Novel approach in investigation of the poly(acrylic acid) hydrogel swelling kinetics in water

The swelling kinetics curves of structurally defined poly(acrylic acid) hydrogel in bidistilled water at temperatures: 25, 30, 35, 40, and 45°C were determined. The possibility of kinetically explaining the isothermal swelling process by applying the following models: reaction controlled by diffusion, first order chemical reaction kinetics, and second order chemical reaction kinetics, was investigated. It was found that kinetically explaining the swelling process using these methods was limited to only certain parts of the process. The swelling process in bidistilled water was described in full range assuming that the hydrogel's swelling rate was a kinetically controlled reaction by the rate of the movement of reactive interface of hydrogel. Based on that model, the kinetic parameters, activation energy (E_a) and preexponential factor (A), of the swelling process were determined to be E_a = 35 kJ/mol and lnA = 8.6. A possible mechanism of the investigated swelling process was discussed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

用层次分析法优选喇萨杏油田三次加密调整区块

以检查井分析资料和二次加密调整井测试资料为基础，以大庆喇萨杏油田已开展的三次加密调整试验和已完成的三次加密调整方案为依据，通过对喇萨杏油田高含水后期各开发区块可调砂岩厚度、单储系数、综合含水、二次加密调整时间及套损井比例等几个主要指标综合分析的基础上，利用层次分析方法对喇萨杏油田各开发区块三次加密调整的可行性进行优选排队，最终给出喇萨杏油田三次加密调整优先进行的区块，为喇萨杏油田有计划、分步骤地实施三次加密调整提供了可靠依据。     

CX6112车铣复合机床设计方案的研究与探讨

文章较系统地论述了车铣复合机床设计方案的形成过程，同时分析了该设计方案的持点，并简要介绍了该产品的主要技术参数和用途，简评了该产品的技术水平。     

厅堂音质评价参量的相关性分析

当代室内声学专家经常选用的评价厅堂音质的物理参量，其间有几个量是相关的。作为室内音质设计的依据．必须寻找基本相互独立的参量，才有更大的实用意义。     

多面体含能材料的爆速和爆压预估

当采用R-P经验方法预估多硝基笼状化合物最大理论密度下爆速和爆压时,需要修正F因子中与分子结构有关的A/3项,使F因子包含有来自笼状分子高晶体密度和分子内部高张力能的贡献。与K-J方法相比,改进R-P方法既保持了原式的优点,又使预估结果获得明显改善。把K-J方法预估结果作为基础数据,利用改进R-P方法估算25种多硝基笼状化合物的爆速和爆压,结果表明该方法的相对误差分别为±1.9％和±5.2％。而用R-P方法时,预估爆速和爆压的相对误差分别为±14.0％和±21.4％。     

Design and Characterization of the CLIMPAQ,Chamber for Laboratory Investigations of Materials,Pollution and Air Quality*

A test chamber has been developed in order to provide a small and simple emission testing facility capable of testing construction products in a climate where the important climatic parameters such as temperature, ventilation rate and air velocity can be varied independently around typical indoor values. The test chamber CLIMPAQ is made of panes of window glass. Other main surface materials are stainless steel and eloxated aluminium. The chamber has a volume of 50.9 litres and is designed to meet the requirements for quantifying air pollution. In this investigation human subjects acted as air pollution judges, and chemical characterization of the air pollution was carried out. Carpet, linoleum, wall paint and seal- ant were tested simultaneously in the CLIMPAQ and in four other chambers ranging from a full-scale chamber of 28 m³ to a field and laboratory emission cell of 3.5· 10^?5m³. Product ranking is the same in all chambers for the sensory measurements. Emission rates based on sensory measurements differ for all products less than 100 % except for tests in a 3-litre chamber where emission rates were higher. Chemical measurements differ up to approximately 10 times for the same product in different chambers. Deviations appear to be the result of different environmental parameters in the various chambers. Low air concentrations or high specific ventilation rates seem to increase emissions, while differences in air velocities and sink properties may also be the cause of differences in emission rates.     

考虑环境影响的水电站水库模糊优化调度模型及其应用

本文在提出一种水电站水库优化调度准则的基础上,建立了考虑环境因素影响的水电站水库模糊优化调度模型,实例研究表明,所建模型是有效的、适用的。     

压制球形药包解决退模问题的技术措施

文中简要阐述了在制备球形药包过程中,为解决压装药件的退模问题所采取的技术措施,并提出了较佳的成型底座的设计方案。     

基于MATLAB优化工具箱的行星轮系参数优化设计

为了合理分配行星轮系的总传动比，并使系统体积小、质量轻，建立了具有3个设计变量、1个目标函数和8个约束方程的优化设计数学模型，并用MATLAB优化工具箱进行求解。经实例计算和分析，说明这种优化方法符合实际、准确可靠；设计的数学模型有一定的使用价值，为深入研究行星轮系建立了基础。     

气门用4Cr9Si2钢调质工艺研究

采用正交试验 ,研究了 4Cr9Si2钢的淬火温度、回火温度与组织、硬度间的关系 ,得出了最佳的工艺参数 (10 10℃淬火 ,6 0 0℃回火 )。实际生产表明 ,采用此工艺后 ,断裂现象基本消除 ,气门的热处理质量有了明显提高。