酞菁铜薄膜光电晶体管的制备与特性

无机光敏器件难于做成大面积光电传感器,且其生产成本高、工艺复杂,而有机光敏器件多采用二极管或平面场效应三极管结构,导致光电流增益小或驱动电压较大.针对这些问题,提出一种新的器件结构.采用真空蒸镀和溅射的方法,制备了结构为氧化铟锡(ITO)/酞菁铜(Cu Pc)/铝(Al)/酞菁铜(Cu Pc)/铜(Cu)的有机光电晶体管.对器件的光电特性进行了测试分析,结果显示晶体管的I-V特性表现出显著的不饱和特性和光敏特性.当发射极集电极偏压为3 V时,器件无光照时电流放大系数为16.5,当625 nm光照射时的电流放大系数为266.2.     

一种新型矢量控制PWM调速系统

本文提出一种以８０９８单片机为中央处理单元，以ＨＥＦ４７５２Ｖ为辅助器件的新型矢量控制ＰＷＭ调速系统，给出控制电器原理框图及实验结果。实验表明本系统硬件电路简单，调节控制方便，运行结果比较理想。     

区域视角下我国老龄化人口的组合预测模型

为提高预测老龄人口的精度,以残差修正GM(1,1)模型、灰色-BP神经网络模型和Logistic预测模型作为单项模型,建立了一种基于相关系数的诱导有序加权平均(IOWA)算子组合预测模型.利用该模型对2000—2020年我国东部、中部、西部和东北部地区及全国老龄(≥65岁)人口数量进行预测显示,该组合预测模型的预测效果显著优于上述3个单项预测模型,表明该模型能够有效地提高老龄人口的预测精度.利用该组合预测模型对未来10年我国东部、中部、西部和东北部地区及全国老龄人口数进行预测显示:我国老龄人口数总体呈现逐步增长态势,同时区域间的老龄化进程差异也不断增大,其中东部地区老龄人口增长得相对较快,中部地区则增长得相对较慢.该预测结果可为我国老龄人口政策的制定提供参考.     

扩展的Jacobi椭圆函数展开法在求解Chen - Lee - Liu方程精确解中的应用

利用扩展的Jacobi椭圆函数展开法研究了Chen - Lee - Liu方程的精确解,所得解包括该方程的系列周期解和孤子解.特别地,当m→1和m→0时,得到了该方程的三角函数解和双曲函数解的精确表达式.绘制了该方程的三角函数解和双曲函数解的孤波图.其二维图像显示,孤立波的振幅不随时间的变化而发生变化,但其空间位置发生变化.     

“增收保”的农业试验研究

利用“增收保”喷施处理小麦、甜菜、棉花等大田作物，均具有较强的抗旱作用和显著的增产效果．拌种、浸种处理冬小麦，发现“增收保”具有较强的促进胚芽生长和根系发育作用，其发芽率、分蘖率、苗高优于清水对照组．试验表明，“增收保”是一种性能优良的植物生长调节剂和营养液．     

一类自治的发展方程的初值问题

本文利用半群理论证明了一类自治的发展方程的初值问题解的存在性和唯一性,得到了解的积分表达式。     

二对烯丙氧基乙氧基苯甲酰对苯二胺的合成与表征

以乙二醇单烯丙基醚、对羟基苯甲酸乙酯、对苯二胺为原料合成了末端为不饱和双键的芳香聚酰胺溶致型液晶化合物——二对烯丙氧基乙氧基苯甲酰对苯二胺,最佳合成的摩尔比为∶羧酸∶对苯二胺∶吡啶=2.2∶1∶2,反应时间为1 h,用POM、FTIR、1H NMR、DSC、XRD对液晶化合物单体进行了表征。该化合物为近晶型液晶,熔点为283℃。最终产率为74%。     

(11<Emphasis Type="Italic">Z</Emphasis>,13<Emphasis Type="Italic">E</Emphasis>)-Hexadecadien-1-yl Acetate: Sex Pheromone of the Grass Webworm <Emphasis Type="Italic">Herpetogramma licarsisalis</Emphasis>—Identification,Synthesis, and Field Bioassays

The grass webworm Herpetogramma licarsisalis (Lepidoptera: Crambidae), which has recently established in pasture in Northland, New Zealand, is an important pest of many tropical and subtropical grasses. Two pheromone components, (Z)-11-hexadecen-1-yl acetate (Z11–16:Ac) and (11Z,13E)-hexadecadien-1-yl acetate (Z11,E13–16:Ac), were identified in pheromone gland extracts of female moths by gas chromatography (GC), GC-electroantennographic detection, and GC-mass spectrometry in conjunction with microchemical tests (dimethyldisulfide and 4-methyl-1,2,4-triazoline-3,5-dione derivatizations). Z11,E13–16:Ac and its geometric isomer (11E,13Z)-hexadecadien-1-yl acetate (E11,Z13–16:Ac) were synthesized via stereoselective Wittig reactions, and the identity of the diene present in the pheromone glands was confirmed to be Z11,E13–16:Ac. Field bioassays at Indooroopilly in Brisbane, Australia, established that Z11,E13–16:Ac was necessary and sufficient for attraction of male grass webworm moths and that the corresponding alcohol, (11Z,13E)-hexadecadien-1-ol (Z11,E13–16:OH), had a strong inhibitory effect on trap catches at the ratios tested. When mixed with Z11,E13–16:Ac in various ratios, Z11–16:Ac had no effect on the attractiveness of lures. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Highly selective and sensitive Th<Superscript>4+</Superscript>-PVC-based membrane sensor based on 2-(diphenylphosphorothioyl)-<Emphasis Type="Italic">N</Emphasis>′,<Emphasis Type="Italic">N</Emphasis>′-diphenylacetamide

A Th⁴⁺ ion-selective membrane sensor was fabricated from poly (vinyl chloride) (PVC) matrix membrane containing 2-(diphenylphosphorothioyl)-N′,N′-diphenyl acetamide (DPTD) as a neutral carrier, potassium tetrakis (p-chlorophenyl) borate (KTpClPB) as anionic excluder and o-nitrophenyloctyl ether (NPOE) as a plasticizing solvent mediator. The effects of the membrane composition, pH and additive anionic influence on the response properties were investigated. The sensor, comprising 30% PVC, 63% solvent mediator, 4% ionophore and 3% anionic additive demonstrates the best potentiometric response characteristics. It displays Nernstian behavior (15.2 ± 0.5 mV per decade) over the concentration range 1.0 × 10⁻²–1.0 × 10⁻⁶ M. The detection limit of the electrode is 6.3 × 10⁻⁷ M (∼140 ng/ml). The response time of the electrode is 30 s .The sensor can be used in the pH range 3.0–9.0 for about 6 weeks. The membrane sensor was used as an indicator electrode in the potentiometric titration of Th⁴⁺ ions with EDTA. It was successfully applied to the determination of thorium ions in binary mixture.     

利用电阻探针对石油设备及管道的腐蚀进行监测

从1998年起，国内石油炼制行业开始大量炼制进口高硫原油，油气管道的腐蚀问题受到了重视。介绍了电阻探针腐蚀监测系统的原理及组成。并针对油气管道，实施了在线监测，安装了6组腐蚀电阻探针，分析了测量结果，为今后防腐工作提供了依据。