交流电磁场检测探头材料仿真分析与实验研究

交流电磁场检测(ACFM)技术中缺陷信号为微弱多干扰电磁场信号,检测探头能否较好地提取信号是缺陷识别和量化的基础和关键,而探头材料直接影响缺陷信号幅值和灵敏度.针对以上问题,文中重点围绕ACFM检测探头材料展开系统研究,借助ANSYS电磁场分析模块,建立仿真模拟,深入分析检测探头材料对缺陷信号影响,并采用真实人工缺陷对3种常用的ACFM检测探头材料进行了实验测试,结果表明:高磁导率的锰锌铁氧体磁芯作为ACFM检测探头材料时,探头获取的缺陷电磁场信号幅值较大,具有较好的信号提取灵敏度.     

主元分析法在MIMO系统中的故障检测与诊断研究

针对多输入多输出对象应用多元分析方法实现系统的故障检测与诊断,能够有效克服机理分析法诊断的缺点,既可以消除各变量之间的关联,也减小外界噪声的影响。通过对多变量液位控制进行试验验证,主元分析法能够有效地对生产过程进行监测,并准确及时地分析判断系统中发生的故障。     

多变量预估控制技术在聚丙烯装置上的应用

介绍了多变量预估控制技术在长盛石化聚丙烯装置的设计、开发过程以及多变量预估控制器的运行情况和应用效果,证明了应用该技术的系统增强了装置的抗干扰能力,提高了装置生产的平稳性,减轻了操作负荷和能耗,增加了装置效益,改变了传统的生产模式。     

VC精馏的多变量控制

为了得到高纯度的氯乙烯单体和解决不易控制精馏塔操作的难题，对精馏过程的工茹爹教实施了多变量控制方案。通过改造，单体质量分数可达99．99％以上。     

Spatiotemporal aspects of jerky flow in Al–Mg alloys, in relation with the Mg content

The spatiotemporal aspects of the Portevin–Le Chatelier effect in Al–Mg alloys are investigated using direct observations of the sample surface with a digital camera. Optical measurements of the surface profile using a white light interferometer allow the estimation of the local strain and strain rate associated with the bands. The effect of Mg content on instability characteristics is analyzed. The reloading time is shown to depend on the Mg content only at the strain and strain rates where type C bands are observed.     

Influence of Ionic Surfactants on the Formation of Liquid Crystals in Oleic Acid/Glycol/Water Systems

The influence of surfactant structure on the formation of lamellar liquid crystals with very low surfactant concentration was investigated for systems composed of oleic acid, diethyleneglycol ethyl ether and water. Surfactants belonging to anionic and cationic families were checked: phosphated oleyl ether 3 EO (PO₃EO), triethanolamine oleate (TEAO) and sodium lauryl ether sulphate (SLES) as anionic surfactants and two alkyl trimethylammonium bromide type (C₁₂TAB and C₁₄TAB) as cationic surfactants. For each of the surfactants, the appropriate relationships between surfactant, oleic acid and glycol to furnish lamellar liquid crystals when these basic compositions were further diluted with water were established. The appropriate ranges of dilution allowing the liquid crystal formation were also determined. These liquid crystals presented an attractive appearance because of their transparency and high viscosity, although in the beginning of its formation, a short range of less viscous compositions (so called liquid/gel compositions) appears in some cases. Through water dilution, the initial surfactant percentages are noticeably reduced being possible liquid crystals with 2–5 wt% of surfactant.

Effect of steel microfibers on corrosion of steel reinforcing bars

Steel microfiber reinforcement was previously found to be successful in mitigating alkali silica reaction in concrete, an expansive phenomenon. The use of steel microfibers to mitigate rebar corrosion, another expansive reaction, was investigated. Mortar specimens with and without steel microfiber reinforcement were exposed to a corrosive environment. All specimens were prepared with water/cement ratios of both 0.40 and 0.55, cured for 28 days, and then submerged in aerated 3.5% NaCl solution. The corrosion behavior of the specimens was monitored via electrochemical measurements. Three types of electrochemical tests were performed: corrosion potential measurements, potentiodynamic polarization, and electrochemical impedance spectroscopy. Chloride concentration measurements and microscopic analysis were performed as well. The polarization curves, Tafel, and polarization resistance measurements indicate that the steel rebar in the microfiber-reinforced mortars are more resistant to corrosion than the rebar in the control mortars, despite higher chloride concentrations. Furthermore, the steel microfiber-reinforced cement based materials have a lower electrolytic resistance. This is not indicative of a higher corrosion rate, which would be the case if it had been observed in standard mortar specimens.     

Electrochemistry of thorium in LiCl-KCl eutectic melts

This work presents a study of the electrochemical properties of Th chloride ions dissolved in a molten LiCl-KCl eutectic, in a temperature range of 693-823 K. Transient electrochemical techniques such as cyclic voltammetry, chronopotentiommetry and chronoamperometry have been used in order to investigate the reduction mechanism on a tungsten electrode and the diffusion coefficient of dissolved Th ions. All techniques showed that only one valence state was stable in the melt. The reduction into Th metal was found to occur according to a one-step mechanism, through a nucleation-controlled process which requires an overpotential of several 100 mV. At 723 K, the diffusion coefficient is D_Th(723 K) = 3.15 ± 0.15 × 10⁻⁵ cm² s⁻¹. EMF measurements indicated that, at 723 K, the standard apparent potential is (723 K) = −2.582 V versus Cl₂/Cl⁻, and the activity coefficient γThCl₄ (723 K) = 4.6 × 10⁻⁴ on the mole fraction scale (based on a pure liquid reference state).     

Velocity measurements and flow field characteristic analyses in a turbo air classifier

Turbo air classifier is one of the most widely used powder classification equipment. The rotor cage as a rotary component can create a forced centrifugal field, so it is a key part for turbo air classifier. In order to investigate the effect of structural variations of the rotor cage on flow field characteristics, three dimensional velocity measurements of the annular region in a turbo air classifier equipped with two different rotor cage bottom plates (A and B type) are performed by laser Doppler velocimeter (LDV). It is found that the different bottom plates have different axial and tangential velocity distributions in the annular region. However, the structural variations of the rotor cage have hardly any effect on the radial velocity. Based on the classification principle, the relation between the classification performance and the flow field characteristics is investigated in great detail.The results of the flow field measurements were tested by the classification experiments carried out with cement raw meal and ground calcium carbonate. The results demonstrate that B type bottom plate can realize the production of narrow particle size distributions, so it is more favorable for classification than A type bottom plate. Classification experiment results are in good agreement with the results of the flow field measurements.     

The effect of Hf substitution for Zr on glass forming ability and magnetic property of FeCoZrMoBAlY bulk metallic glasses

Bulk metallic glasses (BMGs) Fe₆₁Co₆Zr_8−xHf_xMo₇B₁₅Al₁Y₂ (x = 0–8) have been produced by copper mold casting technique using industrial raw materials. The effect of substitution of Hf for Zr on the glass forming ability (GFA) and the magnetic property has been studied by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and superconducting quantum interference device (SQUID). It was found that the substitution of an appropriate amount of Hf for Zr can improve the GFA of the base alloy Fe₆₁Co₆Zr₈Mo₇B₁₅Al₁Y₂, as demonstrated by the increase in reduced glass transition temperature T_rg (=T_g/T_l) and GFA parameters of γ (=T_x/T_g + T_l) and δ (=T_x/T_l − T_g). The Fe₆₁Co₆Zr₅Hf₃Mo₇B₁₅Al₁Y₂ alloy exhibits the highest GFA with the largest T_rg (0.612) and δ (1.633), and can cast a fully amorphous rod in 3 mm diameter. The substitution of Hf for Zr also enhances the magnetic properties, as verified by the increase in saturation magnetization (M_s) in the alloy of Fe₆₁Co₆Zr₃Hf₅Mo₇B₁₅Al₁Y₂, whose M_s is approximately 1.5 times higher than that of the base alloy (x = 0) at room temperature. Finally, the effect of the substitution of Hf for Zr on glass forming ability and magnetic properties is discussed.