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971.
饮用水氯化中氯仿形成的动力学模式 总被引:12,自引:0,他引:12
以黄腐酸(FA)为卤仿前驱物质,分别测定不同投氯量、TOC水平、温度以及pH值对CHCl3形成速率的影响,确定出CHCl3形成的动力学模式。该模式可用于预测投氯后的管网水中CHCl3的形成量,以便采取必要措施保证饮用水符合国家规定CHCl3〈60μg/L的标准。 相似文献
972.
973.
液相对流对固液界面稳定性的影响 总被引:1,自引:0,他引:1
以模型合金丁二腈-乙醇的强制性晶体生长为基础,利用自行研制的液相对流驱动装置,详细考查了液相自然对流及强迫对流作用下,模型合金平界面失稳的动态生长过程,证实了液相的流动加快了液相温度与浓度分布的均匀化,从而增强了液/固界面的稳定性。并且随流动速度的增加,界面稳定性提高。 相似文献
974.
N. M. Wereley T. F. Zahrah F. H. Charron 《Journal of Materials Engineering and Performance》1993,2(5):671-682
Intelligent processing of materials (IPM) deals with the integration of process models and in situ sensors into an intelligent
process controller to achieve desired material properties. IPM-based control systems recently have been developed for both
consolidation and solidification processes. This article explores the application of models based on the finite- element method
(FEM) to develop process actuation systems, to design process schedules and component shape, and to develop a control model
with which to control the process.
The results in this article were presented at the AeroMat ’93 Advanced Aerospace Materials/Processes Conference and Exposition,
Anaheim, CA, 7–10 June 1993 相似文献
975.
Fischer-Tropsch synthesis on Fe-Mn ultrafine catalysts 总被引:2,自引:0,他引:2
The Fischer-Tropsch (FT) synthesis on Fe-Mn ultrafine catalysts prepared by a special degradation method of Fe-Mn complexes is presented. The effects of preparation method and Mn content on the FT performance are examined and the active phases and the role of Mn are elucidated. 相似文献
976.
Studies of the complete oxidation of methane on a Pt electrode-catalyst in the cell with a solid proton-conducting electrolyte (CH4 + O2, Pt ¦ SrCe0.92Dy0.08O3 ¦ Pt, H2O + N2) were carried out. The non-Faradaic effect of electrochemical hydrogen pumping on the rate of methane oxidation has been demonstrated. The induced change in the reaction rate at anodic polarization of a Pt electrode-catalyst was over two orders of magnitude higher than the rate of hydrogen pumping from the reaction zone through the electrolyte. 相似文献
977.
In this work, (a) complexation reaction of zirconium tetra-n-butylate, Zr(OBu
n
)4, with MAc and different organic acids, (b) the hydrolysis reaction of modified Zr species, and (c) the polymerization reaction of complex products are studied. Zr(OBu
n
)4 was reacted with different mole ratios of methacrylic acid (MAc) at room temperature and the maximum combination ratio was found to be 1:2 [Zr(OBu
n
)4:MAc] by FT-IR. The modification of zirconium tetra-n-butylate with the acid mixtures [methacrylic acid-acetic acid (MeCOOH), methacrylic acid-propionic acid (EtCOOH), methacrylic acid-butyric acid (PrCOOH)] was made for a combination ratio of 1:1:1 [MAc:RCOOH:Zr(OBu
n
)4; R: Me, Et, Pr] and the products were characterized by1H-NMR, FT-IR, and UV spectroscopies. Following their synthesis, hydrolysis of the complexes with various amounts of water and polymerization with benzoyl peroxide were realized. The hydrolysis and polymerization products of the complexes were studied by Karl-Fischer coulometric titration and thermal analysis, respectively. Methyl ethyl ketone(MEK) and chloroform were chosen as solvents. 相似文献
978.
Cregut D.; Liautard J.P.; Chiche L. 《Protein engineering, design & selection : PEDS》1994,7(11):1333-1344
Annexin I homology models were built from the annexin V crystalstructure. Three methods for side-chain prediction were testedbased on molecular mechanics conformational search, the useof a rotamer database, or a combination of these two methods.We showed that rotamer-based methods were more efficient andthat molecular mechanics energy minimizations, prior to rotamerselection, did not afford clearly improved predictions. Modelsbuilt in vacuo and with an implicit solvation term were comparedwith the annexin I crystal structure which became availableduring the course of this study. The analysis of solvation energies,root mean square deviations, Xi angles and hydrogen bonds showedthat models built with implicit solvation were of better quality.In annexin V, repeat III displays A-B and D-E loop conformationsquite different from other repeats. Since the sequence differencessuggest that repeat III in annexin I might present a conformationsimilar to other repeats, two annexin I models with differentrepeat III conformations were built and compared to determinewhether the correct conformation could have been predicted.We show that using a combination of evaluation criteria, itis possible to discriminate unequivocally between the nativeand the incorrect fold, stressing that only one criterion shouldnot be used to evaluate protein structures. 相似文献
979.
The decomposition of NO and of N2O over a CuZSM-5 zeolite and a Fe-mordenite, respectively, has been studied using tracer techniques. The results demonstrate the high mobility of the lattice oxygen ions in self-diffusion. They afford a possible explanation for the problem of how two extralattice oxygens located at positions remote from each other may combine to form the O2 molecules which are spontaneously desorbed in these redox reactions. They show that a portion of the lattice oxygen mixes into the O2 released on decomposition. The data also show that N18O and N2
18O undergo exchange with the catalyst oxygen under reaction conditions.On leave from Central Research Institute for Chemistry, Hungarian Academy of Sciences, H-1525 Budapest, Hungary. 相似文献
980.
In Part 1 of this two-part series, we introduced Katamic memory—a neural network architecture capable of robust sequence learning and recognition. In Part 2, we introduce the Blobs World taskjdomain for language learning and describe the DETE language learning system, which is composed of over 50 Katamic memory modules. DETE currently learns small subsets of English and Spanish via association with perceptual! motor inputs. In addition to Kaiamic memory, DETE employs several other novel features: (1) use of feature planes, to encode visual shapes, spatial relationships and the motions of objects, (2) phase-locking of neural firing, in order to represent focus of atention and to bind objects across multiple feature planes, and (3) a method for encoding temporal relationships, so that DETE can learn utterances involving the immediate past and future. We compare DETE to related models and discuss the implications of this approach for language-learning research. 相似文献