全文获取类型
收费全文 | 3578篇 |
免费 | 36篇 |
国内免费 | 75篇 |
专业分类
电工技术 | 4篇 |
综合类 | 91篇 |
化学工业 | 1935篇 |
金属工艺 | 159篇 |
机械仪表 | 19篇 |
建筑科学 | 125篇 |
矿业工程 | 54篇 |
能源动力 | 430篇 |
轻工业 | 195篇 |
水利工程 | 8篇 |
石油天然气 | 54篇 |
武器工业 | 3篇 |
无线电 | 16篇 |
一般工业技术 | 328篇 |
冶金工业 | 181篇 |
原子能技术 | 46篇 |
自动化技术 | 41篇 |
出版年
2023年 | 23篇 |
2022年 | 34篇 |
2021年 | 67篇 |
2020年 | 84篇 |
2019年 | 83篇 |
2018年 | 89篇 |
2017年 | 68篇 |
2016年 | 72篇 |
2015年 | 54篇 |
2014年 | 153篇 |
2013年 | 283篇 |
2012年 | 106篇 |
2011年 | 282篇 |
2010年 | 182篇 |
2009年 | 257篇 |
2008年 | 252篇 |
2007年 | 230篇 |
2006年 | 219篇 |
2005年 | 153篇 |
2004年 | 148篇 |
2003年 | 160篇 |
2002年 | 120篇 |
2001年 | 58篇 |
2000年 | 54篇 |
1999年 | 49篇 |
1998年 | 36篇 |
1997年 | 49篇 |
1996年 | 46篇 |
1995年 | 43篇 |
1994年 | 52篇 |
1993年 | 30篇 |
1992年 | 32篇 |
1991年 | 25篇 |
1990年 | 25篇 |
1989年 | 26篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 5篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 4篇 |
排序方式: 共有3689条查询结果,搜索用时 13 毫秒
31.
《Drying Technology》2007,25(5):891-899
Degradation kinetics of food constituents may be related to the matrix molecular mobility by glass transition temperature. Our objective was to test this approach to describe ascorbic acid degradation during drying of persimmons in an automatically controlled tray dryer with temperatures (40 to 70°C) and air velocities (0.8 to 2.0 m/s) varying according a second order central composite design. The Williams-Landel-Ferry model was satisfactorily adjusted to degradation curves for both control strategies adopted—constant air temperature and temperature fixed inside the fruit. Degradation rates were higher at higher drying temperatures, independent of the necessary time to attain the desired moisture content. 相似文献
32.
Leach characteristics of 137Cs and 60Co radionuclides from both ordinary Portland cement and cement mixed with two different ratios of silica fume and ilmenite have been studied using International Atomic Energy's (IAEA) standard leach method. A mathematical model has been simulated to predict the release rate of each nuclide from cubic geometry waste matrix and the predicted values are discussed in relation to experimentally observed leach rates to confirm the validity of the proposed mechanism in the model. The effect of temperature on the radionuclides leaching rates was also studied and the effective diffusion coefficients were obtained at different temperatures. The net fractional release of the two radionuclides from different waste forms showed a decreasing pattern as 137Cs>60Co, indicating the largest diffusion coefficient for cesium in all waste matrices. 相似文献
33.
The gasification reaction of fir charcoal with CO2 was studied by isothermal thermogravimetric analysis under kinetic control. The derived reaction rate (r=dX/dt) as a function of the converted carbon mass (X) was compared with random pore model predictions and found to be much higher at elevated conversion levels than predicted by theory. Similar enhanced reaction rate behaviour was evidenced after removing the natural alkali catalyst from the charcoal by acid washing, suggesting that with untreated charcoal the late reaction rate contribution stems from both, catalytic and additional structure effects. Literature attributes the unpredicted late reaction rate behaviour to the disintegration of the porous char particle into small fragments, which, in line with percolation theory predictions, seems to occur only after a critical conversion level has been reached. However, our gasification data reveal a gradual rise in the charcoal reactivity thereafter, suggesting a breaking up (embrittlement) of the solid phase accompanied by the exposure of fresh surface area from fracturing. The original random pore model derivation given by Bhatia and Perlmutter is extended to account also for these peculiarities and the resulting kinetic relation described our reaction rate data well over the entire conversion range. 相似文献
34.
35.
Anatoly M. Dolgonosov Ruslan Kh. Khamizov Anna N. Krachak Andrei G. Prudkovsky 《Reactive and Functional Polymers》1995,28(1)
A model for multispecies ion-exchange kinetics based on the Nernst-Planck equation is suggested. It is analyzed in comparison with the “locally-determinate” model described by Hwang and Helfferich [1]. The model makes possible simple computation. The conditions for the occurrence of unusual kinetic curves with a maximum are clarified. The proposed model is developed for different types of kinetic problems and verified by the experimental investigation of a kinetics in ternary systems. 相似文献
36.
研究了13种不同加工热处理制度的Zr-1Nb合金在堆外高压釜内360℃、19MPa水中的吸氢性能,对其影响因素和吸氢机理进行了分析,并讨论了吸氢动力学,建立了吸氢动力学方程,计算了吸氢动力学参数。 相似文献
37.
The isothermal crystallization kinetics of Zr/Ti-based bulk metallic glasses (BMGs) have been investigated by using Avrami exponent. It is a constant nucleation rate and a constant number of quenched-in nuclei that cause the linear John–Mehl–Avrami (JMA) modes in Avrami exponents of Zr62Al8Ni13Cu17 and Zr65Al8Ni10Cu17 BMGs, respectively. However, sub-Tg pre-annealing of Zr62Al8Ni13Cu17, and multiple-step phase transition in Ti43Cu43Zr7Ni7 and Ti45Zr5Cu40Ni7.5Sn2.5 make their Avrami exponents deviate from the linear JMA mode. The difference in Avrami exponents maybe provides useful information for performing the microstructure control of BMG composites upon isothermal annealing. 相似文献
38.
季胺萃取锌的动力学研究 总被引:1,自引:0,他引:1
以恒界面池法研究了氯化物介质中季胺萃锌的动力学。考查了搅拌转速、传质界面积和温度对萃取速率的影响,判定季爱萃锌为界面化学反应的动力学模式。进一步研究了季胺萃取剂浓度和水相Zn^2+浓度对萃取速率的影响,得到了与理论推断相吻合的速率方程。 相似文献
39.
Cure kinetics and shrinkage model for epoxy-amine systems 总被引:1,自引:0,他引:1
Manufacture of most of epoxy resins implies that cure needs to be carried out under pressure. Due to the significance of knowing the influence of the pressure factor in cure kinetics, cure shrinkage of a stoichiometric epoxy-amine system was measured using a pressure-volume-temperature (PVT) analyzer. Recording the specific volume change in the range of temperature from 100 to 180 °C and a pressure of 200 bar we could model the cure kinetics. The Runge-Kutta method was applied to obtain the kinetic constants of the cure reaction. In addition, using the differential scanning calorimeter (DSC) for measurements of 1 bar and the PVT analyzer for pressures of 200, 400, and 600 bar, we also model the kinetic constants as a function of pressure. The results obtained show that the effect of the temperature on the kinetic constants is higher than the effect of pressure. Therefore, both PVT and DSC are complementary techniques to describe the full range of cure kinetic process of epoxy mixtures. 相似文献
40.
Experimental data on the monomer conversion, xm, and the weight average molecular weight, Mw, have been generated under several isothermal and non-isothermal conditions for the polymerization of methyl methacrylate in a rheometer-reactor assembly. The non-isothermal results, in particular, can be used to provide more stringent tests of kinetic models than isothermal data alone. A simple empirical model has been used to describe this system that accounts for the gel (Trommsdorff) and glass effects. The model involves only xm and the temperature, and is quite general. The model parameters are tuned using only three sets of isothermal data. Good agreement is found between the experimental results and model predictions for a whole variety of experimental conditions, including non-isothermal operation and with intermediate addition of initiator. Because of its generality, this model is quite suitable for use for on-line optimizing control as well as for describing industrial reactors. 相似文献