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101.
102.
The effect of the geometrical and operational parameters on the mixing characteristics of a Couette–Taylor vortex flow reactor (CTVFR) were investigated and were correlated with the same parameters by using the tank‐in‐series model. Continuous emulsion polymerization of styrene was conducted at 50°C in a CTVFR to clarify the effects on kinetic behavior and reactor performance of operational parameters such as rotational speed of inner cylinder (Taylor number), reactor mean residence time, and emulsifier and initiator concentrations in the feed streams. It was found that steady‐state monomer conversion and particle number could be freely varied only by varying the Taylor number. In order to explain the observed kinetic behavior of this polymerization system, a mathematical model was developed by combining the empirical correlation of the mixing characteristics of a CTVFR and a previously proposed kinetic model for the continuous emulsion polymerization of styrene in continuous stirred tank reactors connected in series (CSTRs). On the basis of these experimental results, it was concluded that a CTVFR is suitable for the first reactor (prereactor) of a continuous emulsion polymerization reactor system. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 1931–1942, 2001 相似文献
103.
Zhenping Liu Alberto Passalacqua Michael G. Olsen Rodney O. Fox James C. Hill 《American Institute of Chemical Engineers》2016,62(7):2570-2578
The multi‐inlet vortex reactor (MIVR) is used for flash nanoprecipitation to manufacture functional nanoparticles. A validated computational fluid dynamics model is needed for the design, scale‐up, and optimization of the MIVR. Unfortunately, available Reynolds‐averaged Navier‐Stokes methods are unable to accurately model the highly swirling flow in the MIVR. Large‐eddy simulations (LES) are also problematic, as excessively fine grids are required to accurately model this flow. These dilemmas led to the application of the dynamic delayed detached eddy simulation (DDES) method to the MIVR. In the dynamic DDES model, the eddy viscosity has a form similar to the Smagorinsky sub‐grid viscosity in LES, which allows the implementation of a dynamic procedure to determine its model coefficient. Simulation results using the dynamic DDES model are found to match well with experimental data in terms of mean velocity and turbulence intensity, suggesting that the dynamic DDES model is a good option for modeling the turbulent swirling flow in the MIVR. © 2016 American Institute of Chemical Engineers AIChE J, 62: 2570–2578, 2016 相似文献
104.
Scientific literature of agromaterial drying present contradictory conclusions in terms of the kinetic effect of airflow velocity. Some authors confirmed that it does not trigger any modification of drying, while some articles tried to establish empirical models of the effective diffusivity Deff versus the airflow velocity, what is fundamentally erroneous. By analyzing internal and external transfer phenomena, this research aimed at recognizing that once air velocity is higher than a critical airflow velocity (CAV), the internal transfers become the limiting phenomenon. CAV depends on the effective diffusivity and the product size. It was calculated in the cases of two studied raw materials (apple and carrot), differently textured by instant controlled pressure drop (DIC). Values of CAV greatly depend on diffusivity of water within the matrix. At temperature T?=?40°C, they were 1?m/s for untreated carrot and 2.1?m/s for DIC-textured carrot, whose Deff values were 1.31 and about 3?×?10?10?m2/s, respectively. Also, at temperature T?=?40°C, they were 2.1?m/s for untreated apple and 3?m/s for DIC-textured apple, whose Deff were 1.4 and about 10.4?×?10?10?m2/s, respectively. 相似文献
105.
Kaustav Niyogi Maria M. Torregrosa Guy B. Marin Geraldine J. Heynderickx Vladimir N. Shtern 《American Institute of Chemical Engineers》2018,64(5):1859-1873
The hydrodynamics of secondary flow phenomena in a disc‐shaped gas vortex unit (GVU) is investigated using experimentally validated numerical simulations. The simulation using ANSYS FLUENT® v.14a reveals the development of a backflow region along the core of the central gas exhaust, and of a counterflow multivortex region in the bulk of the disc part of the unit. Under the tested conditions, the GVU flow is found to be highly spiraling in nature. Secondary flow phenomena develop as swirl becomes stronger. The backflow region develops first via the swirl‐decay mechanism in the exhaust line. Near‐wall jet formation in the boundary layers near the GVU end‐walls eventually results in flow reversal in the bulk of the unit. When the jets grow stronger the counterflow becomes multivortex. The simulation results are validated with experimental data obtained from Stereoscopic Particle Image Velocimetry and surface oil visualization measurements. © 2018 The Authors AIChE Journal published by Wiley Periodicals, Inc. on behalf of American Institute of Chemical Engineers AIChE J, 64: 1859–1873, 2018 相似文献
106.
在T型对撞反应器的基础上,对其结构进行改进,设计了旋流锥型对撞、T型旋撞和旋流锥型旋撞(二次旋转)3种撞击流反应器。用化学吸收法测量了这几种不同结构的微反应器在气液二相逆流接触条件下平均相界比表面积α及液相吸收传质系数kL;进而分析了反应器进口结构、尺寸和流体流量等条件对传质性能的影响。结果表明:旋撞比直撞的传质系数大,二次旋撞的比一次旋撞的传质系数要大;撞击区进口尺寸越小,气液流体的流量越大,反应器的传质系数越大;液相传质系数较常规气液接触设备的至少高1—2个数量级,其传质强化的原因主要源于微反应器内相界比表面积大幅度地增加。 相似文献
107.
通过料垛码法形成的气流通道大小对倒焰式燃气窑内气流分布以及温度均匀性的影响进行了分析,认为在一定的条件下,通道大小与气体流动速度和流量成正比,根据这一结论,可对倒焰燃气窑内料垛码法起到一定的指导作用。 相似文献
108.
在自建的冷态横流-旋流喷雾两相掺混系统实验台上,采用PIV测量了掺混通道内气液两相掺混过程中液滴群的运动特性,获得了掺混流场中不同位置的液滴分布图像与流场结构特性。实验段结构为方腔(横截面尺寸为95 mm×95 mm),喷嘴采用空心锥形雾化喷嘴。对影响掺混效果的主要参数(横流速度、喷嘴雾化压力、喷嘴雾化粒径)进行了详细研究,绘出了最佳掺混效果下各参数关系曲线。掺混过程主要受不同尺度的旋涡结构影响,液滴多富集于旋涡边缘,稳定的大尺度涡不利于掺混。提高掺混效果的途径即是避免流场中出现稳定的大尺度旋涡结构,采用喷嘴前倾布置、增加喷嘴个数、确定合适的横流速度均是提高掺混效果的有效途径。分析方法与研究结果为工程实际应用中掺混室结构的设计及掺混性能的改进提供了依据和参考。 相似文献
109.
本文比较系统地研究了不同形状、尺寸的收尘极板电流密度分布及背部涡流结构,其结果表明:板型、板宽及回风沟槽高度对电流密度分布具有很大的影响;板宽对背部涡流结构具有明显的影响;而板型及回风沟槽高度对背部涡流几乎没有影响.通过比较分析,选出了一种比较理想的极板形状和尺寸. 相似文献
110.
本文利用渗流理论和管路漏流流动规律及采空区与相邻风流通道交界面上的力学关系、流量关系,建立了一整套采场风流参数计算数学模型,并介绍了解算采空区风流参数的有限元方法。利用现场实测流量结果作为边界条件进行了计算、计算所得采空区边界上的压力值与实测值吻合很好。 相似文献