Sol-Gel Alumina Coating for Improved Cyclic Oxidation Resistance of Silicon Nitride

A 25 nm thick α-alumina layer was deposited on a turbine-grade silicon nitride by sol-gel dip coating and subsequent heat treatment in air at 1200°C. This layer had a nanometer grain structure. Silicon nitride protected by this thin layer showed a significant improvement in oxidation resistance over its uncoated counterpart after 200 cyclic exposures in air at 1250°C. The oxide layer grown on the coated silicon nitride also exhibited superior surface morphology, compared with the uncoated silicon nitride.     

Zinc Coated Steel/Epoxy Adhesive Systems: Investigation of the Interfacial Zone by FTIR Spectroscopy

The present study takes advantage of the ability of Fourier Transform Infrared Spectroscopy (FTIR) for the analysis of ultrathin organic films on metals. FTIR in the reflection mode (IRRAS) is used in order to study the interaction of ultrathin films of dicyandiamide (hardener of most one-pack epoxy resins) with various substrates, model ones such as gold or zinc and industrial ones such as steel and zinc-coated steels.

Pure zinc surfaces and, to a lesser extent, zinc-coated steels are shown to react with dicyandiamide after heating at 180°C, as evidenced by the frequency shift of the absorption band (at about 2200 cm^-1) characteristic for nitrile groups. As real systems consist of thick layers of a fully formulated adhesive cured onto a metallic substrate, the direct investigation of such a buried interphase is no longer possible by FTIR and by most of the known spectroscopies. Some mechanically tested specimens are then analysed, after failure, by FTIR microspectrometry. The spectra obtained, corresponding to the fracture initiation zone which is about 100 μm in diameter, advocate for the presence of an ultrathin layer of modified polymer still covering the substrate.     

甲烷浓度对金刚石薄膜(100)织构生长的影响

以H2和CH4的混合气体为气源,用微波等离子体辅助化学气相沉积法(MPECVD)在1 cm×1 cm S i(100)基体上沉积了金刚石薄膜。研究了不同的甲烷浓度对金刚石薄膜(100)织构生长趋势的影响。分别采用扫描电子显微镜(SEM),Ram an光谱对金刚石膜的表面形貌、质量进行了分析。结果表明,当基体温度为750℃,气压为4.8×103Pa,甲烷浓度为1.4%时,薄膜表面为(100)织构。     

柔性无机材料外墙保温隔热涂料的研制

以弹性丙烯酸乳液为成膜物,以玻化微珠、空心玻璃微珠、膨胀蛭石、岩棉纤维为填料,在助剂的配合下,制备柔性保温隔热涂料。以薄涂型施工于建筑外墙作保温层,其涂层具有生态环保、安全稳固、保温隔热、防水防火、柔韧抗裂、施工简便等优点,适用于夏热冬暖、夏热冬冷地区的建筑物外墙作保温施工。     

陶瓷材料在微机电系统中的应用

在微机电系统(MEMS)中应用到了许多种材料,其中,使用最多的是陶瓷材料。本文分析了当前国内外在MEMS研究中 的陶瓷材料的应用现状。着重分析了在MEMS中硅作为结构材料的应用以及作为薄膜材料的应用,此外,还介绍了其它 一些在MEMS中常见的陶瓷材料,如碳化硅、氮化硅、PZT压电陶瓷等材料的性能和应用。     

隐目标回归算法设计研究

对常用的回归方法进行研究.此类方法虽然几何解释明确、易于求解,但均须事先确定(或假定)变量间的因果关系,再考虑建模,在实际应用中,对于很难确定变量的因果关系的问题,如物联网数据分析,上述方法就会失效.为此,提出一种无需假定因变量的隐目标回归方法.该方法易于核化,可以推广到非线性回归问题.通过人工数据和国际标准数据集上的实验验证了所提算法的有效性.     

Preparation and characterization of mesostructured polymer-functionalized sol–gel-derived thin films

The present study attempts to incorporate methacrylate-based polymers into ordered lamellar organic/inorganic nanocomposite films composed of alternating SiO₂/polymer layers. The films are prepared by dip-coating from a solution containing the monomers and silica precursors, thus leading to composite lamellar mesostructured materials through evaporation-induced self-assembly (EISA). A polymerizable coupling agent is added to covalently link the polymers to the silica matrix. The final polymer/SiO₂ hybrid material is obtained by a separate free-radical polymerization step, initiated by UV exposure or thermal treatment. Using trimethoxy(7-octen-1-yl)silane as a coupling agent, a procedure was established that preserved the mesostructure and maintained the swelling properties of the polymers, while acrylate-based coupling agents lead to a significant distortion of the film mesostructure. Structure and composition of the films were studied by X-ray diffraction, NMR and IR.     

基于电子印刷工艺的薄膜热电偶研制

薄膜热电偶由于具有体积小、热容量小及响应速度快等优点成为近年来学者们研究的重点。薄膜制备常用的方法有射频溅射法、离子镀膜法以及直流脉冲磁控溅射法等,但这些方法操作设备复杂,制作时间长,效率低,成功率低且复现性差。用电子印刷工艺制备薄膜热电偶,将Au,Pt的溶液化微纳米材料印制在基板上,印刷成为Au-Pt薄膜热电偶,该方法操作方便快捷,对电极材料污染小。通过试验证明:采用电子印刷工艺制备的Au-Pt薄膜热电偶符合Au-Pt热电偶检定规程的要求,热电偶精度高,重复性和一致性好。     

基于射频隐身的相控阵雷达搜索控制参量优化设计

机载雷达射频隐身技术对提高飞行器生存能力具有重要意义。 本文研究了机载相控阵雷达基于射频隐身的搜索控制参量优化设计。通过分析截获概率原理 ,给出了目标特征和雷达系统性能对驻留时间和波位间隔等搜索控制参量的影响关系,构建 了目标探测性能与隐身性能约束下的优化模型。仿真获得了满足隐身要求下相控阵雷达的最 优搜索控制参数。     

用三维实体单元分析薄壁箱型结构应注意的问题

从四边固定正方形板受均布载荷的经典问题入手,结合不同类型单元的特点,探讨应用三维实体单元分析薄壁箱型结构时应注意的几个问题,纠正三维实体单元分析和应用的误区,为提高结构分析计算结果精度提供参考.