Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry     

钠冷快堆中喷雾钠火的计算分析

根据钠冷快堆中喷雾钠火的特点建立了理论模型，编制了SSPRAY程序。该程序模拟钠喷雾燃料过程中钠滴的运动、钠和氧气的燃烧反应、热量传递和质量传递等瞬态过程。用该程序计算了气体和墙壁温度、气体压力、氧气摩尔份额、喷雾流燃烧速率和热量热递速率等主要参数。利用AI实验数据和美国SPRAY－3A的计算结果对程序进行了验证，结果符合较好。     

槽孔式水力驱动控制棒槽孔阻力系数实验研究

对槽孔式水力驱动控制棒槽对孔阻力系数进行了大量实验研究，获得了槽孔式水力驱动控制棒槽对孔阻力系数和其随槽对孔位移的变化规律，分析了槽对孔阻力系数与控制棒槽对孔结构参数之间的关系。结果表明：随槽对孔位移的增加，槽对孔阻力系数从某一较大的定值迅速降低到某一较小的定值，然后再迅速反回到初始的定值，形成一个对称的宽幅波谷；槽高使阻力系数曲线波谷幅宽发生变化，也使完全不重合段的阻力系数发生变化；随内套孔径的增大，阻力系数有所降低，其对阻力系数的影响也进一步减弱。孔径增大到一定程度，阻力系数基本不受孔径参数的影响。     

Kinetic study of the hydrolysis of isocyanic acid in the gas phase

The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas.     

工业聚合反应装置 Ⅴ.流化床气相聚合反应器

简介了流化床气相聚合反应器的原理和6种典型的聚合装置。     

气体绝缘封闭电器的高速瞬变过程和现场试验

随着ＧＩＳ的工作电压不断提高和发展，一系列新的现象和问题也同时出现。从国外一些科研，设计，制造部门所研究发表的内容看，大致有隔离开关操作和高速瞬变过程，粒子影响和对干扰定位的技术，元件的监督，现场试验等课题，本文对以上问题加以综合介绍。     

HTR-10燃料元件装卸系统冷态调试

10MW高温气冷实验堆（HTR－10）是一座球床堆，由燃料元件装卸系统实现燃料元件的装卸和循环，且不需要停堆，为保证HTR－10的正常运行，燃料元件装卸系统必须安全，可靠，为此，必须对燃料元件装卸系统进行周密，细致的调试试验和验证，本文介绍了燃料元件装卸系统冷调试的主要调试项目，调试方法和调试结果。     

加氢反应器内构件—急冷箱的试验研究

急冷箱是加氢反应器的重要内件。洛阳石化工程公司设备研究所在认真分析UOP急冷箱的基础上,对其结构进行了改进,开发出了新型急冷箱(已获专利)。经过流体力学、传质、传热性能对比试验、分析,新型急冷箱结构性能优良。     

江苏省县级电力信息网的3种组网方案

对江苏省县级电力信息网工程采用的利用ATM设备、SDH设备和WDM设备的3种组网方案进行了阐述，并分析了各种方案的优缺点。     

聚合反应器制造质量控制要点探讨

聚合反应器是无法检修设备,不允许打开,所以聚合反应器的制造质量必须严格控制,在设备制造过程中,严格按照设计图纸、技术要求及国家现行标准,进行控制设备制造、检验和验收,使制造质量达到规定要求。