纳米晶Mg2Si金属间化合物块体材料的制备及微结构表征

采用机械合金化及热压方法制备了纳米晶Mg2Si块体材料,利用X射线衍射(XRD)、X射线能谱(EDS)分析、场发射扫描电镜(FE-SEM)及宏观密度测定对合成粉体及块体样品的微结构进行了表征.结果表明:正己烷作为合金化过程控制剂能有效避免粉体板结、团聚及防止合成粉体的氧化;合适的工艺参数(如配球、球料比及球磨转速)可有效促进合金化和降低杂质含量;配镁量对获得纯相Mg2Si块体至关重要;热压压力增大能显著提高Mg2Si块体的致密度;在1.5 GPa压力热压获得了相对密度大于98%、晶粒度为69 nm的纯相纳米晶Mg2Si块体.     

SiC_p/AZ91镁基复合材料的热挤压

采用搅拌铸造法制备SiC体积分数为5%、10%和15%的颗粒增强AZ91镁基复合材料（SiCp/AZ91）。复合材料经过T4处理后,于350°C以固定挤压比12：1进行热挤压。在铸态复合材料中,颗粒在晶间微观区域发生偏聚。热挤压基本上消除了这种偏聚并有效地改善颗粒分布。另外,热挤压有效地细化基体的晶粒。结果表明：热挤压明显提高复合材料的力学性能。在挤压态复合材料中,随着SiC颗粒含量的升高,基体的晶粒尺寸减小,强度和弹性模量升高,但是伸长率降低。     

Correlation between current frequency and electrochemical properties of Mg alloy coated by micro arc oxidation

The present work investigated the electrochemical behavior of Mg alloy subjected to micro arc oxidation coating for 120 s with respect to current frequencies from 60 Hz to 2000 Hz. The microstructure and chemical compound of thin coating layers with a thickness of ~ 3 μm were analyzed using scanning electron microscopy and X-ray photoelectron spectroscopy. The microstructural observations on the surface and cross sections revealed that both the size of pores and the number of discharge channels decreased significantly as the current frequency increased, resulting in a compact coating layer. This was primarily attributed to the transition time of the alternating electrical wave, which was determined by the current frequencies tested. Based on potentiodynamic polarization tests, the sample coated at a frequency of 2000 Hz demonstrated the highest polarization resistance of 6.37 × 10⁵ Ω cm², implying that the corrosion resistance was superior to that obtained under other conditions due to its condensed structure. This electrochemical response was also interpreted in relation to the equivalent circuit model.     

Anti-corrosion performance of a new silane coating for corrosion protection of AZ31 magnesium alloy in Hank's solution

Mg alloys can be used as bioresorsable metallic implants. However, the high corrosion rate of magnesium alloys has limited their biomedical applications. Although Mg ions are essential to the human body, an excess may cause undesirable health effects. Therefore, surface treatments are required to enhance the corrosion resistance of magnesium parts, decreasing its rate to biocompatible levels and allowing its safe application as bioresorbable metallic implants. The application of biocompatible silane coatings is envisaged as a suitable strategy for retarding the corrosion process of magnesium alloys. In the current work, a new glycidoxypropyltrimethoxysilane (GPTMS) based coating was tested on AZ31 magnesium substrates subjected to different surface conditioning procedures before coating deposition. The surface conditioning included a short etching with hydrofluoric acid (HF) or a dc polarisation in alkaline electrolyte. The silane coated samples were immersed in Hank's solution and the protective performance of the coating was studied through electrochemical impedance spectroscopy (EIS). The EIS data was treated by new equivalent circuit models and the results revealed that the surface conditioning process plays a key role in the effectiveness of the silane coating. The HF treated samples led to the highest impedance values and delayed the coating degradation, compared to the mechanically polished samples or to those submitted to dc polarisation.     

ZMl Mg合金的表面滚压强化SCIEI

研究了表面滚压对ＺＭ１Ｍｇ合金疲劳强度和疲劳缺口敏感度的影响。结果表明，滚压可使其光滑疲劳极限提高５７％，缺口疲劳极限提高２００％，大大降低疲劳缺口敏感度，使ｑ出现负值。ｈｃｐ的ＺＭ１Ｍｇ合金滚压时以滑移和孪生方式变形和形变强化，引入高的残余压应力，有利于提高缺口疲劳极限和降低疲劳缺口敏感度。     

Theory of the nonlinear internal friction associated with bulk diffusion of solute atoms around dislocations in Al–Mg alloys

In this paper the nonlinear (amplitude-dependent) internal friction (P₃ peak) in cold-worked Al–Mg alloys is theoretically studied by solving the bulk diffusion equations of the solute atoms (Mg atoms) under the action of dislocation drag. The results in the case of a constant external stress show that the bow-out distance of the dislocation has an exponential relation with time, which can be well described by an exponential creep function with a Gaussian distribution in τ. With the increasing strain amplitude, the relaxation strength Δ and relaxation time τ decrease, while the distribution parameter increases. Both activation energy H and pre-exponential factor τ₀ deduced from τ through Arrhenius relation are dependent on strain amplitude.     

含LPSO相Mg_(94)Y_4Zn_1Ni_1合金的组织和力学性能

采用OM、SEM、TEM和电子万能试验机研究了Mg_(94)Y_4Zn_1Ni_1(at%)合金在铸态、退火、挤压和时效态的显微组织与力学性能。结果表明:铸态合金组织由胞状α-Mg相、网状18R LPSO相和块状Mg_(24)(Y,Zn,Ni)_5相组成。退火后,合金中未析出14H LPSO相。经挤压变形,18R LPSO相转变为长条状并沿挤压方向排列,挤压态合金的抗拉强度达到417 MPa,显著高于铸态和退火态合金。经过T5和T6时效处理,在合金的基体中析出大量细小的共格β'沉淀相,合金得到进一步强化。T5态和T6态合金的抗拉强度分别为434和432 MPa,屈服强度均高于300 MPa。     

不同成分Al-Mg3Sb2复相涂层的组织和性能

目的研究Mg_3Sb_2含量对Al-Mg_3Sb_2复相涂层组织、耐蚀性和硬度的影响,对比纯Al涂层和添加不同含量Mg_3Sb_2涂层性能的差异。方法采用氧乙炔火焰喷涂技术和自制的Mg_3Sb_2粉末,在AZ31B镁合金表面制备不同成分的Al-Mg_3Sb_2复相涂层。采用扫描电镜(SEM)观察了涂层的微观组织,利用X射线衍射仪(XRD)分析了球磨粉末和涂层的物相组成,通过电化学工作站(CHI660e)对试样在3.5%Na Cl溶液中进行电化学腐蚀性能测试,并用显微硬度计测试了涂层的硬度。结果经火焰喷涂之后,获得了不同成分的Al-Mg_3Sb_2复相涂层,涂层中的物相主要为Al和Mg_3Sb_2。当Mg_3Sb_2的质量分数为40%和60%时,涂层组织致密,气孔、裂纹等组织缺陷较少。Tafel极化曲线测试中,随着第二相Mg_3Sb_2质量分数的增加,涂层的腐蚀电位逐渐正移。当质量分数达到80%时,其腐蚀电位为-0.9819 V,比纯Al涂层正移417.3 m V,腐蚀电流密度为0.048×10-3 A/cm2,约是纯Al涂层的1/2。显微硬度结果显示随着Mg_3Sb_2含量的增加,涂层的硬度逐渐提高,当质量分数达到80%时,涂层的平均硬度达到334.2HV,是纯Al涂层的6.79倍。结论Mg_3Sb_2的加入可以获得组织较好的涂层,随着其含量的增加,涂层的耐蚀性和显微硬度逐渐提高。     

燃料电池用LSGM-碳酸盐复合电解质材料的稳定性

目前研究较多的固体氧化物电池用碳酸盐复合电解质体系中,碳酸盐在工作温度下的熔融状态使其稳定性受到质疑。本文通过聚丙烯酰胺溶胶凝胶法制得La0.9Sr0.1Ga0.8Mg0.2O2.85（LSGM）粉体与二元碳酸盐复合,制备了新型LSGM-碳酸盐复合电解质,从老化、循环和电池输出三方面考察了LSGM- (Li/Na)2CO3复合电解质的稳定性。在600℃、650 h的测试中,复合电解质的电导率长期稳定在0.07~0.09 S?cm-1;在室温~700℃循环中碳酸盐基本没有损失,电导率也较稳定;单电池在0.6 A?cm-2恒流放电,1 h内平均功率密度为256 mW?cm-2。     

医用镁及镁合金表面可生物降解有机高分子涂层的应用

近年来,镁及镁合金由于其生物可降解性和良好的生物相容性,在医疗器械领域的应用获得了迅速的发展,然而过快的降解速率限制了其在临床上的应用。可生物降解有机高分子涂层是一种降低镁及镁合金降解速率的有效表面改性方法,同时还可赋予镁及镁合金医疗器械多种功能性。首先综述了可降解有机高分子涂层对镁及镁合金耐腐蚀性能和生物相容性的影响。可降解聚合物涂层能阻碍腐蚀性介质与基体的接触,从而延长其降解时间。而涂层对基体的保护提供了碱性较弱的环境,更利于细胞的生长增殖;同时涂层随着基体一起降解,可降低聚合物长期存在生物体内可能引发炎症反应的风险。此外,对聚合物涂层在骨科以及心血管支架领域的应用以及进展进行了综述。一方面,可降解聚合物涂层能显著延长镁及镁合金在生物体内的作用时间;另一方面,涂层可以作为载体材料通过携带具有不同功能的试剂或者药物实现医疗器械的功能化,如促进骨愈合和药物的可控释放。因此,可降解聚合物涂层在镁和镁合金器械领域必将起到无可替代的作用。