Computer-aided thermodynamic study of solid Co---Pd alloys by Knudsen cell mass spectrometry, and calculation of the phase diagram

F.c.c. solid Co---Pd alloys have been investigated thermodynamically by means of computer-aided Knudsen cell mass spectrometry. Thermodynamic evaluation has been performed by applying the “digital intensity ratio” method. The thermodynamic excess properties can be described algebraically by means of thermodynamically adapted power series with two adjustable parameters, i.e. C₁^G (−20 810 + 9.608T) J mol⁻¹) and C₂^G (−30 720 + 6.78T) J mol⁻¹). At 1470 K, f.c.c. solid Co---Pd alloys are characterized by negative molar excess Gibbs energies G^E, exothermic molar heats of mixing (H^E) and small negative molar excess entropies S^E. At 1470 K, the minimum G^E value is −4600 J mol⁻¹ (61.9 at.% Pd), the minimum H^E value is −9400 J mol⁻¹ (59.5 at.% Pd) and the minimum S^E value is −3.3 J mol⁻¹ K⁻¹ (55.9 at.% Pd). The thermodynamic activities of Co show small positive deviations from the ideal case for the Co-rich alloys (x_Pd < 0.34), and negative deviations from Raoults' law for alloys with higher Pd contents. The Pd activities a_Pd show negative deviations from the ideal case for all compositions. The phase diagram has been computed by means of a generally applicable procedure for the calculation of the equilibrium compositions of coexisting phases. This was achieved using the results of this work, thermodynamic data from earlier mass spectrometric studies on the liquid phase, and literature data for the heat capacities and enthalpies of Co and Pd.     

Joint relay selection and power allocation for amplify-and-forward two-path relaying networks

This paper presents a joint relay selection and power allocation scheme for amplify-and-forward two-path relaying networks,in which diferent relay nodes forward information symbols alternatively in adjacent time slots.Our approach is based on the maximization of the received signal-to-noise ratio under total power consumption by the transmission of the symbol.We show that in spite of inter-relay interferences,the maximization problem has a closed-form solution.Simulation results explicitly indicate that the performance of proposed approach outmatches the existing methods including equal power allocation and one-path relaying.     

磁保持射频继电器在移动通信设备自动测试系统中的应用研究

介绍了磁保持继电器的原理和移动通信设备自动测试系统的体系结构,重点阐述了磁保持射频继电器在直放站自动测试系统中的应用方法,并提出了使用磁保持射频继电器提高自动测试系统的安全性,防止意外损坏射频程控仪器的新方案和相应的软硬件设计.该方案在实际自动测试系统中已得到成功应用。     

梯形波脉冲筛板萃取柱传质性能

本文以UO_2(NO_3)_2—30％TBP(KO)为实验体系,进行了梯形波脉冲筛板柱传质性能的研究。实验中测量了两组分的两相稳态浓度剖面共13组,以扩散模型为基础,求得了梯形波脉冲柱的“真实”传质单元高度HTU_(ox),分散单元高度HDU及表观传质单元高度HTU_(oxp)。通过对实验结果进行分析,选择出了适于本实验体系的较好的操作条件。     

Ignitable Liquid Classification and Identification Using the Summed-Ion Mass Spectrum

Abstract

The mass spectra calculated by summing the intensities of each nominal mass over all chromatographic times, the summed ion spectra, were calculated for a set of 440 commercially available ignitable liquids that had been analyzed by gas chromatography–mass spectrometry. Each ignitable liquid is generally comprised of a mixture of chemicals, and the mixtures may be very complex in some cases, e.g., petroleum distillates, gasoline, etc. The summed ion spectra were evaluated to determine if they contained sufficient information content to allow their use for rapid and accurate identification of the ignitable liquid in a database or library. The summed ion nominal mass spectra were encoded in one bit per channel at 1% transition intensity and a set of 96,580 unique pairwise comparisons were made between spectra, resulting in an average of approximately 50 differing channels per comparison. A subset of 62 summed ion spectra were further compared by a similarity metric and found by cluster analysis to group closely along the ASTM ignitable liquid classification scheme. Receiver operator characteristic analysis of the use of the similarity index in combination with the summed ion spectra was shown to provide 99% probability of correct liquid identification and 95% probability of correct ASTM classification by primary and sub-class. Interlaboratory tests found 95% probability of correct liquid identification and 85% probability of correct ASTM classification at the primary class level. These results demonstrate the use of the summed ion spectrum as a first step in the rapid identification of an ignitable liquid by database or library searching.     

城市多元化视角下的《老友记》

本文从城市多元化的视角阐释美国电视剧《老友记》成功的原因,展现以纽约为代表的多元化现代都市中的各种元素的碰撞,并进一步预测这些大城市的未来命运。     

Mass appraisal of residential apartments: An application of Random forest for valuation and a CART-based approach for model diagnostics

To the best knowledge of authors, the use of Random forest as a potential technique for residential estate mass appraisal has been attempted for the first time. In the empirical study using data on residential apartments the method performed better than such techniques as CHAID, CART, KNN, multiple regression analysis, Artificial Neural Networks (MLP and RBF) and Boosted Trees. An approach for automatic detection of segments where a model significantly underperforms and for detecting segments with systematically under- or overestimated prediction is introduced. This segmentational approach is applicable to various expert systems including, but not limited to, those used for the mass appraisal.     

变压器中低压后备保护与出线保护整定配合的研究

介绍了镇江电网变压器的中、低压侧后备保护的一般配置,阐述了变压器的中压侧或低压侧后备保护与出线有时不能相互逐级配合的情况,以及这种情况造成的危害。提出了解决这种上下级保护不能相互逐级配合的两种处理方法,并通过运行实践证明该方法是行之有效的。     

四川锦屏山电站施工辅助洞通风设计方案分析

四川锦屏山电站施工辅助隧道属特长隧道,本文根据其特殊性,重点比较了目前常用的几种隧道通风方式,最终选择一种较为合理的通风方案.     

宇宙主胁量限定粒子质量、微观临界尺寸和真空光速（胁量力学初导IV）

扩展到任意质量体的宇宙主胁量描述。宇宙主胁量同质量之间只差一个常量系数。宇宙主胁量创造了粒子的质量，造就了粒子的微观临界尺寸，构筑了恒定而有限的真空光速。