Mesoporous Hollow Sb/ZnS@C Core–Shell Heterostructures as Anodes for High‐Performance Sodium‐Ion Batteries

Combining the advantage of metal, metal sulfide, and carbon, mesoporous hollow core–shell Sb/ZnS@C hybrid heterostructures composed of Sb/ZnS inner core and carbon outer shell are rationally designed based on a robust template of ZnS nanosphere, as anodes for high‐performance sodium‐ion batteries (SIBs). A partial cation exchange reaction based on the solubility difference between Sb₂S₃ and ZnS can transform mesoporous ZnS to Sb₂S₃/ZnS heterostructure. To get a stable structure, a thin contiguous resorcinol‐formaldehyde (RF) layer is introduced on the surface of Sb₂S₃/ZnS heterostructure. The effectively protective carbon layer from RF can be designed as the reducing agent to convert Sb₂S₃ to metallic Sb to obtain core–shell Sb/ZnS@C hybrid heterostructures. Simultaneously, the carbon outer shell is beneficial to the charge transfer kinetics, and can maintain the structure stability during the repeated sodiation/desodiation process. Owing to its unique stable architecture and synergistic effects between the components, the core–shell porous Sb/ZnS@C hybrid heterostructure SIB anode shows a high reversible capacity, good rate capability, and excellent cycling stability by turning the optimized voltage range. This novel strategy to prepare carbon‐layer‐protected metal/metal sulfide core–shell heterostructure can be further extended to design other novel nanostructured systems for high‐performance energy storage devices.     

Pseudocapacitive Sodium Storage by Ferroelectric Sn2P2S6 with Layered Nanostructure

Sodium ion batteries (SIB) are considered promising alternative candidates for lithium ion batteries (LIB) because of the wide availability and low cost of sodium, therefore the development of alternative sodium storage materials with comparable performance to LIB is urgently desired. The sodium ions with larger sizes resist intercalation or alloying because of slow reaction kinetics. Most pseudocapacitive sodium storage materials are based on subtle nanomaterial engineering, which is difficult for large‐scale production. Here, ferroelectric Sn₂P₂S₆ with layered nanostructure is developed as sodium ion storage material. The ferroelectricity‐enhanced pseudocapacitance of sodium ion in the interlayer spacing makes the electrochemical reaction easier and faster, endowing the Sn₂P₂S₆ electrode with excellent rate capability and cycle stability. Furthermore, the facile solid state reaction synthesis and common electrode fabrication make the Sn₂P₂S₆ that becomes a promising anode material of SIB.     

Modulated Triple‐Material Nano‐Heterostructures: Where Gold Influenced the Chemical Activity of Silver in Nanocrystals

For efficient charge separations, multimaterial hetero‐nanostructures are being extensively studied as photocatalysts. While materials with one heterojunction are widely established, the chemistry of formation of multijunction heterostructures is not explored. This needs a more sophisticated approach and modulations. To achieve these, a generic multistep seed mediated growth following controlled ion diffusion and ion exchange is reported which successfully leads to triple‐material hetero‐nanostructures with bimetallic‐binary alloy‐binary/ternary semiconductors arrangements. Ag₂S nanocrystals are used as primary seeds for obtaining AuAg‐AuAgS bimetallic‐binary alloyed metal–semiconductor heterostructures via partial reduction of Ag(I) using Au(III) ions. These are again explored as secondary seeds for obtaining a series of triple‐materials heterostructures, AuAg‐AuAgS‐CdS (or ZnS or AgInS₂), with introduction of different divalent and trivalent ions. Chemistry of each step of the gold ion–induced changes in the rate of diffusion and/or ion exchanges are investigated and the formation mechanism for these nearly monodisperse triple material heterostructures are proposed. Reactions without gold are also performed, and the change in the reaction chemistry and growth mechanism in presence of Au is also discussed.     

Facile synthesis of rutile TiO2/carbon nanosheet composite from MAX phase for lithium storage

Titanium oxide (TiO₂), with excellent cycling stability and low volume expansion, is a promising anode material for lithium-ion battery (LIB), which suffers from low electrical conductivity and poor rate capability. Combining nano-sized TiO₂ with conductive materials is proved an efficient method to improve its electrochemical properties. Here, rutile TiO₂/carbon nanosheet was obtained by calcinating MAX (Ti₃AlC₂) and Na₂CO₃ together and water-bathing with HCl. The lamellar carbon atoms in MAX are converted to 2D carbon nanosheets with urchin-like rutile TiO₂ anchored on. The unique architecture can offer plentiful active sites, shorten the ion diffusion distance and improve the conductivity. The composite exhibits a high reversible capacity of 247 mA h g⁻¹, excellent rate performance (38 mA h g⁻¹ at 50 C) and stable cycling performance (0.014% decay per cycle during 2000 cycles) for lithium storage.     

Ultralow Expansion Glass as Material for Advanced Micromechanical Systems

Ultralow expansion (ULE) glasses are of special interest for temperature stabilized systems for example in precision metrology. Nowadays, ULE materials are mainly used in macroscopic and less in micromechanical systems. Reasons for this are a lack of technologies for parallel fabricating high-quality released microstructures with a high accuracy. As a result, there is a high demand in transferring these materials into miniaturized application examples, realistic system modeling, and the investigation of microscopic material properties. Herein, a technological base for fabricating released micromechanical structures and systems with a structure height above 100 μm in ULE 7972 glass is established. Herein, the main fabrication parameters that are important for the system design and contribute thus to the introduction of titanium silicate as material for glass-based micromechanical systems are discussed. To study the mechanical properties in combination with respective simulation models, microcantilevers are used as basic mechanical elements to evaluate technological parameters and other impact factors. The implemented models allow to predict the micromechanical system properties with a deviation of only ±5% and can thus effectively support the micromechanical system design in an early stage of development.     

一种新型筒形矿仓物位测量方案的设计

针对常用的矿仓物位测量方式受粉尘和堆矿死角因素的影响而存在矿仓物位测量不准确的问题,提出了一种新型的矿仓物位测量方案。该方案选择重锤物位计消除粉尘干扰、采用多点布局求取均值的方法消除堆矿死角干扰。实际应用表明,该方案解决了粉尘和堆矿死角对物位测量的影响,降低了矿仓岗位人员的劳动强度。     

基于OpenGVS半潜船操作模拟器视景系统的研究

为了满足半潜船作业人员学习和培训的需要,有必要在航海模拟器大环境下研发半潜船操作模拟器仿真系统。以船舶静力学为基础,实现了半潜船装载重大件货物的过程的动态稳性计算,以Visual C++6.0和OpenGVS场景管理软件为开发平台,研制开发了半潜船操作模拟器应具备的视景系统。该仿真系统实现了视点的转移和跟踪,通过设置在半潜船的驾驶台、甲板及外部三个虚拟相机,实时动态显示半潜船各种运动的状态,同时实现了半潜船操作模拟器几个模块间的相互通信,取得了很好的效果。     

Information transmittal, Newton’s law of gravitation, and tensor approach to general relativity

The special relativity considered in [A. Einstein, Zur Elektrodynamik der bewegte Körper. Ann. Physik, 17 (1905) 891-921] is based on the concept of finite speed of information transmittal by the available signals (rays of light). It is demonstrated that the same concept applies to Newton’s law of universal gravitation since the magnitude of distances between attracting masses can be physically defined (carried, accounted in acting forces of gravity) only by signals (physical processes) propagating at finite velocities. It follows that the speed of propagation of gravity is finite. The linear transformations of special relativity are applied to Newton’s law of gravitation to take into account the relativistic effects of information transmittal in a field of central forces of attraction. Relativistic representations of Newton’s law are obtained with respect to the center of gravity exposing illusory effects that appear at high velocities. It is verified that in atomic physics the effect of Newtonian gravitation on the motion of elementary particles at high velocities is negligible also in relativistic consideration. Computational methods are developed to measure the intensity of gravitation at a distant space-time location using a body that travels in space, emitting uniform pulses of light that are received by the observer at a different space-time location. It is demonstrated that the tensor approach to the general relativity and the united theory of space, time and gravitation in which the geometrical properties (metric) of the four-dimensional space-time continuum depend on the distribution of gravitating masses in space and their motion represent a transformed Lorentz invariant with a new type of inertia in the field of forces changing in space and time. Real physical processes evolve according to the forces represented in the tensor form by this invariant which is equivalent to the coordinate-free local invariant of relativistic dynamics that defines the field and the motion of a body whose velocities and accelerations can be measured by relativistic identification methods at a point, time and direction of interest. The results open new avenues for research in the general relativity and can be used for software development, field measurements and experimental studies in application to distant or fast moving systems.     

A highly selective triphenylamine-based indolylmethane derivatives as colorimetric and turn-off fluorimetric sensor toward Cu detection by deprotonation of secondary amines

A new triphenylamine-based fluorogenic probe bearing an indolylmethane unit (R1) was developed as a fluorescent chemosensor with high selectivity toward Cu²⁺ over other cations tested. The new probe R1 only sensed Cu²⁺ among heavy and transition metal (HTM) ions in CH₃CN/H₂O (70/30, v/v) solution. The capture of Cu²⁺ by the receptor resulted in deprotonation of the secondary amine conjugated to the triphenylamine, so that the electron-donation ability of the “N” atom would be greatly enhanced; thus sensor showed a 250 nm change in the new absorption band (from 291 nm to 541 nm) and a large colorimetric response, it also exhibited the large decrease in fluorescence intensity at 378 nm and affinity to Cu²⁺ over other cations such as Hg²⁺, Fe³⁺, Pb²⁺, Zn²⁺, Cd²⁺, Ni²⁺, Co²⁺ and Mn²⁺ make this compound a useful chemosensor for Cu²⁺ detection in CH₃CN/H₂O (70/30, v/v) mixture. The probe R1 (c = 1.0 × 10⁻⁶ M) displayed significant fluorescence change and colorimetric change upon addition of Cu²⁺ among the metal ions examined.