瓶装毒性气体的毒害与安全防护（10）

叙述了瓶装毒性气体的类别、毒害与安全防护。     

A Critical Assessment of Industrial Coal Drying Technologies: Role of Energy,Emissions, Risk and Sustainability

Low-rank coals (LRCs) constitute about 45% of the total coal reserves and hence will soon be the fossil fuel of choice in many countries despite their high moisture content on mining, which varies from 30% to as high as 66%. It is important to reduce their water content to enhance the heating value and reduce transportation costs while enhancing combustion efficiency, safety, and reduction of emissions on combustion. The level of moisture to be achieved upon drying LRCs depends on the end application; it varies from as low as 0% for hydrogenation processes to 15% for briquetting and gasification processes. Numerous drying technologies have been proposed for drying coal; they include pulse combustion, vacuum, fluid bed, rotary, flash, microwave, and superheated steam drying. Each technology has some pros and cons, which are not always clearly spelled out in the literature. In addition, it is necessary to develop sustainable rather than just cost-effective drying systems for LRC. In this article we assess various coal drying techniques critically and identify their strengths and weaknesses. Some theoretical comparisons of different dryer types are carried out based on energy utilization and carbon footprints. The jury is still out on optimal drying technology for LRC and innovative design concepts should be evaluated before finalizing the selection.     

Transportation options in a carbon-constrained world: Hybrids,plug-in hybrids,biofuels, fuel cell electric vehicles,and battery electric vehicles

Multiple alternative vehicle and fuel options are being proposed to alleviate the threats of climate change, urban air pollution, and oil dependence caused by the transportation sector. We report here on the results from an extensive computer model developed over the last decade to simulate and compare the societal benefits of deploying various alternative transportation options including hybrid electric vehicles and plug-in hybrids fueled by gasoline, diesel fuel, natural gas, and ethanol, and all-electric vehicles powered by either batteries or fuel cells. These simulations compare the societal benefits over a 100-year time horizon of each vehicle/fuel combination in terms of reduced local air pollution, greenhouse gas pollution, and oil consumption compared to gasoline cars.     

温室效应和温室气体减排分析

人类活动所排放的温室气体在大气层中的不断增加和积累，使地球温室效应变得越来越严重。由于温室气体所造成的气候异常和由此引发的灾害无国界，因此解决温室气体排放是全人类共同的问题。为此，介绍了温室气体和温室效应，以及大气层中CO2浓度变化和世界排放CO2的情况；通过分析说明世界经济高速发展对化石燃料需求的不断增长，是第二次世界大战以来尤其是近20年来大气中CO2浓度快速增长的主要原因。同时还对排放CO2最多的发电和供热、交通运输、房屋建筑3大领域的节能和减排进行了分析，指出解决全球变暖问题需要人类的智慧、良知和理智。     

低电压气体导电及高速高灵敏度湿敏传感器研究

气体在电场作用下可形成导电能力。研究发现气体中微量水汽的存在对此导电能力具有极为灵敏的作用。本文阐述了低电压气体导电机理及其敏感效应。研制了一种低电压微功耗微型电极系统实现自持暗放电，使通常气体导电必需的高电压降低了一个多数量级，仅为几百伏。基于低电压气体导电机理的湿敏传感器的水汽分压强灵敏度优于１Ｐａ／ｎＡ，反应时间优于一秒。上述结果表明：气体低湿度快速测量是实际可能的。     

Sediment greenhouse gases (methane and carbon dioxide) in the Lobo-Broa Reservoir, São Paulo State, Brazil: Concentrations and diffuse emission fluxes for carbon budget considerations

Carbon gases (methane, CH₄, and carbon dioxide, CO₂) were measured for the first time in sediments of the Lobo‐Broa Reservoir, near São Carlos in São Paulo State, Brazil. It is believed these are the first measurements of this kind in any of the many reservoirs located in Brazil. Even though the Lobo‐Broa Reservoir is classified as oligotrophic, the sediment gas concentrations were exceedingly high, ranging from 0.4–3 mmol L^?1 for CH₄ and 1–9 mmol L^?1 for CO₂. Both gases exceeded their in situ gas saturation values at these shallow water depths (7 m in central basin; 11 m at dam), resulting in numerous sediment bubbles. Organic matter was highly concentrated in the reservoir sediments, averaging 25.5% loss on ignition (LOI) (dam) to 26.9% LOI (central basin) for the 0–12 cm depth interval, with values as high as 29–30% LOI (12% organic carbon) in the surface 0–5 mm layer. The theoretical flux of dissolved pore water carbon gases to the sediment–water interface (SWI) averaged 3.4 mmol L^?1 m^?2 day^?1 CH₄ and 7.3 mmol L^?1 m^?2 day^?1 CO₂ for the surface 0–10 mm. From gas emission measurements at the water surface, it was calculated that 90% of CH₄ is consumed either at the SWI or in the water column, resulting in a loss of 0.31 mmol L^?1 m^?2 day^?1 of CH₄ to the atmosphere. However, only 20% of the total CO₂ gas transported across the water–atmosphere interface (36.3 mmol L^?1 m^?2 day^?1, or 1600 mg CO₂ m^?2 day^?1) was produced in the sediments. The remaining 80% of CO₂ probably comes from other carbon sources. With CH₄ oxidation in the aerobic water column, close to 30% of the carbon gas flux to the atmosphere could be accounted for by gas production of CO₂ and CH₄ in the sediments and their diffuse transport to the water column.     

Theoretically based data assessment for the correlation of the thermal conductivity of dilute gases

This paper presents two schemes for a theoretically based data assessment of the thermal conductivity of dilute polyatomic gases. The first employs the simplified Thijsse expression, combined with accurate experimental data obtained from a transient hot-wire apparatus, as reference. The second makes use of theoretical results for the temperature dependence of the ratio D _int/D. Both methods lead to mutually consistent results for linear molecules and to useful criteria for discriminating between experimental data sets. The paper also demonstrates the influence of data burdened with systematic errors upon the final results of different correlation schemes.     

Soret-‘shifted’ dew-point temperatures for surfaces exposed to hydrocarbon vapors dilute in compressed nitrogen

Soret-driven species transport causes concentration non-uniformities in the immediate vicinity of ‘cold’ surfaces immersed in undersaturated vapor-containing streams. These concentration non-uniformities, in turn, alter corresponding condensation onset temperatures, often by as much as 30 K (i.e., ca. 3%) in previously studied, near-atmospheric pressure combustion systems [see, e.g., Rosner, D.E. and Nagarajan, R., 1985. Chemical Engineering Science 40 (2), 177]. Because high-pressures often cause remarkable increases in the relevant binary Soret factor, α_T,12, we investigate here the importance of these vapor phase ‘transport’ effects for ‘compressed’ N₂ streams containing dilute quantities of an alkane: C₁₂H₂₆ (n-dodecane) or C₈H₁₈ (n-octane). We invoke the virial equation of state (VES) to predict gas phase non-ideality, and its appreciable effect on previously available ideal gas Soret factors. Our illustrative numerical results, valid for, say, nominally 1000 K N₂ streams up to pressures of over 100 atm, reveal that high-pressure Soret ‘shifts’ in T_dp can amount to ca. 80%, even at surface temperatures above the equilibrium freezing points of these condensates. We conclude that these high-pressure vapor phase transport phenomena will not only influence the interpretation of such hot gas/‘cold’ surface ‘dew-point’ measurements, they will significantly raise the temperatures at which containment or immersed surfaces must be maintained to avoid the ravages of corrosive or insulating inorganic condensates [Rosner, D.E., Chen, B.K., Fryburg, G.C., Kohl, F.J., 1979. Combustion Science and Technology 20, 87; Rosner, D.E., 1988a. Invited paper, Benjamin G. Levich Memorial Issue of Journal of Physico-Chemical Hydrodynamics 10 (5/6), 663]. In principle, the present theory could itself be used to study the pressure dependence of the binary Soret factor—at least for systems with well-characterized saturation vapor pressures.     

气体和气体混合物的单参数状态方程

1 INTRODUCTIONThere are many equations of state that can be appliedto calculate pVT and thermodynamic properties forfluids.The simplest equation of state for gas is thefamous virial equations with the second coefficient B