Surface designing of polypropylene by critical monitoring of the grafting conditions

The grafting of acrylic acid onto electron beam‐irradiated polypropylene was carried out using preirradiation method. The stability of peroxy radicals was investigated by electron spin resonance. It was found that the decay of peroxy radicals is much faster at 70°C than at 40°C and ambient temperature. The grafting has been observed to be strongly dependent on the monomer dilution in the reaction medium. The grafting was ascertained by attenuated total reflectance (ATR). The distribution of grafts across the samples was monitored by infrared microscopy. It was found that the graft management is considerably influenced by composition of the grafting medium. The grafting involving pure monomer leads to the surface enrichment with the polyacrylic acid chains. The samples grafted in pure monomer led to much lower contact angles as compared to the diluted monomer solution. The swelling of the grafted samples also showed a trend that was governed by the graft management. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 546–553, 2006     

Solar radiation climate in Malawi

Recently, Diabaté et al. [Diabaté, L., Blanc, Ph., Wald, L., 2004. Solar climate in Africa. Solar Energy 76, 733–744] created a map of solar radiation climate in Africa using clearness index for 62 sites. They established a solar climate class II located in Malawi and Madagascar. However, their analysis did not include any irradiation data from a site in Malawi. In this study, the solar radiation climate of Malawi has been studied using long-term global radiation data from a local site. The mean monthly (K_tm) and seasonal (K_ts) daily clearness indices for the site were computed. It is observed that K_tm has two maxima in a year (K_tm = 0.58 in May and K_tm = 0.64 in September), in close conformity with findings of Diabaté et al. (2004). Other results are presented and discussed.     

Preparation of an anion‐exchange adsorbent by the radiation‐induced grafting of vinylbenzyltrimethylammonium chloride onto cotton cellulose and its application for protein adsorption

Poly(vinylbenzyltrimethylammonium chloride)‐graft‐cotton cellulose, an anion‐exchange matrix, was synthesized by a mutual radiation‐induced grafting technique with a ⁶⁰Co γ‐radiation source. The grafted matrix was characterized by grafting yield estimation, elemental analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy. The grafting yield decreased with the increase in the dose rate. However, the grafting yield and nitrogen content of grafted samples increased almost linearly with an increase in the total irradiation dose. To evaluate the performance of the grafted anion‐exchange matrix, the protein adsorption and elution behavior were investigated in a continuous column process under various experimental conditions, with bovine serum albumin used as a model protein. The binding and elution behavior of the anion‐exchange matrix depended on different experimental parameters, such as the grafting yield, ionic strength, pH of the medium, and amount of protein loaded. From a breakthrough curve, the equilibrium binding capacity and elution percentage of the grafted anion‐exchange matrix were estimated to be 40 mg/g and 94%, respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5512–5521, 2006     

大空域机动巡航导弹的模糊PID控制器设计

针对大空域机动巡航导弹下降转平飞过程中出现的强非线性特点．在俯仰通道设计了模糊PID双模控制方案。以高度误差和该误差变化量为输入．以高度误差为阀限．在高度误差较大时采用响应迅速的模糊控制器．较小时采用稳态精度较高的PID控制器。最后通过仿真表明通过该方案所控制的弹道符合方案弹道．满足设计指标要求。     

Non‐reflecting artificial boundaries for transient scalar wave propagation in a two‐dimensional infinite homogeneous layer

This paper presents an exact non‐reflecting boundary condition for dealing with transient scalar wave propagation problems in a two‐dimensional infinite homogeneous layer. In order to model the complicated geometry and material properties in the near field, two vertical artificial boundaries are considered in the infinite layer so as to truncate the infinite domain into a finite domain. This treatment requires the appropriate boundary conditions, which are often referred to as the artificial boundary conditions, to be applied on the truncated boundaries. Since the infinite extension direction is different for these two truncated vertical boundaries, namely one extends toward x →∞ and another extends toward x→‐ ∞, the non‐reflecting boundary condition needs to be derived on these two boundaries. Applying the variable separation method to the wave equation results in a reduction in spatial variables by one. The reduced wave equation, which is a time‐dependent partial differential equation with only one spatial variable, can be further changed into a linear first‐order ordinary differential equation by using both the operator splitting method and the modal radiation function concept simultaneously. As a result, the non‐reflecting artificial boundary condition can be obtained by solving the ordinary differential equation whose stability is ensured. Some numerical examples have demonstrated that the non‐reflecting boundary condition is of high accuracy in dealing with scalar wave propagation problems in infinite and semi‐infinite media. Copyright © 2003 John Wiley & Sons, Ltd.     

超Jaynes-Cummings模型中的原子置于热辐射场时的相干特性

超Jaynes一Cummings模型中的两能级原子置于热辐射场。通过求解原子与热辐射场相互作用过程中原子约化密度算符非对角元．精确得出子原子相干性的衰变规律。研究了在相互作用系统中外加驱动场时可保持原子的相干性，此时外加驱动场的时间演化与原子的跃迁频率、原子偶极矩、热库的温度和k模光子频率等因素有关。     

Influence of a Jump in the Power of Laser Radiation on Its Measurement

Simulation and investigation of the effect of an isolated jump on realization of the unit of power of laser radiation and dissemination of the size of the unit are considered. Results are obtained by means of a newly developed algorithm that characterizes the behavior of the mean value of a signal and the standard deviation of a system as functions of the parameters of a jump in the power of laser radiation and the length and amplitude of the jump. If information concerning the time when a jump occurs is available, the proposed algorithm makes it possible to take into account how a jump affects the ultimate result of a measurement.     

同步辐射光刻技术

同步辐射光刻有希望代替传统光刻技术,用于0.25μm以下图形的超精细加工。本文叙述了它的原理、相关技术的开发现状和工艺应用。     

Improved cellulase production by stable Clostridium cellulolyticum mutants

Methods for the production of mutants of the cellulase producer Clostridium cellulolyticum ATCC 35319 were examined using an agar plate screening technique. Spontaneous and UV light-induced mutants were isolated, some of which exhibited a high level of both endoglucanase and exoglucanase activities as assayed using CMC (carboxymethyl cellulose) and PNPCb (paranitrophenyi-β-cellobioside) respectively. The volumetric enzyme activities were up to 2.5 times those of the wild strain.