除氧器复合钢板的对接焊接工艺

分析了用于制造除氧器的不锈钢复合板的焊接工艺.对SA516Gr70+SA240TP304不锈钢复合板采用新的SAW加FCAW焊接工艺,并将其与原SAW加SMAW焊接工艺进行对比.对由这两种焊接工艺得到的焊接接头试样进行金相组织和力学性能试验.试验结果表明,新焊接工艺可获得性能良好的对接接头,焊接接头各个截面上微观组织结...     

茶多酚改性天然胶乳复合材料的制备及性能研究

以多羟基结构的茶多酚作界面改性剂,制备了埃洛石纳米管/天然胶乳复合材料及二氧化硅/天然胶乳复合材料,研究了茶多酚对复合材料界面作用及力学性能的影响。结果表明,茶多酚分别能与埃洛石纳米管和二氧化硅形成氢键,改善了填料与橡胶基体间的界面作用。茶多酚改性天然胶乳复合材料的力学性能显著提高,其原因归因于复合材料界面状态的改善。     

利用剩余高程异常模型建立阳山矿区GPS高程转换算法

随着卫星重力测量技术的不断完善和发展,使得利用重力场模型进行GPS点高程转换的精度和可靠性都获得了极大提升。文章利用SRTM、DTM2006.0模型和EGM2008模型求得阳山矿区GPS点剩余高程异常,并进行残余高程异常拟合,建立阳山矿区剩余高程异常转换计算方法。在对阳山矿区22个D级GPS点,48个E级GPS点的高程数据进行比较后,发现此方法转换最高精度能达到2.8 cm,最差精度为4.4cm,平均精度为3.2 cm,从而证明了此方法可以提高阳山矿区GPS高程转换的精度。     

A New Flame Retardant for Wood Materials Tested in Wood‐Plastic Composites

A new flame retardant based on an ammonium phosphonate is studied with respect to its thermal decomposition and its mode of action in wood‐plastic composites (WPCs). The measurements are carried out by means of fire tests (cone calorimeter) and pyrolysis investigations (thermogravimetry, infrared spectroscopy). The flame retardant acts mainly in the condensed phase by increasing the amount of residue formed by the wood part in the WPC. Additional flame dilution is achieved by the release of water, ammonia and carbon dioxide during the decomposition of the flame retardant.

     

Studies on Removal of Low Content Copper from the Sea Nodule Aqueous Solution using the Cationic Resin TP 207

Selective removal of copper remaining in the raffinate, obtained after solvent extraction of copper with LIX 84-I from the sea nodule leach solution, containing 0.512 g/L Cu(II), 0.212 g/L Fe(III), 15.16 g/L Ni(II), and 2.012 g/L Co(II), was carried out with TP 207, in the batch and column adsorption system. The operational factors affecting the copper adsorption such as initial copper ion concentration (0.05–1.0 g/L), pH (1–4 Jie , W.J. ; Xiu , Z.Q. ; Qing , Z.G. ; Ying , C.Z. ( 2010 ) Deep removal of copper from cobalt sulfate electrolyte by ion-exchange . T. Nonferr. Metal Soc. , 20 : 1534 – 1540 . Zhong , C.Q. ; Kang , M.X. ; Yan , M.A. ; Xia , Z.C. ( 2005 ) A Method of Removing Copper from Cobalt Electrolyte . [P] CN1598013A , 3 – 23 . (In Chinese). Nam , C.W. ; Kim , B.S. ; Park , K.H. ( 2003 ) Recovery of cobalt, nickel from manganese nodules by reduction roasting and smelting . Korean Soc. Geosyst. Eng. , 40 : 191 – 197 . Nam , C.W. ; Park , K.H. ; Kim , H.I. ( 2004 ) Sulphuric acid pressure leaching of Cu-Ni-Co-Fe matte . Korean Soc. Geosyst. Eng. , 419 : 413 – 417 . ), resin dosage (5–100 g/L), and temperature (293–338 K) were investigated. Adsorption of copper was found to be maximum at an equilibrium pH of 1.97 without any adsorption of other metal ions in the solution and was strongly affected by the resin dosage. Adsorption equilibrium data was well fitted with the Langmuir isotherm, and the monolayer adsorption capacity of copper ion was determined as 68.7 mg g^?1, at 298 K. The positive values of ΔH^o (11.5, 10.4, and 10.1 kJ mol^?1) determined at corresponding initial copper concentrations: 0.1, 0.3, and 0.5 g/L, respectively, in the solution, indicated that the adsorption was endothermic in nature. Kinetic studies confirmed that the adsorption of copper followed pseudo second order reaction with intra particle diffusion.     

复配混凝剂强化处理生活污水试验研究

择优选取对TP及COD去除效果均较优的3种混凝剂AlCl_3、FeCl_3、Fe_2(SO_4)_3,以依次投加的方式进行复配,考察了复配混凝剂对生活污水中TP和COD的去除效果及影响因素。研究结果表明,当复配混凝剂按m(AlCl_3)∶m(FeCl_3)∶m〔Fe_2(SO_4)〕=5∶6∶7投加时,对污染物的去除效果最好;pH是影响污染物去除效果的关键因素;在最佳配比条件下,当复配混凝剂投加量为160 mg/L时,出水TP可达0.402 mg/L,达到《城镇污水处理厂污染物排放标准》(GB 18918—2002)的一级A标准,COD去除率比单一混凝剂高12.9%~20.1%。     

珠三角地区A~2O工艺和倒置A~2O工艺运行效果研究

对A2O工艺和倒置A2O工艺处理珠三角地区生活污水的效果进行对比研究。结果表明,2种工艺出水水质均能稳定达到排放限值要求,适合生活污水的深度处理。倒置A2O工艺的NH3-N去除率显著高于A2O工艺,但TP去除效率显著低于A2O工艺,TN去除效率不存在显著差异,但倒置A2O工艺出水TN质量浓度较A2O工艺稳定,在TN去除方面具有较强的抗冲击能力及稳定性。分析了影响2种工艺脱氮除磷效果的因素,并提出改进建议,为同类型污水处理厂工艺改进提供参考。     

Silicate-based polymer-nanocomposite membranes for polymer electrolyte membrane fuel cells

Proton-exchange membrane fuel cells have emerged as a promising emission free technology to fulfill the existing power requirements of the 21st century. Nafion^® is the most widely accepted and commercialized membrane to date and possesses excellent electrochemical properties below 80 °C, under highly humidified conditions. However, a decrease in the proton conductivity of Nafion^® above 80 °C and lower humidity along with high membrane cost has prompted the development of new membranes and techniques. Addition of inorganic fillers, especially silicate-based nanomaterials, to the polymer membrane was utilized to partially overcome the aforementioned limitations. This is because of the lower cost, easy availability, high hydrophilicity and higher thermal stability of the inorganic silicates. Addition of silicates to the polymer membrane has also improved the mechanical, thermal and barrier properties, along with water uptake of the composite membranes, resulting in superior performance at higher temperature compared to that of the virgin membrane. However, the degrees of dispersion and interaction between the organic polymer and inorganic silicates play vital roles in improving the key properties of the membranes. Hence, different techniques and solvent media were used to improve the degrees of nanofiller dispersion and the physico-chemical properties of the membranes. This review focuses mainly on the techniques of silicate-based nanocomposite fabrication and the resulting impact on the membrane properties.     

大直径奥氏体不锈钢无缝钢管的试制

介绍了大直径奥氏体不锈钢无缝钢管的试制情况,以及在开发过程中采用的一些思路。在管坯制造阶段,将管坯锻造锻压比控制在3.0～3.5;在穿孔轧制阶段,采用专业3D设计软件对穿孔参数进行模拟和计算;穿孔顶头通过表面处理、涂抹润滑剂,并结合内水冷的方式提高寿命;设计制造出穿孔机组合导板,从而降低生产大直径奥氏体不锈钢钢管的工具成本。对试制出的成品管进行了化学成分、机械性能、晶粒度和晶间腐蚀试验分析,产品各项指标均满足ASMESA312/SA312M——2007《无缝和焊接奥氏体不锈钢公称管》标准要求。     

运用粒子图像测速仪研究双层桨搅拌槽内流体流动

The flow fields in a dual Rushton impeller stirred tank with diameter of 0.48 m （T） were measured by using Particle Image Velocimetry （PIV）. Three different size impellers were used in the experiments with diameters of D = 0.33T, 0.40T and 0.50T, respectively. The multi-block and 360° ensemble-averaged approaches were used to measure the radial and axial angle-resolved velocity distributions. Three typical flow patterns, named, merging flow, parallel flow and diverging flow, were obtained by changing the clearance of the bottom impeller above the tank base （C1） and the spacing between the two impellers （C2）. The results show that while C1 is equal to D, the parallel flow occurs as C2≥0.40T, C2≥0.38T and C2≥0.32T and the merging flow occurs as C2≤0.38T, C2≤0.36T and C2≤0.27T for the impellers with diameter of D=0.33T, 0.40T and 0.50T, respectively. When C2 is equal to D, the diverging flow occurs in the value of C1≤0.15T for all three impellers. The flow numbers of these impellers were calculated for the parallel flow. Trailing vortices generated by the lower impeller for the diverging flow were shown by the 10° angle-resolved velocity measurements. The peak value of turbulence kinetic energy （ k/V^2tip = 0.12-0.15 or above） appears along the center of the impeller discharging stream.