Comparison of corrosion behavior of zirconium bombarded with self-ion and molybdenum ion

In order to study the effects of zirconium and molybdenum ion bombardment on the aqueous corrosion behavior of zirconium, one group of specimens was implanted with zirconium ions with ions surface densities ranging from 1 × 10¹⁵ to 2 × 10¹⁷ ions/cm² at about 170 °C, using a metal vapor vacuum arc (MEVVA) source operated at an extraction voltage of 50 kV. The other group of specimens was bombarded with molybdenum ion with ions surface densities ranging from 1 × 10¹⁶ to 5 × 10¹⁷ ions/cm² at about 160 °C, using a MEVVA source operated at an extraction voltage of 40 kV. The valence states and depth distribution of elements in the surface of the samples were analyzed by X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES), respectively. Polarization curves measurement was employed to evaluate the aqueous corrosion resistance of the zirconium samples in a 1N H₂SO₄ solution. It was found that the aqueous corrosion resistance of zirconium implanted with 5 × 10¹⁶ Zr ions/cm² is the best in first group samples. For molybdenum ion implantation, the aqueous corrosion resistance of samples declined with raising ions surface densities. The natural corrosion potentials of zirconium samples bombarded with self-ions are more negative than that of the as-received zirconium. While, as for molybdenum ion implantation, the results are opposite. Finally, the mechanisms of the corrosion behavior of the zirconium samples implanted with zirconium and molybdenum ions are discussed.     

A numerical study of the heterogeneous porosity effect on self-propagating high-temperature synthesis (SHS)

Self-propagating high-temperature synthesis (SHS), or the so-called micropyretic/combustion synthesis, is a technique whereby a material is synthesized by the propagation of a combustion front across a powder. Heterogeneous distributions of porosities are common during self-propagating high-temperature synthesis when powders are pressed and the conventional modeling treatments thus far have only considered uniform systems. Heterogeneities in the porosity are thought to result in local variations of such thermophysical/chemical parameters for the reactants as density and thermal conductivity further changing the combustion temperature, the propagation velocity, and the propagation pattern of a combustion front. This study investigates the impact of porosity variations during self-propagating high-temperature synthesis with Ti + 2B. In addition, the simulations for the propagation of combustion fronts across a non-uniform compact where the porosity is monotonically decreased or increased along the specimens due to die wall friction are also carried out.     

多路数据采集与传输系统的设计

系统采用单片机技术进行现场模拟电压采样处理并进行数据传输，将外部采进来的模拟信号转换成数字信号，经过调制、滤波、解调之后，在另一单片机最小系统板将采集的数据结果显示出来。完成了整个数据采集与传输过程．系统具有发送端设定8路顺序循环采集与指定某一路采集的功能．     

硬铝合金焊接性能的研究

为了有效地使用热处理强化变形铝合金制造各种结构材料和零部件。研究其焊接性能指标．以Al-Cu-Mn系铝合金(2A16)为对象，采用交流钨极氩弧焊焊接工艺及同质和异质焊丝，制备了2A16硬铝合金焊接试样．通过测试力学性能、金相组织和扫描电镜断口分析等方法，对其焊接性能进行了研究．结果表明：2A16硬铝合金有较好的抗结晶裂纹形成能力，影响其焊接性能的主要问题是过时效软化区的强度下降：当填充金属中Mg／Cu质量比比较大时，焊缝出现脆断倾向，欲进一步提高焊接接头强度，一方面可采用能量密度更高的热源，同时减小焊接线能量，以减少过时效软化区的不利影响；另一方面，限制填充金属中Mg／Cu的质量比，避免出现对焊接接头强化不利的β相和T相．     

用单片机实现各音色电子琴

介绍了音色概念以及音色的决定性因素。针对传统电子琴采用以滤波网络电路对某次谐波量进行放大或衰减来模拟音色的方法,提出了一种新的实现方案,即采用以单片机为主体的数字电路,"软硬"兼施,模拟音色的波形,再通过D/A输出,从而达到听觉上的模拟音色的目的。解决了传统的模拟音色电子电路的设计的复杂性和多变性问题。给出了具体的实现电路、软件设计方法和步骤。     

彩云易散琉璃脆——白乐天《简简吟》等感伤诗对宋词的影响

白居易自分其诗为讽喻、闲适、感伤、杂律等四类,最重讽喻之作,在其诗集中冠之卷首.宋代词人的接受视域中,最重“感伤”、“闲适”之作.如果说白居易《长恨歌》是将目光投向了家国兴替与李杨悲欢,是以最高统治者为关注对象的,《琵琶引》更多的是诗人自我怜惜,自伤零落栖迟.那么《简简吟》、《花非花》等作品则是以普通女性为关注对象,感伤美好事物易逝.     

臭氧降解低浓度四溴双酚A及生物毒性控制

为考察臭氧氧化技术对水中低质量浓度四溴双酚A的降解和毒性控制效能,利用臭氧反应装置研究不同pH和臭氧投加量条件下四溴双酚A(质量浓度为0.15 mg/L)的降解效果,考察反应过程中水样的急、慢性毒性和遗传毒性的变化规律及控制效果,分析毒性变化内在原因,并提出可能性降解机理.结果表明,当溶液pH为7.0、臭氧投加量为0.12 mg/L,四溴双酚A可被完全降解.反应初期,水样的急、慢性毒性迅速升高,原因主要是产生了毒性更高的有机中间产物;随着反应的进行,有毒中间产物被深度降解,急、慢性毒性均得到有效控制,且随着臭氧投加量的增加毒性控制得更快、更显著.当臭氧投加量为0.12 mg/L时,急性毒性在反应20 min时即可被完全控制,慢性毒性在反应60 min也被控制至0.76 TU,反应后水样的急、慢性毒性均满足排放标准.反应过程中水样的致突变比均小于2.0,不具有基因水平的遗传毒性.降解机理分析表明,臭氧降解四溴双酚A主要包括脱溴、β位断裂、加成、去羟基化、甲基化等反应过程.     

钛合金双辉离子无氢渗碳中的离子绕射现象

针对钛合金耐磨性差、易产生氢脆的特性,以格栅状高纯度固体石墨做源极,钛合金Ti6A14V做阴极,氩气作为工作气体,依靠辉光放电和空心阴极效应在Ti6A14V表面制备渗碳合金层;X射线衍射和辉光放电光谱试验显示,合金层由高硬度相TiC及游离态减磨C相组成;渗层内C元素的含量呈梯度分布;表面硬度大幅度提高.由表及里硬度梯度降低;反复试验表明,试样周围高浓度、稳定的渗碳气氛对形成理想的渗碳效果是非常重要的.     

高强耐热铝合金2A70-4T6棒材的研制

研究了高强耐热铝合金2A70—4T6棒材的化学成分、挤压工艺、热处理工艺对其组织性能的影响。通过大量的对比试验．确定了最佳的化学成分范围、合理的挤压工艺和热处理工艺制度。研制出多批量大规格2A70—4T6铝合金棒材，满足了用户的需要。     

D2、M2、S5模具扁钢脱碳特性实验研究

开展了在空气和氮气两种气氛下,采用Gleeble-1500热模拟机与普通电炉两种热方式、不同加热温度、加热时间对D2、M2、S5钢脱碳层深度影响的试验研究。依据试验结果,结合现场实际制定了较为合理的生产工艺并在现场成功应用,使上述模具扁钢脱碳层指标达到了美国ASTM－A681技术标准。