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31.
Mitra DadvarMuhammad Sahimi 《Chemical engineering science》2002,57(6):939-952
Immobilized glucose isomerase is widely used for converting glucose to fructose by enzymatic isomerization. The process takes place in a packed-bed reactor consisting of mesoporous particles with distributed pore sizes and interconnectivities. Its efficiency is, however, significantly affected by deactivation of the mesoporous particles. In this paper, we study deactivation of the mesoporous particles using a three-dimensional pore network model of the pore space with distributed pore sizes and interconnectivities, and investigate several plausible mechanisms of deactivation of the porous particles. The results of the present study, which will be used as the input for simulation of the phenomenon at the reactor level, demonstrates the strong effect of the particles’ morphology on the deactivation process. 相似文献
32.
This study investigated the effects of viscosity ratio (p) and composition on morphology development in an immiscible polymer system mixed under chaotic flow conditions. It was seen that morphology of the dispersed phase developed through a widely accepted route involving transitions from lamellas to fibrils and to droplets. It was found in experiments with p≥1 that the dispersed phase converted into droplets very rapidly with narrow droplet size distribution when p∼1. For higher values of p, the speed of morphological transitions slowed down, the droplet size distribution became wider, and much larger droplets were formed. Similar effects were observed at higher concentration of the dispersed phase. No self-similar scaling behavior was observed in the droplet size distribution, which can be attributed to the lack of self-similarity in the breakup of lamellas into fibrils. 相似文献
33.
针对细胞图像的特点,提出一种改进的基于分水岭算法的细胞图像分割方法。在该方法中.对细胞图像进行数学形态学变换,即采用Top—hat变换后的图像与原始图像相加再减去Bottom—hat变换后的图像以得到最大对比度的图像.继而进行距离变换,最后运用分水岭算法进行分割。实验证明,该改进方法能够得到较好的分割结果。 相似文献
34.
Morphology and deformation behavior of binary blends comprising styrene/butadiene block copolymers (polystyrene content, ΦPS∼0.70) having different molecular architectures were studied by means of transmission electron microscopy and tensile testing. In contrast to the binary diblock copolymer blends discussed in literature, the phase separation behavior of the blends investigated was found to be strongly affected by asymmetric molecular architecture. The blends showed macrophase separated grains, in which the structures resembled the microphase morphology of none of the blend components. Unlike the classical rubber-modified or particle-filled thermoplastics, neither debonding at the particle/matrix interface nor the particle cavitation was observed in these nanostructured blends. The microdeformation of the blends revealed plastic drawing of polystyrene lamellae or PS struts dispersed in rubbery matrix and orientation of the whole deformation structures along the strain direction. 相似文献
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高压凝固对Al-Mg合金枝晶形态的影响 总被引:2,自引:0,他引:2
利用OLYMPUS光学显微镜研究了高压凝固对Al-9.6Mg合金枝晶形态的影响。结果表明,与常压下典型的破碎的粗大枝晶组织相比,高压凝固条件下,枝晶臂较完整,二次枝晶间距减小,并且大部分一次枝晶臂增长。从高压对成分过冷和热过冷的影响及溶质扩散角度探讨了枝晶形态的变化机理。高压这种极端凝固条件为改变合金的组织形态提供了一种新途径。 相似文献
38.
This paper examines a new concept of corrosion surface damage analysis by using the digital image processing. Corrosion phenomena are analyzed using a digital value for morphological surface damages instead of electrochemical methods. Initial images are characterized by three categories: color, texture and shape features. To calculate corrosion surface damages color we use the interpretation of HIS model. For the texture attributes, the method of co-occurrence matrix is used. Five types of corrosion damage are examined. Multidimensional scaling procedure is used to define the classification plane. This study suggests a probabilistic method of decision-making. This analysis develops a method for automated identification system of corrosion damages and is supposed to be more advantageous than that of electrochemical techniques. 相似文献
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Biomechanics of human head has been widely studied since several decades. At a mechanical level, the use of engineering allowed investigating injury mechanisms developing numerical models of adult head. For children, the problem is more difficult and evaluating child injury mechanisms using data obtained from scaling adult injury criteria does not account for differences in morphology and structure between adults and children. During growth, child head undergoes different modifications in morphology and structure. The present paper compares the anthropometry and numerical simulations of a child head model based on medical CT scans to a child head model developed by scaling an adult head model using the method proposed by Mertz [H.J. Mertz, A procedure for normalizing impact response data, SAE paper 840884, 1984]. These analysis point out significant differences showing that scaling down an adult head to obtain a child head does not appear relevant. Biofidelic and specific child geometry is needed to investigate child injury mechanisms. 相似文献