铝电解用TiB_2阴极涂层固化、炭化的升温制度

采用DTG ,DDTA等热分析手段 ,研究了高温固化、炭化过程中 ,铝电解用TiB2 阴极涂层糊料的质量和能量的变化速率 ,制定了涂层的变速固化、炭化升温制度 ;在此基础上 ,研究了升温制度对TiB2 阴极涂层性能的影响。结果表明 :变速升温制度优于匀速升温制度 ,采用变速固化、炭化升温制度所制备的涂层形变小、无裂纹 ,其抗拉强度达 3.13MPa,电阻率为 2 3.2 μΩ·m ;而采用升温速度为 10 .3℃ /h的匀速固化、炭化升温制度制备的涂层形变大、裂纹多 ,抗拉强度小 (2 .6 9MPa) ,电阻率大 (2 8.6 μΩ·m)。     

Effects of temperature and blank holding force on biaxial forming behavior of aluminum sheet alloys

Biaxial forming behavior is investigated for three aluminum sheet alloys (Al 5182 containing 1% Mn (5182+Mn), Al 5754, and 6111-T4) using a heated die and punch in the warm forming temperature range of 200–350 °C. It is found that, while all three alloys exhibit significant improvement in their formability compared with that at room temperature, the non-heat-treatable alloys 5182 + Mn and 5754 give higher part depths than that of heat-treatable 6111-T4. The formability generally increases with decreasing BHP (BHP), but increasing the forming temperature and/or BHP minimizes the wrinkling tendency and improves the forming performance. The stretchability of the sheet alloys increase with increasing temperature and increasing BHP. For the alloys and forming conditions involved in the current study, the formability, measured in terms of part depth, comes mainly from the drawing of metal into the die cavity, although stretching effects do influence the overall forming behavior. The optimum formability is achieved by setting the die temperature 50 °C higher than the punch temperature to enhance the drawing component. Setting the die temperature higher than the punch temperature also improves the strain distribution in a part in such a manner that postpones necking and fracture by altering the location of greatest thinning.     

利用微波介电加热和微波干燥水解法制备TiO2微粒

利用微波介电加热和微波干燥条件下TiCl4直接水解的方法制备出平均尺寸为40m，粒径分布窄，均为球形且形态均一，团聚较少，金红石型的TiO2纳米粒子，其内部品粒平均大小为17nm。而传统加热和干燥条件下形成的纳米微粒平均为60nm，粒经大小不均一，形态较不规则，团聚严重。微波加热和干燥方法具有清洁、快速均匀高效、环境友好的优点，推广前景良好。TiCl4水解法经济便利，适于工业化生产。     

关于煤炭硫分分级的探讨

根据国家质量技术监督局的计划安排,国家标准GB／T15224－1994《煤炭质量分级》需要修订。本文主要讨论“煤炭硫分分级”方面的内容。     

自控温加热带的研制

研究了炭黑含量、辐照剂量以及体系共结晶性对以高密度聚乙烯/乙烯 丙烯酸乙烯酯共聚物为基材的自控温加热带电阻率及电热稳定性能的影响,以及加工条件和后处理工艺对材料电性能的影响。结果表明,50～80kGy的辐照剂量为本体系提供优异的电热稳定性,适当的加工及后处理工艺能大大改善该体系的导电性。     

6m大容积焦炉烘炉实践与体会

介绍了 6 m大容积焦炉由冷态到转入正常加热温度的烘炉操作过程中 ,按照一定的升温曲线 ,通过对焦炉热工和炉体膨胀的科学管理 ,确保新建焦炉顺利由冷态过渡到生产状态。     

Time dependences of conduction and self‐heating in acetylene carbon black‐filled high‐density polyethylene composites

The time dependences of electrical conduction and self‐heating behaviors in high‐density polyethylene filled with acetylene carbon black of 0.082 in volume fraction are studied in relation to voltage and ambient temperature. The characteristic decay current constant τ_i, and the exponential growth time constant for self‐heating τ_g are determined for the samples under voltages U above the critical value U_c for the onset of self‐heating. The influences of voltage and ambient temperature on τ_i and τ_g as well as the amplitude of the low‐resistance to high‐resistance switching are discussed on the basis of the random resistor network (RRN) model and the relationship between U_c and the intrinsic resistivity. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1124–1131, 2006     

Effect of test frequency and water content on localized crack-tip heating in nylon-6,6

Fatigue crack propagation (FCP) tests were conducted at various frequencies on nylon-6,6 specimens equilibrated over a range of moisture levels to determine the crack growth rates and the crack-tip temperatures as a function of water content. Frequency-sensitivity was correlated with the amount of crack-tip heating taking place, with crack-tip temperature being found to depend strongly on the estimated loss compliance, D″, of the material. The frequency-sensitivity of FCP in nylon was seen also to be affected by mean stress, suggesting that creep processes are often significant in FCP of nylon.     

串联感应加热电源相角保护

数字感应加热电源在工业中一般采用串联负载与PFM调功方式。串联负载谐振与PFM调功方式要求逆变器频率稳定工作在感性区,但在实际工作过程中逆变器频率可能会由感性区越过谐振点滑入容性区,引起逆变器发生"炸管"现象。为了防止"炸管"现象的发生,在谐振点附近的感性区设置限相区,当频率进入限相区经PI处理使其稳定工作在感性区达到保护逆变器的目的。通过DSP实验平台测试,限相区的设置可以很好的保护逆变器使其稳定工作在感性区。     

小型密闭压力容器法中试验条件对分解反应程度的影响

(dp/dt)max是小型密闭压力容器法（MCPVT）中用来表征自反应物质受热分解反应激烈程度的物理量。本文在大量实验的基础上，通过线性回归推导出了X（样品容器容积V、升温速率R及样品质量m）与（dp/dt)max的数学关系式，已知X0时的(dp/dt)max0,就可求得任意X下的（dp/dt)max，与实测值比较，结果表明，利用该关系式计算的结果较为可靠，从而为MCPVT最终成为国际上评价自反应物质受热分解反应激烈程度标准方法奠定了基础。