工业聚合反应装置 Ⅴ.流化床气相聚合反应器

简介了流化床气相聚合反应器的原理和6种典型的聚合装置。     

红外加热胶接技术

提出了红外加热胶接的思想，并对红外加热胶接技术作了简单阐述。介绍了一种红外加热胶接矿用阻燃、防腐、橡塑风筒布的装置。     

Selectivity of partial hydrogenation reactions performed in a pore-through-flow catalytic membrane reactor

The selectivity of partial hydrogenation reactions of unsaturated substrates was studied in a membrane reactor operating at 323 K and 40 bar hydrogen pressure. The reactor system was constructed as a loop of a saturation vessel and a membrane module in which the reaction mixture was resaturated with hydrogen up to 100 times. In a porous membrane made from cross-linked polyacrylic acid palladium nanoparticles were incorporated as catalysts. A well-defined residence time within the membrane was achieved due to a defined pore structure of the membrane and a convective mass flow of the reaction mixture through the membrane. The selectivity for the partially hydrogenated products was investigated as a function of the pore size of the PAA membrane and was compared to commercially available catalysts. Compared to experiments with supported catalysts (Pd/C and Pd/Al₂O₃) in a slurry and a fixed bed reactor the selectivity for the desired products could be increased by 3% (1-octyne) up to 40% (geraniol).     

建筑节能发展缓慢的原因及其对策

我国实施建筑节能已近10年，但仍然只停留在试点、示范的层面上，尚未扩大到整体．分析了造成建筑节能发展缓慢的原因，并提出了推行和普及建筑节能的对策．     

新型VAE乳液及其在胶粘剂中的应用

介绍了在高压环形反应器上采用连续聚合工艺进行的VAE(醋酸乙烯-乙烯共聚物)乳液新品种的开发。通过在普通型VAE乳液配方基础上调整保护胶体的品种和用量,并采用新型氧化-还原引发体系,生产出高固含(6S%)低粘度的VAE乳液,具有优异的粘接强度和干燥速度。用于包装行业的快速粘接和配制成木材拼板胶,效果优异。     

井下伴热电缆导体集肤效应的有限元法分析

运用有限元法, 对交频井下伴热电缆导体内部的集肤效应现象进行了数值模拟和分析,比较直观地得出交频电缆中电流密度的分布特性, 以及交流电的不同频率对导体集肤深度的影响。在集肤效应作用下, 电缆导体内部的有效过流面积减小, 交流阻抗显著加大, 其发热量也很大,井下电缆伴热加热技术就是利用这一原理来加热原油的。通过数值模拟, 可以定量地说明电参数对加热效果的影响, 为稠油井井下电缆伴热技术中优化加热参数提供指导。     

原油集输太阳能加热节能技术的应用

在油田的采油、集输等过程中,传统技术使用燃烧煤、油、天然气和电加热方法来实现原油加热,造成大量的能源消耗和严重的环境污染。原油集输太阳能加热计算机控制节能系统,为油田的采油、集输开辟了节能新途径。该系统不仅具有自动化、智能化的特点,而且节能效果显著,实际节气率超过40%。文章介绍了该系统的结构、工作原理、功能特点以及应用效果。     

Feasibility study on the use of polyallyldiglycol-carbonate cell dishes in TUNEL assay for alpha particle radiobiological experiments

In the present work, we have studied the feasibility of a method based on polyallyldiglycol-carbonate (PADC) films to investigate the effects of alpha particles on HeLa cervix cancer cells. Thin PADC films with thickness of about 20 μm were prepared from commercially available CR-39 films by chemical etching to fabricate custom-made petri dishes for cell culture, which could accurately record alpha particle hit positions. A special method involving “base tracks” for aligning the images of cell nuclei and alpha particle hits has been proposed, so that alpha particle transversals of cell nuclei can be visually counted. Radiobiological experiments were carried out to induce DNA damages, with the TdT-mediated dUTP Nick-End Labeling (TUNEL) fluorescence method employed to detect DNA strand breaks. The staining results were investigated by flow cytometer. The preliminary results showed that more strand breaks occurred in cells hit by alpha particles with lower energies. Moreover, large TUNEL positive signals were obtained even with small percentages of cells irradiated and TUNEL signals were also obtained from non-targeted cells. These provided evidence for the bystander effect.     

Structural Description of Polyaromatic Nucleus in Residue

The proton nuclear magnetic resonance spectroscopy （1H-NMR）, the synchronous fluorescence spectrometry （SFS） and the ruthenium ions catalyzed oxidation （RICO） method were used to determine the chemical structure of polyaromatic nucleus in Oman residue fractions. The results of 1H-NMR analyses showed that the average numbers of aromatic rings in the aromatics, resins and asphaltenes units were 3.2, 5.6 and 8.2, respectively. SFS was used to investigate the distribution of aromatic rings in residue fractions, the main distribution range of aromatic rings in aromatics, resins and asphaltenes were 3 4 rings, 3--5 rings and more than 5 rings, respectively. The aromatic network in residue fractions was oxidized to produce numerous carboxylic acids. The types and content of benzenepolycarboxylic acids, such as phthalic acid, benzenetricarboxylic acids, benzenetetracarboxylic acids, benzenepentacarboxylic acid and benzenehexacarboxylic acid disclosed the condensed types of aromatic nuclei in the core. The biphenyl fraction （BIPH）, the cata-condensed fraction （CATA）, the peri-condensed fraction （PERI） and the condensed index （BCI） were calculated based on the benzenepolycarboxylic acids formed. The results implied that there was less biphenyl type structures in all residue fractions. The aromatics fraction was almost composed of the cata-condensed type system, and the asphaltenes fraction was wholly composed of the peri-condensed type system, while in the resins fraction co-existed the two types, herein the peri-con- densed type was predominant over the cata-condensed type. Based on the analytical results obtained in the study, the components --aromatics, resins and asphaltenes -- were given the likely structural models.     

西安脉冲堆源区测量仪表的研制

西安脉冲反应堆源区测量仪表是源区低端测量的关键仪表，同时也是反应堆堆外中子通量监测仪表系统的重要组成部分，该仪表在同类型反应堆仪表的基础上进行了研制改进和更新，使仪表在测量灵敏度、测量范围、抗干扰能力、可靠性及可维修性等主要性能指标方面有了较大提高。简要介绍了该仪表的设计思想、构成、工作原理、主要技术指标、应用效果及特点等。