Kinetic study of the hydrolysis of isocyanic acid in the gas phase

The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas.     

工业聚合反应装置 Ⅴ.流化床气相聚合反应器

简介了流化床气相聚合反应器的原理和6种典型的聚合装置。     

HTR-10燃料元件装卸系统冷态调试

10MW高温气冷实验堆（HTR－10）是一座球床堆，由燃料元件装卸系统实现燃料元件的装卸和循环，且不需要停堆，为保证HTR－10的正常运行，燃料元件装卸系统必须安全，可靠，为此，必须对燃料元件装卸系统进行周密，细致的调试试验和验证，本文介绍了燃料元件装卸系统冷调试的主要调试项目，调试方法和调试结果。     

加氢反应器内构件—急冷箱的试验研究

急冷箱是加氢反应器的重要内件。洛阳石化工程公司设备研究所在认真分析UOP急冷箱的基础上,对其结构进行了改进,开发出了新型急冷箱(已获专利)。经过流体力学、传质、传热性能对比试验、分析,新型急冷箱结构性能优良。     

聚合反应器制造质量控制要点探讨

聚合反应器是无法检修设备,不允许打开,所以聚合反应器的制造质量必须严格控制,在设备制造过程中,严格按照设计图纸、技术要求及国家现行标准,进行控制设备制造、检验和验收,使制造质量达到规定要求。     

管壳式换热器流场三维数值模拟

采用多孔介质方法 ,在PHOENICS 3 3程序的基础上建立了换热器的三维流动计算模型。引入体积穿透率、表面穿透率、分布阻力等来描述换热器内的管束。模型通过计算Halle等[1] 的实验工况来进行验证 ,并尝试用于计算 2 0 0MW低温供热堆主换热器内的流场     

Feedback linearizing control of a fluidized bed reactor

The design of an adaptive nonlinear controller for the control of a fluidized bed reactor is derived by using exact linearization techniques. Reset action and parameter adaptation are used to make more robust the precise compensation of nonlinear terms, which is called for in the linearization technique. A nonlinear antiwindup mechanism is introduced to handle reset windup problem and to provide fast response without large overshoot. Simulation results show that the proposed adaptive controller guarantees good setpoint tracking. The developed estimation algorithm allows accurate estimation of the parameters for which the regressor component is not zero.     

多孔挡板流化床还原UO3反应器模型的研究

针对ＵＯ＿３的Ｎ＿２还原反应建立了多孔挡板流化床反应器模型。将多孔挡板床的每一级视为具有相似的流动状态，每一级的上、下段称为稀、密相段，分别用鼓泡床和活塞流模型描述。该模型的计算值与￠６３ｍｍ的多孔挡板床Ｈ＿２还原ＵＯ＿３的热态实验值能较好的吻合。还预计了还原温度、操作气速和挡板结构参数对固相转化率的影响，为该类反应器的工业设计、放大和优化提供了依据。     

压水堆硼稀释事故的计算

一、概述核电厂压水堆的初始过剩反应性是通过控制捧、固体可燃毒物和溶解在主回路冷却剂中的硼酸等三种方式联合控制的。随着反应堆的燃耗和裂变毒物的积累,堆的过剩反应性不断减少,需要通过化容系统,控制硼酸的浓度来进行补偿。如果化容系统发生故障或操作员误操作,就会给回路注入无硼或低于规定浓度的补给水,给反应堆引入正反应性,造成硼稀释事故。按核安全法规的要求,应对换料、冷停堆、热停堆和启动等工况进行计算,并要求在这些     

Transient operation of a catalytic liquid-liquid plug flow reactor for kinetics measurements

A centrifugal partition chromatograph (CPC) was used as a liquid-liquid catalytic reactor for the isomerisation of hexen-3-ol into ethylpropylketone with a water soluble rhodium catalyst. Global mass transfer coefficients were measured and shown to depend on both the nature of the solute and the flow rate. Liquid-liquid partition isotherms were also determined with the CPC using elution chromatography. Finally, a reactor model was derived to account for the experimental results obtained both under stationary and transient (pulse) conditions. A parameter sensitivity evaluation is also presented.