综合物化探方法在内蒙古张家沟银铅锌矿床勘查中的应用

本文在野外勘探成果的基础上结合室内研究总结了张家沟银铅锌矿矿床的地球物理及地球化学特征,归纳了张家沟银铅锌矿矿床地质、地球物理、地球化学找矿标志,提出了该区地球物理综合找矿方法技术集成,进一步提出了张家沟银铅锌矿床找矿方向,应注意岩体内外接触破碎带两侧次级羽状纵张裂隙带及磁力推测断裂构造汇部位,特别是负磁异常区域并伴有土壤地化异常部位的含矿性研究。     

海相沉积淤泥复合固化强度的试验研究

针对现有淤泥固化试验采用的固化剂相对单一的问题,为了系统研究多材料固化滨海沉积淤泥强度特性,以唐山南堡典型滨海沉积淤泥为研究对象,通过对比单掺、双掺及三掺等固化剪切强度,结合粉煤灰废物利用问题,系统研究了水泥、生石灰及粉煤灰等不同固化剂组合对滨海相沉积淤泥固化强度的影响。结果表明:不同固化剂对滨海相沉积淤泥抗剪强度影响的差异较为明显,抗剪强度基本随掺加固化剂的种类增加而增加,掺加6%生石灰、10%水泥和6%粉煤灰28 d龄期的固化淤泥抗剪强度最高,其黏聚力为238.4 kPa、内摩擦角为32.94°;抗剪强度指标的提高随龄期的变化存在差异,即淤泥单掺生石灰抗剪强度指标的提高主要在养护后期,施工中可适当增加闷料时间以使生石灰和淤泥颗粒反应充分;采用水泥来固化淤泥可在短期内明显提高强度,在高含水率的淤泥材料施工中有更好的工程效果;固化剂掺量相同情况下,抗剪强度随着龄期增长而增加。研究成果对滨海沉积淤泥的固化和工程应用具有参考价值。     

一个簇基无机-有机杂化材料的合成与表征

对簇基无机-有机杂化材料的制备方法及表征手段进行了研究。利用水热合成技术制备了一个具有新颖结构的簇聚物(H_2en)_2(H_3O)_(12)[Si_2Mo_(14)~(VI)Mo_2~VV_2~VV_(10)~(IV)O_(84)](1,en=乙二胺),采用元素分析、红外光谱、X射线光电子能谱、电子顺磁共振、TG及X射线单晶衍射等技术对晶体结构进行了分析。结构分析显示,簇基杂化材料是由两个高还原态的二帽Keggin型簇阴离子[Si(1)Mo_6~(VI)Mo_2~VV_6~(IV)O_(42)]~(10-)和[Si(2)Mo_8~(VI)V_2~VV_4~(IV)O_(42)]~(6-)通过(μ_2-O)_2双桥氧原子连接成以簇阴离子二聚体为结构单元的1-D链,相邻的1-D链再经质子化的水分子通过氢键连接成新颖的3-D簇阴离子超分子网络,质子化的乙二胺和水分子填充于网络之中。磁性研究表明化合物1金属离子间存在反铁磁性相互作用。     

Al_2O_3包覆对富锂锰基正极材料Li_(1.2)Mn_(0.54)Co_(0.13)Ni_(0.13)O_2的电化学性能影响

采用水热法合成富锂三元正极材料,探究了最佳包覆比例下Al_2O_3包覆对材料的电化学性能影响.采用扫描电镜(SEM)和X射线衍射仪(XRD)表征了富锂三元正极材料的表面形貌和结构,通过循环伏安(CV)、交流阻抗(EIS)技术分析了材料电化学性的影响因素.结果表明,通过异丙醇铝水解制得了氧化铝包覆层,提高了材料的比容量,稳定了材料的结构.     

可控合成自组装NaYbF_4:Er的研究

采用水热法制备了Er~(3+)掺杂的NaYbF_4上转换发光材料,X射线衍射结果表明,Er~(3+)掺杂没有改变产物的NaYbF_4晶相,EDS图发现该晶体主要成分是Na、Yb和F,同时还发现了Er,说明晶体中成功掺进了Er元素。SEM分析发现产物为圆盘状结构并且没有严重的团聚现象,晶体尺寸均匀。上转换发光光谱图出现了三个比较明显的发光峰,其发光中心分别位于525nm、540nm和660nm,其中660nm处最强。红光强于绿光主要是因为在高浓度Yb~(3+)的作用下Er~(3+)发生了交叉弛豫。     

Comparisons of Fly Ash and Deposition Between Air and Oxy-FuelCombustion in Bench-Scale Fluidized Bed with Limestone Addition

In Oxy-fuel circulating fluidized bed, the residual CaO particles may react with high concentration of CO₂ in flue gas to form bonded deposit on heat transfer surfaces in backpass when limestone is used as a sorbent to capture SO₂.In this paper, experiments were designed on ash deposition in a bench-scale fluidized bed under oxy-fuel and air atmosphere. A novel ash deposit sampling probe was used to simulate the tubes of tail surfaces. The chemical composition of fly ash and ash deposit from both air-firing and oxy-fuel firing cases were analyzed by Inductively Coupled Plasma-Atomic Emission Spectrometry(ICP-AES) and Scanning Electron Microscopy(SEM), respectively. The degrees of carbonation reaction of ash deposits were measured by Thermo Gravimetric Analysis. The results showed that there are distinct differences in fly ash deposition rate between oxy-fuel and air firing cases, and oxy-fuel combustion with limestone addition can affect chemical composition of fly ash and ash deposit, especially for elements of Ca, Na, K, and S. However, the carbonation reaction degree of ash deposits is found weak, which is due to the relatively low CaO content in ash deposit or not long enough of the sampling time.[JP]     

Synthesis of calcium silicate hydrate based on steel slag with various alkalinities

This study aimed to improve the hydraulic potential properties of the slag. Therefore, a method of dynamic hydrothermal synthesis was applied to synthesize calcium silicate hydrate. The phases and nanostructures were characterized by XRD, FTIR, TEM, and BET nitrogen adsorption. The infl uence of alkalinity of steel slag on its structures and properties was discussed. The experimental results show that, the main product is amorphous calcium silicate hydrate gel with fl occulent or fi brous pattern with a BET specifi c surface area up to 77 m2/g and pore volume of 0.34 mL/g. Compared with low alkalinity steel slag, calcium silicate hydrate synthesized from higher alkalinity steel slag is prone to transform to tobermorite structure.     

水热反应时间对Sm_2O_3微晶结构的影响

以SmCl3·6H2O和NaOH为起始原料,采用水热和热处理相结合的方法成功制备了Sm2O3微晶.利用X-射线衍射仪(XRD)、扫描电子显微镜(SEM)等研究了水热反应时间对Sm2O3物相和形貌的影响.结果表明:在200℃水热条件下反应48h后,得到以Sm2O3为主晶相的细棒状前驱体,经过800℃下煅烧1h后得到了纯的立方相Sm2O3微晶.     

NaEuF_4微米晶的水热合成与表征

以柠檬酸钠(Na3Cit)为螯合剂和形貌控制剂,通过水热方法成功合成了尺寸均匀的六角形NaEuF4微米晶.采用X-射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、能量色散X射线(EDX)和光致发光光谱(PL)对所得产物的结构、形貌以及发光性质进行分析.XRD和SEM分析表明:所得NaEuF4微米晶为六方相,颗粒较均匀.NaEuF4微米晶的尺寸和形貌可通过改变Na3Cit的量和反应时间进行调整.提出NaEuF4微米晶的可能形成机理,并研究其光致发光光谱性质.     

Risk reduction in Sechahun iron ore deposit by geological boundary modification using multiple indicator Kriging

Uncertainty on the geological contacts and the block volumes of the models along boundaries is often a major part of the global uncertainty of reserve estimation.This work introduces a geostatistical technique that has been developed and tested in an iron ore deposit at Bafq mining district,in central Iran,and that,based on a probability criterion,helps to objectively model the geometry of this iron ore deposit.The main problem in reserve estimation of this ore body is its geometrical modeling and uncertainty in geological boundaries.This work deals with the geostatistical method of multiple indicator kriging,which is used to determine the real boundaries of ore body in different categories.This approach has potential to improve project performance and decrease operational risk.For this purpose,the ore body is separated into two categories including rich iron zone （w（Fe）〉45%） and poor iron zone （20%〈w（Fe）〈45%）.It significantly benefits to decrease the risk of reserve evaluation in the deposit.This case study also highlights the value of multiple indicator kriging as a tool for estimates the position of grade boundaries within the deposit.Comparison of the resultant probability maps with the real ore/waste contacts on the extracted levels shows that the first indicator model could separate the whole ore body （poor plus rich） from the waste zone by probability of more than 0.35,which concludes the total reserve of 53 million tons.The second indicator model applied to separate the rich and poor domains and the results show that the blocks with the estimated probability of equal to or more than 0.4 lay within the rich ore zone consisting of 15.8 million tons reserve.