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Yin-Feng Wang Meng Li Jin-Ming Teng He-Ye Zhou Chuan-Feng Chen 《Advanced functional materials》2021,31(49):2106418
Recently, circularly polarized organic light-emitting diodes (CP-OLEDs) fabricated with thermally activated delayed fluorescence (TADF) emitters are developed rapidly. However, most devices are fabricated by vacuum deposition technology, and developing efficient solution-processed CP-OLEDs, especially nondoped devices, is still a challenge. Herein, a pair of triptycene-based enantiomers, (S,S)-/(R,R)-TpAc-TRZ, are synthesized. The novel chiral triptycene scaffold of enantiomers avoids their intermolecular π–π stacking, which is conducive to their aggregation-induced emission characteristics and high photoluminescence quantum yield of 85% in the solid state. Moreover, the triptycene-based enantiomers exhibit efficient TADF activities with a small singlet-triplet energy gap (ΔEST) of 0.03 eV and delayed fluorescence lifetime of 1.1 µs, as well as intense circularly polarized luminescence with dissymmetry factors (|gPL|) of about 1.9 × 10−3. The solution-processed nondoped CP-OLEDs based on (S,S)-/(R,R)-TpAc-TRZ not only display obvious circularly polarized electroluminescence signals with gEL values of +1.5 × 10−3 and −2.0 × 10−3, respectively, but also achieve high efficiencies with external quantum, current, and power efficiency up to 25.5%, 88.6 cd A−1, and 95.9 lm W−1, respectively. 相似文献
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对比不同热电厂企业工人接触职业危害因素情况,分析原因,为在建或已建热电厂提供职业危害因素预防措施,降低企业由于设计、施工或管理方面原因造成后期运行过程中职业危害接触超标情况的发生。根据我室历年对新疆地区热电厂职业危害因素检测结果与评价报告的比较,找出不同热电厂职业病危害因素的共性及异性,分析不同设备、工艺及管理方式不同所造成职业危害因素检测结果的差异及原因。建议优化厂区工艺及土建设计;优化设备选型及原料选择运用现代化的管理手段,加强职业卫生管理体系宣贯的有效运作。 相似文献
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To improve the convertibility of reconfigurable manufacturing system (RMS), the concept of delayed reconfigurable manufacturing system (D-RMS) was proposed. RMS and D-RMS are both constructed around part family. However, D-RMS may suffer from ultra-long system problem with unacceptable idle machines using generic RMS part families. Besides, considering the complex basic system structure of D-RMS, machine selection of D-RMS should be addressed, including dedicated machine, flexible machine, and reconfigurable machine. Therefore, a system design method for D-RMS based on part family grouping and machine selection is proposed. Firstly, a part family grouping method is proposed for D-RMS that groups the parts with more former common operations into the same part family. The concept of longest relative position common operation subsequence (LPCS) is proposed. The similarity coefficient among the parts is calculated based on LPCS. The reciprocal value of the operation position of LPCS is adopted as the characteristic value. The average linkage clustering (ALC) algorithm is used to cluster the parts. Secondly, a machine selection method is proposed to complete the system design of D-RMS, including machine selection rules and the dividing point decision model. Finally, a case study is given to implement and verify the proposed system design method for D-RMS. The results show that the proposed system design method is effective, which can group parts with more former common operations into the same part family and select appropriate machine types. 相似文献
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Yude Ji Yanping Guo Yuejuan Liu Yun Tian 《International Journal of Adaptive Control and Signal Processing》2020,34(3):283-297
This article focuses on the consensus problem of leader-following fractional-order multi-agent systems (MASs) with general linear and Lipschitz nonlinear dynamics. First, the distributed adaptive protocols for linear and nonlinear fractional-order MASs are constructed, respectively. We allow the control coupling gains to be time varying for each agent. Moreover, the adaptive modification schemes for the control gain are designed, which renders smaller control gains and thus requires smaller amplitude on the control input without sacrificing consensus convergence. Second, based on fractional-order Lyapunov stability theorem and Barbalat's lemma, two novel sufficient conditions in terms of linear matrix inequalities are provided to ensure that the leader-following consensus can be obtained in the case for any undirected connected communication graph. Furthermore, we show that the proposed algorithm also works for consensus of agents with intrinsic Lipschitz nonlinear dynamics. As a result, the proposed framework requires no global information and thus can be implemented in a fully distributed manner. Finally, the numerical simulations are given to demonstrate the effectiveness of obtained the theoretical results. 相似文献
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In this paper, permanent magnet synchronous motors (PMSMs) are investigated. According to the feature of PMSMs, a novel state equation of PMSMs is obtained by choosing suitable state variables. Based on the state equation, robust controllers are designed via interval matrix and PI control idea. In terms of bilinear matrix inequations, sufficient conditions for the existence of the robust controller are derived. In order to reduce the conservation and the dependence on parameter, the control inputs of PMSMs are divided into two parts, a feedforward control input and a feedback control input, and relevant sufficient conditions for the existence of the controller are obtained. Because of the suitable choice of state variables, the proposed control strategies can cope with the load uncertainty and have robustness for disturbance. Finally, simulations are carried out via Matlab/Simulink soft to verify the effectiveness of the proposed control strategies. The performance of the proposed control strategies are demonstrated by the simulation results. 相似文献
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针对国内某炼油厂延迟焦化加热炉三点注汽问题,采用热负荷自动调节的算法进行了研究。运用该模型方法,分析了三点注汽量对加热炉热负荷和炉管结焦系数的影响,发现三点注汽量的改变均会对热负荷和炉管结焦系数产生影响,主要表现为提高注汽量将会提高热负荷,同时降低结焦系数;第1点注汽量和第2点注汽量对热负荷和结焦系数的影响较强,第3点注汽量对热负荷和结焦系数的影响较弱。在实际操作中,加热炉中的结焦程度既不能太强也不能太弱,合适的结焦系数能够保证正常开工周期里炉管不结焦,也能保证瓦斯、注汽量等参数的合理分配。通过对热负荷、注汽量的智能分配,可得到不同原料油加工负荷条件下更加合理的装置运行方案。 相似文献
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结合松辽盆地大庆长垣西侧扶余、杨大城子油层的勘探实践,从顶生下储的特殊成藏原理出发,详细地讨论了扶余、杨大城子油层的油水层形成机理,提出了2种形成模式。认为扶杨油层的油水同层是在以上覆烃源岩的超压为驱动力的成藏条件下形成,油水混合运移注入储层,由于储层的孔喉小,油水重力分异不好,造成孔隙存油,喉道存水。这种低渗透储层孔隙结构复杂,含油饱和度低,油水在孔隙中分布状况特殊,使得电阻率等曲线反映流体的信息变弱,造成油水层识别变难。为此提出多参数降维油气水层识别方法,经实际应用取得较好的效果。 相似文献
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