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991.
Kum‐Il Lee Yong‐Sik Yim Sang‐Wook Chung Jiaqiu Wei Jong Il Rhee 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(9):1036-1045
A two‐dimensional (2D) spectrofluorometer was used to monitor various fermentation processes with recombinant E coli for the production of 5‐aminolevulinic acid (ALA). The whole fluorescence spectral data obtained during a process were analyzed using artificial neural networks, ie self‐organizing map (SOM) and feedforward backpropagation neural network (BPNN). The SOM‐based classification of the whole spectral data has made it possible to qualitatively associate some process parameters with the normalized weights and variances, and to select some useful combinations of excitation and emission wavelengths. Based on the classified fluorescence spectra a supervised BPNN algorithm was used to predict some of the process parameters. It was also shown that the BPNN models could elucidate some sections of the process's performance, eg forecasting the process's performance. Copyright © 2005 Society of Chemical Industry 相似文献
992.
克拉2气田储层岩石的应力敏感性及其对生产动态的影响 总被引:9,自引:2,他引:7
克拉2气田是一个异常高压气藏,压力系数在2.0以上。在衰竭式开采条件下,其地层压力降幅可为普通气藏地层压力降幅的3倍以上,因此研究储层岩石应力敏感性及其对生产动态的影响意义重大。研究得出,岩石的应力敏感性特征主要有:岩石物性对应力的敏感性总体上不大,其中以孔隙度最小,渗透率次之,压缩系数最大;岩石物性随地层压力的下降而下降;在同一地层压降下.岩石物性下降幅度不是渗透率的连续函数,而是与渗透率分布范围有关,高渗透率范围,岩石物性下降幅度小,低渗透率范围,岩石物性下降幅度大。研究得出,克拉2气田岩石的应力敏感性对其生产动态的影响较小。 相似文献
993.
994.
H. Fan A. Wright J. Gabaldon A. Rodriguez C.J. Brinker Y.‐B. Jiang 《Advanced functional materials》2006,16(7)
The synthesis of three‐dimensionally ordered, transparent gold‐nanocrystal (NC)/silica superlattice thin films using the self‐assembly (by spin‐coating) of water‐soluble gold nanocrystal micelles and soluble silica is reported by Fan and co‐workers on p. 891. The robust, 3D NC/silica superlattice films are of interest for the development of collective optical and electronic phenomena, and, importantly, for the integration of NC arrays into device architectures. Nanocrystals and their ordered arrays hold many important applications in fields such as catalysis, surface‐enhanced Raman spectroscopy based sensors, memory storage, and electronic and optical nanodevices. Herein, a simple and general method to synthesize ordered, three‐dimensional, transparent gold nanocrystal/silica superlattice thin films by self‐assembly of gold nanocrystal micelles with silica or organosilsesquioxane by spin‐coating is reported. The self‐assembly process is conducted under acidic sol–gel conditions (ca. pH 2), ensuring spin‐solution homogeneity and stability and facilitating the formation of ordered and transparent gold nanocrystal/silica films. The monodisperse nanocrystals are organized within inorganic host matrices as a face‐centered cubic mesostructure, and characterized by transmission electron spectroscopy and X‐ray diffraction. 相似文献
995.
996.
997.
Solubility of dimethyl-2,6-naphthalene dicarboxylate in acetic acid, N,N-dimethylfonnamide, N,N-dimethyl acetamide, dimethyl sulphoxide, and N-methyl-2-ketopyrrolidine were determined using a dynamic method. The measured systems were correlated by UNIFAC group contribution method. A new main group (aromatic ester, ACCOO) was defined to express the activity coefficients of the aromatic ester. New interaction parameters of the ACCOO group were expressed as the first-order function of temperature and were determined from the experimental data. The calculated results for the new interaction parameters were satisfactory. The measured systems were also correlated with the Wilson and 2-h models, and the results were compared with those of the UNIFAC model. 相似文献
998.
The macroscopic deformation behavior of a fiber-reinforced aluminum-boron composite is investigated. Different periodic and random arrangements of the microstructure are considered with macroscopic hardening behavior due to the evolution of plastic zones on the microscale being taken into account.
For the solution of the initial boundary value problem, a non-standard algorithm is applied. It consists of the direct solution of the whole set of equations, treating all variables as global quantities. Together with a higher order time integration method (BDF2), an automatic step size control is used in the FEM calculations. 相似文献
999.
1000.
Guiying Li Ze He Taicheng An Xiangying Zeng Guoying Sheng Jiamo Fu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(7):1019-1026
BACKGROUND: To investigate the microbial degradation performance of organic pollutants in the atmosphere using a biotrickling filter, two microorganism strains, Bacillus cereus S1 and Bacillus cereus S2, were selected, identified and inoculated into a twin biotrickling filter for comparison. RESULTS: Both strains showed good performance towards the degradation of model organic pollutants when gas flow rates ranged from 100 to 600 L h−1. For S1, the total maximum removal efficiency (RE) of toluene was maintained nearly 100% not only at gas flow rates of 100 L h−1 corresponding to empty bed residence time (EBRT) 199.44 s, but also at gas flow rates of 200 L h−1 (EBRT = 99.72 s) and 300 L h−1 (EBRT = 66.48 s). However, S2 had a much lower degradation capability; near 100% removal efficiency was obtained only at the gas flow rate of 100 L h−1 although both bacteria belong to the same Bacillus cereus. With further increase in gas flow rate, the total REs for both S1 and S2 decreased slightly at first and then dropped sharply to 46% and 35%, respectively, at an EBRT of 33.24 s, corresponding to a gas flow rate of 600 L h−1. Starvation for between 2 and 10 days resulted in the re‐acclimation times of both strains ranging between 1.0 and 15.5 h. CONCLUSION: Strain S1 would be a better choice for inoculation into a biotrickling filter than strain S2, because of its much higher toluene removal capacity and rapid recovery to full performance. Copyright © 2008 Society of Chemical Industry 相似文献