江苏复杂断块高含水单元改善水驱效果的技术对策

在分析高含水开发单元特点的基础上,针对该阶段剩余油的品位、分布和油水关系极为复杂、挖潜难度大的技术难点,提出了适合江苏复杂断块油田高含水开发单元改善水驱开发效果的思路和工作程序、技术对策,并在真武油田高含水开发单元进行了实际应用,取得了良好的效果.     

Concomitant Crystallization of Copper(II) Sachharinato Complexes with 2-methylpyrazine as a Monomer and an One-dimensional Polymer: Syntheses,Crystal Structures,Spectroscopic and Thermal Properties

The reaction of [Cu(sac)₂(H₂O)₄] · 2H₂O with 2-methylpyrazine (mpyz) leads two complexes, concomitant crystallization of a mononuclear complex [Cu(sac)₂(mpyz)(H₂O)₂] (1) and a polymeric complex [Cu(sac)₂(μ-mpyz)]_n (2). Both complexes have been characterized by elemental analyses, magnetic measurements, FT-IR and ESR, TG-DTA and single-crystal X-ray diffraction analyses. Single-crystal X-ray analyses show that complex 1 consists of discrete molecules in which the copper(II) ions exhibits a square-pyramidal coordination geometry. The individual molecules of 1 are connected into a hydrogen-bonded chain structure, which is further assembled to form a three-dimensional network by π–π stacking interactions. Complex 2 is an 1D coordination polymer in which copper(II) centers are bridged by the mpyz ligand. The chains are further assembled to form two-dimensional frameworks by π–π and C–H···π stacking interactions.     

原油破乳脱钙复合剂的研制

介绍了原油破乳脱钙复合剂的筛选方法。所用的破乳剂有PY、UD 10、2 0 40、SDX、SL、硬脂酸 三乙醇胺 ,所用的脱钙剂有KL 1、KL 2、KL 3、KL 4、YH、EA、SJ、LP。首先将一定量的破乳剂与原油混合 ,振荡、静置 ,按油水分层情况及脱水率 ,筛选出较优的破乳剂。然后 ,在已加入破乳剂的原油中加入一定量的脱钙剂水溶液 ,振荡、静置 ,用燃烧瓶法处理油样 ,用原子吸收分光光度计测其钙含量 ,并与未经处理的原油对比。根据脱钙率 ,筛选出较优的脱钙剂。经过对破乳剂和脱钙剂的种类、用量、pH值等条件的选择 ,配出了针对俄罗斯原油、布伦特原油、扎非罗原油破乳、脱钙效果最好的复合剂PY YH、PY EA ,其脱钙率大于 80 %,脱水率大于98%,可直接用于炼厂的原油破乳脱钙工艺中。     

小纸层析法快速测定^99mTc—HMPAO放射化学纯度

采用小纸层析系统１：１的氯仿／四氢呋喃展开剂分析＾９９ｍＴｃ－ＨＭＰＡＯ的放射化学纯度，并与两个薄层析系统和一个纸层析系统的方法作比较。配对ｔ检验结果表明两种方法测定的放射化学纯度无显著差异；放射化学纯度在７４．２％－９６．４％，小纸层析法与薄层／纸层析法紧密相关，回归公式ｙ＝１．００６ｘ－０．３２３。     

Influence of zero-loss filtering on electron optical phase contrast

Complex scattering amplitudes are used to calculate the phase contrast of colloidal gold particles. Comparison of measurements of the phase contrast intensity at the centre of the gold particle as a function of defocus for unfiltered and zero-loss filtered images demonstrates the increase in phase contrast achieved by zero-loss filtering even for a thick carbon substrate film. The granulation of amorphous germanium films is measured by the spatial rms (root mean square) values of image intensity in a defocus series.     

提高润滑油基础油氧化安定性的组合工艺

以生产润滑油基础油的老三套工艺为基础，开发了改善油品氧化安定性的组合工艺。该工艺的主要特点是包括一步络合脱氮过程。实验证明，该组合工艺既可以有效地提高基础油的氧化安定性，又能降低溶剂精制深度，提高基础油收率。     

葛洲坝电站2号水轮机转轮室中环修复

针对葛洲坝电站2号机组运行中出现转轮室中环损坏的现象,设计制造出转轮室现场机加工的大型专用机床,在修复改造过程中,解决了一系列技术难题,改造后技术指标均达到理想水平,为电站机组现场修复技术积累了宝贵经验.     

TiO_2-聚乙烯复合膜的制备及红外光谱对其膜层结构的表征

开发了以Ｔｉ４＋为桥联剂制备无机－有机复合膜的新方法以自制的硅藻土多孔陶瓷为基膜（支撑体），使用浸涂法－热致相转化法相结合制备了ＴｉＯ２－聚乙烯复合膜，并用红外光谱表征了复合膜层与层之间的结合方式和强度，支撑体中的ＳｉＯ２通过Ｔｉ４＋与聚乙烯的分子之间形成了新的化合物型膜层     

Photostabilisation of colour formers for heat-sensitive recording systems: Effect of counter-ions on the photofading of fluoran dyes

Fluorans are given considerable attention as functional dyes for heat-and/or pressure-sensitive recording media. Numerous potential metal complexes were synthesised to prolong the life of coloured species. The protecting effect of these compounds against the photofading was examined on cellulose. It was found that the zinc or nickel salts of 3,5-dihydroxy-2-naphthoic acid and its derivatives can be applied as effective stabilisers against the fading of fluoran dyes.