
25.
The operating conditions of this study are close to the typical operating conditions of flue gas desulfurization system in coal-fired power plants. The aim of this study is to investigate the absorption kinetics of SO2 and NO from simulated flue gas into an aqueous solution of acidic sodium chlorite using a bench-scale spraying column. The range of absorption rates measured in this study is between 1.91×10?11 and 9.59×10?10?mol?s?1?cm?2. The range of rate constants measured in this study is between 1.32×107 and 1.21×108?(L?mol?1)1.9?s?1, and the average rate constant is 6.16×107?(L?mol?1)1.9?s?1. The activation energy and frequency factor are 129 Kcal/mol (53.97 KJ/mol) and 6.93×1016?[(L/mol)1.9/s], respectively. 相似文献
26.
27.
A centrifugal partition chromatograph (CPC) was used as a liquid-liquid catalytic reactor for the isomerisation of hexen-3-ol into ethylpropylketone with a water soluble rhodium catalyst. Global mass transfer coefficients were measured and shown to depend on both the nature of the solute and the flow rate. Liquid-liquid partition isotherms were also determined with the CPC using elution chromatography. Finally, a reactor model was derived to account for the experimental results obtained both under stationary and transient (pulse) conditions. A parameter sensitivity evaluation is also presented. 相似文献
28.
Dmitry Yu. Murzin 《Chemical engineering science》2002,57(8):1299-1306
Several aspects of heterogeneous catalytic kinetics over induced nonuniform surfaces are considered. The reaction mechanism is thought to occur through a surface collision of species, adsorbed on two distinct surface sites, which display nonuniform behavior. The expressions for rates of elementary reactions have been deduced within the framework of the surface electronic gas model, which accounts for the case of inhomogeneous surface. Equations for catalyst activity in the range of medium coverage have been derived and compared with the power-law model. 相似文献
29.
Anton A. Kiss Costin S. Bildea Alexandre C. Dimian Piet D. Iedema 《Chemical engineering science》2002,57(4):535-546
This article continues earlier work (Comput. Chem. Eng. 24 (2000) 209) concerning the design and control of isothermal reactor-separator-recycle systems. The multiplicity behaviour of six reaction systems of increasing complexity, from one-reactant, first-order reaction to chain-growth polymerisation, is investigated. Below a critical value of the plant Damkohler number, Da<Dacr, the only steady state involves infinite flow rates. Feasible steady states become possible if the critical value is exceeded, Da>Dacr. For one-reaction systems, one stable steady state is born at a transcritical bifurcation. For consecutive-reaction systems, including polymerisation, a fold bifurcation can lead to two feasible steady states. Moreover, the transcritical bifurcation is destroyed when two reactants are involved. If the gel-effect is included, a maximum of four steady states are possible. When multiple steady states exist, the achievable conversion is constrained by the instability of the low-conversion branch. This has practical importance for polymerisation systems when the radicals’ quasi-steady state assumption is not valid or the gel effect is significant. 相似文献
30.
Mirona K. Mironova 《Cement and Concrete Research》2002,32(1):9-15
The paper treats complex phenomena that accompany the diffusion of sulfate ions into cement paste or systems. The ion distribution within the material was studied by designing a specific diffusion model. The model accounts for two phenomena: capillary filling with products of the chemical reactions and the subsequent liquid push out of the capillary. The approach allows to quantify the concentration of free ions having penetrated the cement stone and that of chemically reacted ions, and to assess the liquid push out. Experimental data are also presented. 相似文献