Atomic layer chemical vapour deposition of copper

Copper films with (1 1 1) texture are of crucial importance in integrated circuit interconnects. We have deposited strongly (1 1 1)-textured thin films of copper by atomic layer deposition (ALD) using [2,2,6,6-tetramethyl-3,5-heptadionato] Cu(II), Cu(thd)₂, as the precursor. The dependence of the microstructure of the films on ALD conditions, such as the number of ALD cycles and the deposition temperature was studied by X-ray diffraction, scanning electron microscopy (SEM), and transmission electron microscopy. Analysis of (1 1 1)-textured films shows the presence of twin planes in the copper grains throughout the films. SEM shows a labyrinthine structure of highly connected, large grains developing as film thickness increases. This leads to low resistivity and suggests high resistance to electromigration.     

Dissolved organic carbon dynamics in the upper rhone: The influence of side-arms?

Dissolved organic carbon (DOC) dynamics were investigated over a two year period in the Upper Rhǒne River to examine the role of side-arms in providing DOC to the main channel in relation to discharge fluctuations, especially floods. Concentrations of DOC are shown to remain low in space and in time (average 1.5 mg ^?1) and to be more related to global hydrological events (precipitation) than to any local flushing for backwaters during floods. The results do not support the general assumption that side-arms are the providers of DOC to the main channel.     

36%渗乐乳油

３６％渗乐乳油田ＨＰ－１增效剂与乐果及其他助剂调配而成。五年田间小区和大田药效试验证明：３６％渗乐乳油高效，安全，用量少，对各类蚜虫防效优异。     

1，4－丁二醇的生产及市场需求

介绍了１，４－丁二醇的生产工艺、生产能力、产量和市场需求。     

涡轮钻具在高陡构造的应用及展望

介绍了涡轮钻具在秋参1井的应用情况,详细叙述了涡轮钻具在山前高陡构造快速钻进及防斜打直方面的优点,与常规钻井相比,机械钻速明显提高,钻井周期明显缩短,钻井成本明显下降,经济效益显著。     

减粘裂化分馏塔顶系统的腐蚀及防护

辽河石化分公司减粘裂化装置改炼辽河超稠油的减压渣油后 ,分馏塔顶系统由HCl -H2 S -HCN -有机酸 -H2 O引起的电化学腐蚀严重 ,其中油水分离器局部腐蚀速率达 3.1mm/a ,12AlMoV管束的空冷器运行不足两个月即发生泄漏。塔顶系统采用BZH - 1中和缓蚀剂、无机氨BZH - 913油溶性缓蚀剂综合注剂方案 ,使腐蚀得到控制     

7-羟基全氢化噁唑并噁嗪鞣剂的合成及其鞣性研究

报导了新型鞣剂 7-羟基全氢化唑并嗪 (以下简称 OX- Z)的合成方法。试验确定合成的最佳条件为 :在氮气保护下 ,将等摩尔量的二乙醇胺在 10℃水浴中缓慢滴入乙二醛中 ,滴加时间 0 .5 h,在 2 0℃水浴中继续反应 1.5 h,产率为 6 2 .9%。 OX- Z对浸酸绵羊皮单独鞣制 ,可使收缩温度升高到 87℃。最佳鞣制条件为 :p H10 .0 ,OX- Z用量 5 % ,鞣制时间 8h。在对 OX- Z与皮胶原的结合类型的研究中证明它们之间是以化学键结合的。     

二维谐振子与二维氢原子的能量及波函数

借助于ＳＵ(１,１)代数,找出了二维谐振子与二维氢原子的能量及波函数间的关系．     

常减压减一线生产柴油组分的探讨

从理论上分析了降低减一线馏程干点的可能性 ,并通过操作调整 ,降低了减一线馏程干点 ,使之符合作柴油调合组分。不仅对原直馏柴油的质量不产生影响 ,且经济效益可观。     

螺旋焊管内涂层涂敷挥发份的清除

针对大口径螺旋焊管内涂层涂敷作业时，钢管内残留的涂料挥发份如何清除的问题，介绍了一种自行设计制造的内涂层涂敷挥发份吹除装置。