SHS of mineral-like ceramics for immobilization of radioactive nuclear wastes

Synthetic analogs of titanate ceramics (perovskite and zirconolite) designed for use as a matrix for immobilization of high-level nuclear fuel reprocessing wastes (HLW). Such ceramics have been prepared by SHS method from a mixture of titanate ceramics and non-radioactive model oxides. Synthesis conditions have been optimized. The synthesized low-porosity cylindrical compacts exhibited a high strength and low rate for leaching Cs, Sr, Y, Ce, and La in bidistilled water. The phase composition and microstructure of synthesized products have been characterized. The immobilization of Cs was found to be accompanied by a marked loss of this element. The text was submitted by the authors in English.     

基于场景重构与报警聚合的网络取证分析技术

提出一种包含报警标准化、去冗余、场景重构和报警聚合的网络取证分析方法. 通过去除失败攻击的报警, 减少了对证据分析的干扰. 在场景重构中, 通过反向关联, 减少了不必要的证据, 同时通过对孤立报警的补充, 保证了证据链的完整性. 在报警聚合中, 提出了聚合同一攻击步骤的不同报警的方法, 以抽象层和具体层两个层次重构入侵场景. 最后通过实验验证了所提出方法的有效性.     

Volatility of Simulated High-Level Nuclear Waste Glass by Thermogravimetric Analysis

The volatilities of simulated, high-level nuclear waste glasses have been measured using thermogravimetric analysis (TGA). These volatilities were measured in the region of the glass transition temperature ( T _g) of the waste glasses, which is between 450° and 500°C. These data were obtained because the Waste Acceptance Preliminary Specifications require that no foreign materials be released into the canistered waste form upon heating of the canister to this glass transition temperature. In fact, all of the waste glass samples studied actually exhibited a net weight gain upon heating. This weight gain was shown to be due to oxygen uptake through oxidation of FeO. Powdered glass samples did show a small weight loss which was smaller in magnitude than the weight gain and was associated with water desorption. No true volatility was detected to the level of sensitivity (0.01 wt%) of the TGA instrument. This converts to a sensitivity of 330 μ g/m² of glass surface and a corresponding minimum value of 41 mg of volatiles for each Defense Waste Processing Facility conistered waste form. TGA experiments carried out at higher temperatures (800°C) revealed that organic concentrations in the waste glasses are less than 0.01 wt%. Thus, these results demonstrate that the Defense Waste Processing Facility will be able to comply with the Waste Acceptance Preliminary Specifications on the exclusion of foreign materials from the canistered waste forms, after exposure to T _g.     

几种光谱方法(FTIR、FT-Raman,NMR)在橡胶分析中的应用

综述了傅里叶变换红外光谱 ,傅里叶变换拉曼光谱以及核磁共振波谱在橡胶结构的定性、定量分析中的应用     

用固体核磁技术分析PE 100管材料的抗熔垂性

用固体核磁技术分析了2种具有不同抗熔垂性能的聚乙烯管材料的凝聚态结构与流变性能。管材树脂的抗熔垂性能与其核磁迟豫特性紧密相关,好的抗熔垂性能对应更长的纵向迟豫时间。抗熔垂性能好的双峰管材料的重均分子量更高,高相对分子质量部分的含量更多。     

Synthesis and characterization of soluble (porphyrinato)iron(II) polymers

The use of (tetrakis(4-hexylphenyl)porphyrinato)Fe(II) in polymerization reactions with bidentate ligands such as 9,10-diisocyanoanthracene and 1,4-diisocyanobenzene led to well-defined stacked polymers1 and2 which are still soluble in common organic solvents such as chloroform, dichloromethane, and tetrahydrofurane. They have been completely characterized by¹H-NMR and UV/vis spectropscopy in solution, even allowing end-group analysis for determination of the average degree of polymerization, yieldingn=10 andn=5 for1 and2, respectively. Mößbauer and IR spectroscopy further established the strong Fe-CN bonding reflected by very small isomer shifts and quadrupole splittings (E _Q0.2 mm s^–1) and a large decrease in the IR stretching frequency (v _CN60 cm^–1). The axially stacked polymers exhibit semiconducting properties only upon doping.Presented at the 5th International Symposium on Macromolecule-Metal Complexes (MMV), Summer 1993 in Bremen, Germany.     

核电工程项目调试工期的影响因素与优化

调试启动工作是核电工程项目进度控制中非常重要的环节,对整个工程的顺利投入运行有着重要的作用。如果调试工期过长,则会导致核电工程不能按期交付使用,从而对整个核电工程的进度造成影响。主要探讨了核电工程项目调试工期的影响因素和优化措施。     

基于背景噪声的图像盲篡改检测

数字图像在成像过程中会产生特定的背景噪声,如果两幅不同噪声的图像拼接在一起,篡改区域和其他区的噪声会有差异。提出一种基于偏度统计特性的背景噪声估计算法,其通过对图像分块计算每块的噪声标准差,从而检测出噪声异常部分以达到篡改检测的目的。算法利用DCT变换去除原图细节部分,利用偏度统计特性估计噪声,利用条件最小值法求出噪声的标准差。算法改进了迭代求条件最小值法,利用微分方法求取最小值,避免了初始值设定问题,提高了算法的准确率。实验结果表明,提出的噪声估计算法正确率高,且对拼接篡改图像篡改检测有明显效果。     

用于入侵检测及取证的冗余数据删减技术研究

近年来计算机犯罪逐年增多,并已成为影响国家政治、经济、文化等各个领域正常发展的重要因素之一。入侵检测技术与入侵取证技术对于打击计算机犯罪、追踪入侵、修补安全漏洞、完善计算机网络安全体系具有重要意义。但是,随着网络的普及以及计算机存储能力的提升,入侵检测及取证技术目前需要分析的往往是GB乃至TB级的海量数据,而且有用信息往往湮没在大量由正常系统行为触发的冗余事件之中。这无疑给分析过程带来了巨大的挑战,也使分析结果的准确性不高。因此,如何设计出一种自动冗余数据删减技术来提高入侵检测及取证方法的准确率及效率,是当前入侵检测和取证领域的关键问题之一。文中即对这方面已有的研究工作进行了综述,首先介绍了冗余数据删减技术的发展历程及其在医学数据分析等传统领域的应用,然后重点介绍了针对入侵检测和入侵取证的现有各种冗余数据删减方法,最后通过对当前冗余数据删除技术的比较,指出了该领域当前存在的问题及未来的研究方向。     

基于 ARM9的便携式网络监控取证系统设计与实现磁

针对传统监控取证系统体积大、移动性差、成本高等不足,运用嵌入式技术,视频处理技术及无线网络传输技术,设计了一种基于 ARM9的便携式网络监控取证系统[3]。该系统以 ARM9芯片 S3C2440为硬件平台,以 Linux 操作系统为软件开发平台,将 USB 摄像头采集到的图像数字化后经过 MPEG-4压缩算法的处理,通过构建嵌入式 Web 服务器[2]以及 Java Applet 技术[1],实现了远程监控端通过 IE 浏览器对现场的监控取证,最终形成了一套集视频采集、预处理、存储、显示、传输为一体的便携式视频监控取证终端系统。