Phase separation studies in RIM polyurethanes catalyst and hard segment crystallinity effects

Polyurethanes were prepared from pure 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butane diol (BDO) or 1,2-ethane diol (EDO) and α,ω-hydroxyl poly(propylene oxide) (PPO) by reaction injection moulding (RIM). Hard segment (MDI + BDO or EDO) level was 45–50 wt%. The PPO had about 20% ethylene oxide copolymerized in at the chain ends to provide 80% primary OH end groups. M_n was varied from 2000 to 4000. Dibutyl tin dilaurate catalyst and mould temperature were varied. Dynamic mechanical, wide-angle X-ray, differential scanning calorimeter, molecular weight and tensile elongation measurements were made on the RIM polyurethanes. At low reaction rates (low catalyst or temperature) highly crystalline, well phase separated but low molecular weight polymers were produced. At high catalyst or temperature levels more poorly phase separated but high molecular weight, tough polymers resulted. Higher M_n PPO gave better phase separation and EDO gave higher melting temperatures. Preventing hard segment crystallinity by substituting asymmetric MDI or glycols resulted in phase compatibility.     

Head-to-head polymers: 33. Bromination of cis-1,4-polybutadiene to head-to-head poly(vinyl bromide)

Cis-1,4-polybutadiene (PB) in a 0.5% solution of a solvent mixture of dichloromethane and 1,2-dibromoethane or tetrahydrofuran was quantitatively brominated with elemental bromine at 0°C under careful exclusion of oxygen to head-to-head poly(vinyl bromide). Partially brominated PB has a structure of random or block sequences of butadiene units in the polymer depending on the bromination solvent but shows no stereospecificity in the CHBrCHBr-dyads. Partially brominated PB with block structure showed a microphase-separated morphology over a wide range of composition. Microphase separation is less pronounced for the more random structure of butadiene units. I.r and ¹³C n.m.r. spectroscopy of the partially brominated PB was used to follow the progress of the bromination.     

石英砂脱水性能的研究

通过大量试验结果 ,研究了各种粒度范围的石英砂的脱水性能 ,包括沉降特性、过滤性能、极限压缩浓度等 ,为进行此类产品的固液分离提供了重要的参考数据     

涡流管类比逆流换热器方法的研究

结合Scheper，Lewins和Bejan的理论模型，对涡流管类比逆流换热器模型进行了深入地分析，得出了冷流分量对温度分离效应的函数关系式，为了解涡流管机理和实验中强化涡流管温度分离效应提供了理论依据。     

应用烃类直接检测技术预测天然气藏

柴达木盆地位于青藏高原北部，是中国大型含油气盆地之一，历经４０年的勘探，发现了丰富的油气资源。柴达木盆地东部地区是第四纪沉降与沉积中心，区内第二系生储气岩厚度大、分布广、第四纪新构造运动形成的同生沉积构造发育、保存完整、具有形成大中型天然气田的地质条件。此外，由于该地区含气地层时代新、埋藏浅、成岩与胶结作用差、含气层厚度大、孔渗性好，加之构造条件简单，人文干扰小、是应用烃直接检测技术寻找天然气的有     

GL—2型Φ600mm螺旋选别攀枝花钛铁矿生产实践

攀矿选钛厂设计采用传统的螺旋选矿设备ＦＬＸ一１型φ６００ｍｍ螺旋选矿机和φ１２００ｍｍ螺旋溜槽，从选矿（铁）厂磁选尾矿物料中回收原生粒状钛铁矿积累了多年生产实践经验。而广东有色金属研究院研制的ＧＬ一２型φ６００ｍｍ螺旋选矿机具有处理能力大、分选效率高、选别粒级宽、不需冲洗水及占地面积小等特点，有取代选钛厂目前使用的螺旋选矿设备之趋势。     

Machining with tool–chip contact on the tool secondary rake face—Part II: analysis and discussion

The forces, chip thickness, and natural tool–chip contact length in machining with a double-rake-angled tool are predicted in Part II of the present study. It is revealed that in comparison with a single-rake-angled tool, a double-rake-angled tool increases the forces, especially the thrust force. However, the increase in chip thickness and tool–chip contact length is not significant under the input conditions specified in the present study. The effect of seven input variables of the proposed model is quantitatively investigated. The predicted variations of forces, chip thickness, and natural tool–chip contact length are in good agreement with theoretical and experimental results obtained by other researchers. The interrelationships among the resultant force, the chip thickness, and the natural tool–chip contact length are established, which provides a new and promising method to estimate the tool–chip contact length by employing the resultant force. It is demonstrated that the model can also be extended to study the problem of machining with a groove-type chip breaker tool.     

空分设备的酸性腐蚀及预防

以切换式换热器空分设备为例 ,分析了空分设备酸性腐蚀的原因、可能造成的危害 ,提出了预防措施。     

乙苯/苯乙烯塔分离效率问题的技术分析及整改措施

分析了齐鲁分公司200kt/a乙苯/苯乙烯装置乙苯/苯乙烯塔(T-401)分离效率低的原因,即降液管设计偏小,液体在降液管内流速过快,引起液体飞溅;安装分布器使用的石棉垫片溶胀而粉碎后堵塞了分布槽;分布器上使用的垫片脱落形成缝隙而漏液;填料装得不密实,留有缝隙;二级分布槽变形等.针对存在问题提出了相应的整改措施,并考察了整改措施实施效果.结果表明,整改后该塔的分离能力满足了工艺要求,并有一定的操作弹性.     

Enantioselective extraction of mandelic acid enantiomers based on chiral ligand exchange

Based on the chiral ligand exchange, the distribution behavior of mandelic acid enantiomers, and the partition of Cu^2 at different pH values were studied in a water/alcohol two-phase system containing Cu^2 and N-ndodecyl-L-proline(A). The influences of the solvent sort, the pH value, the concentrations of Cu^2 and chiral ligand on the partition coefficient(K) and separation factor(α) were discussed. The experimental results show that the A formed has more stable ternary complex with D-mandelic acid enantiomer than with L-mandelic acid enantiomer. There is an important influence of the pH value on K and a. When the pH values are less than 3.5, the formation of binary complexes is thermodynamically unfavourable. K and a become maximum when pH values are above 3.5 and the molar ratio of the chiral ligand to Cu^2 is 2:1.