Architectural Control of Hierarchical Nanobelt Superstructures in Catanionic Reverse Micelles

BaXO₄ (X = Mo, W) nanobelts and a variety of hierarchical superstructures assembled from the nanobelts have been synthesized in a catanionic reverse‐micelle system. The effects of various factors, such as the mixing ratio (r) between the anionic and cationic surfactants, the temperature, and the presence of polymeric additives, on the formation of the nanobelts and their hierarchical assembly have been examined in detail. In particular, r has been shown to be powerful in modulating the formation and assembly of the BaMoO₄ and BaWO₄ nanobelts. Architectural control of the penniform nanobelt superstructures has been readily achieved by changing the experimental parameters. A plausible two‐stage growth mechanism has been proposed for the formation of penniform BaXO₄ nanobelt superstructures in catanionic reverse micelles.     

球式热风炉球床结构的热工讨论

球式热风炉作为低成本，高效率的冶金炉已被越来越多的钢铁企业所采用，广钢新3号高炉首次采用球式热风炉，炉子的球床结构，球径大小，材质的选择都将对球式热风炉的热工性能产生重要的影响。本文主要从热工理论方面探讨了球床结构的合理性。     

动态陶瓷微滤膜净化沐浴污水实用研究

利用自制的动态陶瓷微滤膜对沐浴污水进行了处理,根据处理水质指标及膜操作参数的比较,发现在0.15MPa以下时,膜通量随压力的升高明显增加,大于0.15MPa时,压力对膜通量的影响不明显。合适的操作压力是0.1～0.15MPa,稳定通量为90～110L/m2·h。不同压力出水CODCr去除率达87%～98%、浊度从120°降到3°以下,处理后颜色为无色。并根据实验结果进行了工程化工艺初步设计和经济分析。     

环氧基的PCB对无铅组装的兼容性

综述了环氧树脂基的PCB与无铅化组装的兼容性问题。经过大量试验表明,常规的FR-4基材和双氰胺固化的高Tg基材是不能满足无铅化组装要求的,而采用酚醛固化的中等-Tg的环氧树脂基材是可能成为无铅化组装用基材的。同时,PCB制造过程也起着重要的作用。PCB设计和再(回)流焊的加热梯度也影响着无铅化的性能。     

Deep‐UV Photochemistry and Patterning of (Aminoethylaminomethyl)phenethylsiloxane Self‐Assembled Monolayers

The 193 nm photochemistry of (aminoethylaminomethyl)phenethylsiloxane (PEDA) self‐assembled monolayers (SAMs) under ambient conditions is described. The primary photodegradation pathways at low exposure doses (< 100 mJ cm^–2) are benzylic C–N bond cleavage (ca. 68 %), with oxidation of the benzyl C to the aldehyde, and Si–C bond cleavage (ca. 32 %). Amine‐containing photoproducts released from the SAM during exposure remain physisorbed on the surface, where they undergo secondary photolysis leading to their complete degradation and removal after ca. 1200 mJ cm^–2. NaCl(aq) post‐exposure rinsing removes the physisorbed materials, showing that degradation of the original PEDA species (leaving Si–OH) is substantially complete after ca. 450 mJ cm^–2. Consequently, patterned, rinsed PEDA SAMs function as efficient templates for fabrication of high‐resolution, negative‐tone, electroless metal and DNA features with good selectivity at low dose (i.e., ca. 400 mJ cm^–2) via materials grafting to the intact amines remaining in the unirradiated PEDA SAM regions.