The synthesis of block copolyetherketones based on 4,4′‐dichlorodiphenylketone,phenolphthaleine, and bisphenol A and investigation of their properties

Block structured polyethers based on phenolphthaleine, 4,4′‐dichlorodiphenylketone, and bisphenol A with different degrees condensation (n = 1, 5, 10, and 20) were synthesized by means of acceptor‐catalytic polycondensation. Equaimolar quantities of chloranhydrides of iso‐ and terephthalic acids were used. Higher molecular masses were obtained from longer oligoketones with higher condensation degrees. Better molecular packing, increased thermal and mechanical properties were obtained with higher condensation degrees of oligoketones. © 2007 Wiley Periodicals, Inc. JAppl Polym Sci, 2008     

A strategy for the electro-organic synthesis of new hydrocaffeic acid derivatives

Electrochemical treatment processes can significantly contribute to the protection of the environment through the minimization of waste and toxic materials in effluents. From a pharmaceutical point of view and due to the existing resemblance between the electrochemical and biological reactions, it can be assumed that the oxidation mechanisms on the electrode and in the body share similar principles. In this paper, the application of electrochemical studies in the design of an environmentally friendly method was delineated for the new hydrocaffeic acid (HCA, 3,4-dihydroxy hydrocinnamic acid) derivatives synthesis at carbon electrodes in an undivided cell. In this cell, the EC mechanism reaction was involved, comprising two steps alternatively; (1) electrochemical oxidation and (2) chemical reaction. In particular, the electro-organic reactions of HCA, an important biological molecule, were studied in a water–acetonitrile (90:10 v/v) mixture in the presence of benzenesulfinic acid (3) and p-toluenesulfinic acid (4). The research included the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential electrolysis and product spectroscopic identification.     

Memory of Distributed Computer Systems: Distinctive Features of Their Architectural-Structural Organization and Use

Distinctive features of architectural-structural organization and use of memory networks are considered with the aim of choosing an optimal configuration in designing distributed computer systems.     

白云鄂博主矿开拓运输工艺转换有关问题的探讨

本文对白云鄂博主矿采场铁公路联合运输向公路运输转换位置是否确定为1638m水平以及运输工艺转换过程中相关问题进行分析论证，提出主矿采场铁路至少可向下延深一个水平，技术上可行，节约运费千万元以上。     

GSM技术在配电网故障自动隔离及恢复系统的应用

为了使配电网故障的隔离和恢复的通讯更加可靠、迅速、经济，设计了一种基于GSM通讯技术，借助移动通讯系统短信业务和数据业务，实现配电网故障的自动隔离与恢复的系统。该系统通过MCU采集数据，判断故障位置与故障类型，经GSM通讯模块上传主站，主站统筹全局，实现故障段的切除，非故障区的供电。阐述了系统的工作原理、硬件结构、通讯协议和软件流程。现场的实际运行情况证明数据上报通讯准确率为100％，多次模拟线路故障，根据故障点的不同，一般在2～3min内系统都能可靠的隔离故障，恢复系统。     

Synthesis and characterization of acidic properties of Al-SBA-15 materials with varying Si/Al ratios

Al-SBA-15 of varying Si/Al ratios in the range 11.4–78.4 was synthesized using tri-block copolymer P123. The calcined materials were examined by XRD, pore size distribution, surface area, ²⁷Al NMR spectroscopy. The acidity and acid strength distribution were studied using microcalorimetric adsorption of NH₃. The acidic properties were also examined by cumene cracking reaction as a function of Si/Al ratios. Systematic variation of acidity and activity was observed as a function of Si/Al ratio. The initial heats of NH₃ adsorption correlated well with activity indicate that acid sites with ΔH > 100 kJ/mole is responsible for cumene cracking activity. Linear correlations were obtained with total acidity and cumene cracking activities. The tetrahedral aluminum was found to be responsible for the observed acidities and catalytic activities.     

永州电力通信交换网集中操作和维护的实现

分析实现永州电力通信交换网集中操作和维护的必要性，介绍了实现程控交换机远程操作和维护的两种方式，总结在实践过程中所得到的经验和教训。     

云台山隧道进口黄土段施工技术

从防排水、边仰坡支护、洞口加固、洞内超前支护、钢拱架锚喷联合支护等方面详细介绍了云台山隧道进口黄土段的施工技术,总结了该隧道的施工效果,强调了黄土隧道施工中防排水超前支护预注浆、施工监控的作用,积累了隧道施工经验.     

在以纯碱为原料的非强酸性水溶液体系中采用酸碱滴定分析的误差来源及分析方法的改进

以三聚磷酸钠生产过程为例,论述了在以纯碱为原料的非强酸性水溶液体系中,由于反应不完全导致反应物中存在少量的碳酸盐,这部分碳酸盐干扰了用酸碱滴定法测量的中和度,并据此提出中和度分析改进方法.由此可以推广到其它以纯碱为原料的非强酸性水溶液体系中.     

新形势下的研究生思想政治工作探索

在新的历史时期 ,研究生思想状况受市场经济的影响呈现出业务学习积极、开放竞争意识强化 ,价值取向多元化、道德观念复杂化 ,集体主义淡化、个人意识加强等多样化特征 ,使研究生思想政治工作更为复杂、更为艰巨。针对这种形势 ,本文提出研究生思想政治工作必须立足于研究生思想状况多样化的现实 ,采取多种措施才能做好研究生思想政治工作 ,并进一步提出了新的历史时期开创研究生思想政治工作新局面应采取的对策措施