氩氧气氛下沉积的CdTe薄膜及太阳电池的性质

研究了在氩氧气氛下近空间升华沉积CdTe的技术．发展了在表面十分平整的玻璃衬底上沉积优质CdTe薄膜的方法,对比了在玻璃衬底和CdS薄膜上CdTe薄膜的结构特征．通过研究氧分压对CdTe薄膜择优取向的影响,证实了在恰当的近空间升华沉积过程中,两种衬底上的CdTe薄膜具有相同的结构．研究了玻璃衬底上CdTe薄膜的电学与光学性质,观察了后处理对上述薄膜性质的影响,并研制出了效率达1338%的小面积CdTe 薄膜太阳电池．     

退火温度对电子束沉积Ag/TiO2薄膜光学性质和光催化性能的影响

研究了退火温度对电子束制备Ag/TiO₂薄膜光学 性质和光催化性能的影响。在石英玻璃、硅片 上沉积了Ag/TiO₂复合薄膜,在空气氛围下,进行了400℃, 500℃的退火一小时.用紫外-可见分光光度 计、X射线衍射仪(XRD) 、原子力显微镜(AFM)对沉积和退火后的薄膜分别进行光学、结构、 形貌分析。结 果表明:300℃下制备的Ag/TiO₂复合薄膜为无定形结构,400℃以上薄呈多晶态。吸光度和表面粗糙度 随退火温度的增加而增大,薄膜的光学带隙随退火温度的增加而减小。锐钛矿相表现出了更 好的光催化性能。     

BST薄膜铁电移相器研究进展

钛酸锶钡(BST)薄膜因其具有高的介电调谐量,相对低的损耗tgδ和快的开关速度,在微波移相器的应用中显示出巨大优势。介绍了改善BST薄膜的介电性能的有效方法,衬底材料的选择,以及BST薄膜铁电移相器的结构类型和研究进展。     

Proton Conduction in Dense and Porous Nanocrystalline Ceria Thin Films

The electrical conductivity of ceria thin films (epitaxial as well as dense and porous nanocrystalline) is investigated in dry and wet atmosphere at temperatures below 500 °C. For the epitaxial and the fully dense nanocrystalline samples, no significant differences can be observed between dry and wet conditions. In marked contrast, the nanocrystalline porous films obtained via spin coating exhibit a considerable enhancement of the protonic conductivity below 300 °C in wet atmosphere. This outcome reveals that the residual open mesoporosity plays the key role for the enhancement of the proton transport at low temperatures and not the high density of grain boundaries. The quantitative analysis of the various pathways, along which the proton transport can take place, indicates that the observed proton conduction can arise not only from bulk water adsorbed in the open pores but also from the space charge zones on the water side of the water/oxide interface.     

Characterization of amorphous Ni-Si binary alloy films by flash evaporation

We previously reported on an extremely small temperature coefficient of resistivity (TCR) of thin amorphous Ni-Si film resistors fabricated by new flash evaporating method, which have a wide range of resistivity.¹ In the present paper, we describe the structural and chemical properties of these films for the purpose of clarifying the cause of resistive change of films resulting from heat treatment. X-ray diffraction patterns show that Ni-Si films with greater than 20 wt.% Si remains predominantly amorphous after heat treatment. Changes in composition and binding energy of the films resulting from heat treatment are measured by means of XPS. Electrical characteristics are also investigated as a function of Si concentration and temperature. The resistance variations resulting from heat treatment are found to originate from a structural change. The activation energy needed for this change is obtained by analyzing the extent of change during isothermal heating and found to vary from 1 eV to 2.5 eV with increasing Si content from 20 wt.% to 80 wt.%.     

Sensitization of zinc oxide photoanode with an indoline dye

A dye‐sensitized solar cell (DSC) made of nanoporous ZnO film on aluminum‐doped zinc oxide (ZnO/AZO) transparent substrate has higher solar‐to‐electric energy conversion efficiency than a DSC consisting of nanoporous ZnO film deposited on conventional fluorine‐doped tin oxide (ZnO/FTO) transparent substrate. The ZnO/AZO DSC gave an overall conversion efficiency of 7.2% whereas the ZnO/FTO yielded a conversion efficiency of 4.5%. The film‐substrate orientation and higher light harvesting of the nanoporous ZnO film on the AZO after heating in air are mainly attributed to the higher energy conversion efficiency of the ZnO/AZO DSC. Copyright © 2012 John Wiley & Sons, Ltd.     

脉冲准分子激光沉积Mg/Ag掺杂薄膜

基于梯度掺杂功能薄膜材料在工业应用中的需要、通过金属掺杂对新材料改性研究的需要 ,用单束激光交替作用于两相异靶材 ,制备了Mg Ag组分比为 0 .9的掺杂薄膜     

测量低损耗薄膜材料介电常数的标量法

依据被测介质性质,在现有实验设备条件下,提出了一种标量法测量低损耗薄膜介质介电常数的新方法.该方法利用传输线法测量原理,先测量待测介质损耗,间接得到反射系数,由反射系数与介电常数关系式,推导得出待测介质的介电常数.该方法有样品容易制作,测量简单准确等特点.通过测量实例的误差分析,指出标量法测量薄膜材料介电常数的不足,提出相应的改进措施.     

Molten‐Salt‐Assisted Self‐Assembly (MASA)‐Synthesis of Mesoporous Metal Titanate‐Titania,Metal Sulfide‐Titania,and Metal Selenide‐Titania Thin Films

New synthetic strategies are needed for the assembly of porous metal titanates and metal chalcogenite‐titania thin films for various energy applications. Here, a new synthetic approach is introduced in which two solvents and two surfactants are used. Both surfactants are necessary to accommodate the desired amount of salt species in the hydrophilic domains of the mesophase. The process is called a molten‐salt‐assisted self‐assembly (MASA) because the salt species are in the molten phase and act as a solvent to assemble the ingredients into a mesostructure and they react with titania to form mesoporous metal titanates during the annealing step. The mesoporous metal titanate (meso‐Zn₂TiO₄ and meso‐CdTiO₃) thin films are reacted under H₂S or H₂Se gas at room temperature to yield high quality transparent mesoporous metal chalcogenides. The H₂Se reaction produces rutile and brookite titania phases together with nanocrystalline metal selenides and H₂S reaction of meso‐CdTiO₃ yields nanocrystalline anatase and CdS in the spatially confined pore walls. Two different metal salts (zinc nitrate hexahydrate and cadmium nitrate tetrahydrate) are tested to demonstrate the generality of the new assembly process. The meso‐TiO₂‐CdSe film shows photoactivity under sunlight.     

紫外激光双波段高反射镜的研制

通过非线性光学频率变换的方式,1 064 nm YAG激光可获得355 nm、266 nm波长的激光。在此系统中工作的反射镜必须同时满足两个波段的高反射。根据薄膜设计理论选择合适的镀膜材料,采用电子束离子辅助沉积工艺,经过参数优化和反复试验,在石英基片上制备了355 nm反射率为97.9%,266 nm反射率为96.8%的双波段反射镜,且在紫外波段355 nm的激光损伤阈值为1.76J/cm2,266 nm为1.12 J/cm2。测试结果表明,此反射镜的各项性能满足使用要求。